2-(溴乙酰基)-1,3-噻唑; 2-溴-1-(1,3-噻唑-2-基)乙酮

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 上游产品

2-(溴乙酰基)-1,3-噻唑; 2-溴-1-(1,3-噻唑-2-基)乙酮 基本信息

中文名称:
2-(溴乙酰基)-1,3-噻唑; 2-溴-1-(1,3-噻唑-2-基)乙酮 
中文别名:
2-(溴乙酰基)-1,3-噻唑;
2-溴-1-(1,3-噻唑-2-基)乙酮 
英文名称:
Ethanone,2-bromo-1-(2-thiazolyl)-
英文别名:
2-BROMO-1-(1,3-THIAZOL-2-YL)ETHANONE;
2-bromo-1-(1,3-thiazol-2-yl)-1-ethanone;
2-Brom-1-thiazol-2-yl-aethanon;
2-Bromo-1-(thiazol-2-yl)ethanone;
2-bromo-1-thiazol-2-yl-ethanone;
2-Bromo-1-(1,3-thiazol-2-yl)ethanone;
2-(BROMOACETYL)-1,3-THIAZOLE;
2-(3-ETHOXYPHENOXY)-5-METHYLANILINE;
2-bromo-1-(1,3-thiazol-2-yl)ethan-1-one;
2-(bromoacetyl)thiazole 
CAS No.:
3292-77-1
分 子 式:
C5H4BrNOS
分 子 量:
206.06
精确分子量:
204.92000
PSA:
58.20000
InChI:
InChI=1/C5H4BrNOS/c6-3-4(8)5-7-1-2-9-5/h1-2H,3H2
危险品标志:
风险术语:
R34   
安全术语:
S22;S26;S36/37/39;S45
分子结构式:
SDS:
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2-(溴乙酰基)-1,3-噻唑; 2-溴-1-(1,3-噻唑-2-基)乙酮 物化性质

密度:
1.763g/cm3
熔点:
54-55ºC
沸点:
266.7ºC at 760mmHg
闪点:
115.1ºC
折射率:
1.61

2-(溴乙酰基)-1,3-噻唑; 2-溴-1-(1,3-噻唑-2-基)乙酮 安全信息

海关代码:
2934100090
危险类别码:
R34
安全说明:
S22-S26-S36/37/39-S45
危险标志:
C:Corrosive;

2-(溴乙酰基)-1,3-噻唑; 2-溴-1-(1,3-噻唑-2-基)乙酮 MSDS

Name: 2-Bromo-1-(1 3-thiazol-2-yl)ethanone Material Safety Data Sheet
Synonym: None Known
CAS: 3292-77-1
Section 1 - Chemical Product   MSDS Name:2-Bromo-1-(1 3-thiazol-2-yl)ethanone Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
3292-77-1 2-Bromo-1-(1,3-thiazol-2-yl)ethanone 97+% unlisted
Hazard Symbols: C
Risk Phrases: 22 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute exposure.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 3292-77-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 54 - 55 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H4BrNOS
Molecular Weight: 206.06

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Amines, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide, hydrogen bromide, bromine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 3292-77-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Bromo-1-(1,3-thiazol-2-yl)ethanone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Pseudomonas putida:

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3292-77-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3292-77-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3292-77-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

2-(溴乙酰基)-1,3-噻唑; 2-溴-1-(1,3-噻唑-2-基)乙酮 海关数据

中国海关编码:2934100090

概述:
2934100090. 结构上含有一个非稠合噻唑环的化合物(不论是否氢化). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

2-(溴乙酰基)-1,3-噻唑; 2-溴-1-(1,3-噻唑-2-基)乙酮 上游产品

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