1-Cbz-4-哌啶甲醛

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 上游产品
  • 下游产品

1-Cbz-4-哌啶甲醛 基本信息

中文名称:
1-Cbz-4-哌啶甲醛 
中文别名:
1-Cbz-4-哌啶甲醛;
4-甲酰基哌啶-1-甲酸苄酯;
1-N-Cbz-4-甲酰基哌啶;
4-甲酰基-N-Cbz-哌啶;
1-CBZ-4-哌啶甲醛 
英文名称:
1-Piperidinecarboxylicacid, 4-formyl-, phenylmethyl ester
英文别名:
1-Cbz-4-Piperidinecarboxaldehyde;
4-FORMYL-N-CBZ-PIPERIDINE;
Benzyl 4-formylpiperidine-1-carboxylate;
1-Cbz-4-Piperidine Carboxaldehyde;
Benzyl 4-formyltetrahydro-1(2H)-pyridinecarboxylate;
benzyl 4-formylpiperidine-1-carboxylate 
CAS No.:
138163-08-3
分 子 式:
C14H17NO3
分 子 量:
247.29
精确分子量:
247.12100
PSA:
46.61000
InChI:
InChI=1/C14H17NO3/c16-10-12-6-8-15(9-7-12)14(17)18-11-13-4-2-1-3-5-13/h1-5,10,12H,6-9,11H2
风险术语:
36/37/38
分子结构式:
SDS:
查看

1-Cbz-4-哌啶甲醛 物化性质

密度:
1.221g/cm3
沸点:
384.5ºC at 760mmHg
闪点:
186.3ºC
折射率:
1.593
蒸汽压:
4.07E-06mmHg at 25°C

1-Cbz-4-哌啶甲醛 安全信息

海关代码:
2933399090
危险类别码:
R36/37/38
安全说明:
26-36/37/39
危险标志:
Xi

1-Cbz-4-哌啶甲醛 MSDS

Name: Benzyl 4-formyltetrahydro-1(2H)-pyridinecarboxylate 90+% Material Safety Data Sheet
Synonym: 4-Formyl-piperidine-1-carboxylic acid benzyl este
CAS: 138163-08-3
Section 1 - Chemical Product   MSDS Name:Benzyl 4-formyltetrahydro-1(2H)-pyridinecarboxylate 90+% Material Safety Data Sheet
Synonym:4-Formyl-piperidine-1-carboxylic acid benzyl este

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
138163-08-3 Benzyl 4-formyltetrahydro-1(2H)-pyridi 90+% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 138163-08-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Viscous liquid
Color: yellow
Odor: sweetish odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H17NO3
Molecular Weight: 247

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, amines, reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 138163-08-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzyl 4-formyltetrahydro-1(2H)-pyridinecarboxylate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 138163-08-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 138163-08-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 138163-08-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

1-Cbz-4-哌啶甲醛 海关数据

中国海关编码:2933399090

概述:
2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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