1-(4-硝基苯基)-3-乙氧基-5-吡唑酮

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

1-(4-硝基苯基)-3-乙氧基-5-吡唑酮 基本信息

中文名称:
1-(4-硝基苯基)-3-乙氧基-5-吡唑酮 
中文别名:
1-(4-硝基苯基)-3-乙氧基-5-吡唑酮;
1-(对硝基苯基)-3-乙氧基-5-吡唑酮 
英文名称:
3H-Pyrazol-3-one,5-ethoxy-2,4-dihydro-2-(4-nitrophenyl)-
英文别名:
5-ethoxy-2-(4-nitrophenyl)-4H-pyrazol-3-one;
EINECS 223-882-0 
CAS No.:
4105-90-2
分 子 式:
C11H11N3O4
分 子 量:
249.22
精确分子量:
249.07500
PSA:
87.72000
MDL:
MFCD00143123
EINECS:
223-882-0
InChI:
InChI=1/C11H11N3O4/c1-2-18-10-7-11(15)13(12-10)8-3-5-9(6-4-8)14(16)17/h3-6H,2,7H2,1H3
安全术语:
S24/25
分子结构式:
SDS:
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1-(4-硝基苯基)-3-乙氧基-5-吡唑酮 物化性质

外观与性状:
白色至灰白色固体
密度:
1.41 g/cm3
熔点:
142ºC
沸点:
390.8ºC at 760 mmHg
闪点:
190.1°C
折射率:
1.63
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房。 冷藏温度4ºC

稳定性相关:

常温常压下稳定,避免与氧化剂接触。

1-(4-硝基苯基)-3-乙氧基-5-吡唑酮 安全信息

海关代码:
2933199090
安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

1-(4-硝基苯基)-3-乙氧基-5-吡唑酮 MSDS

Name: 3-Ethoxy-1-(4-Nitrophenyl)-2-Pyrazolin- 5-One 98% (UV-Vis) Material Safety Data Sheet
Synonym: None
CAS: 4105-90-2
Section 1 - Chemical Product   MSDS Name:3-Ethoxy-1-(4-Nitrophenyl)-2-Pyrazolin- 5-One 98% (UV-Vis) Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
4105-90-2 3h-pyrazol-3-one,5-ethoxy-2,4-dihydro- 98 223-882-0
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 4105-90-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 142 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C11H11N3O4
Molecular Weight: 249.23

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 4105-90-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3h-pyrazol-3-one,5-ethoxy-2,4-dihydro-2-(4-nitrophenyl)- - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 4105-90-2: No information available.
Canada
CAS# 4105-90-2 is listed on Canada's NDSL List.
CAS# 4105-90-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4105-90-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

1-(4-硝基苯基)-3-乙氧基-5-吡唑酮 海关数据

中国海关编码:2933199090

概述:
2933199090. 其他结构上有非稠合吡唑环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933199090. other compounds containing an unfused pyrazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1-(4-硝基苯基)-3-乙氧基-5-吡唑酮 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):1.5

2.氢键供体数量:0

3.氢键受体数量:5

4.可旋转化学键数量:3

5.互变异构体数量:3

6.拓扑分子极性表面积87.7

7.重原子数量:18

8.表面电荷:0

9.复杂度:369

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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湖北楚盛威化工有限公司

产品介绍:
产品名称:1-(对硝基苯基)-3-乙氧基-5-吡唑酮 Cas号:4105-90-2 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
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