三异丙醇胺环硼酸盐

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

三异丙醇胺环硼酸盐 基本信息

中文名称:
三异丙醇胺环硼酸盐 
中文别名:
三异丙醇胺环硼酸酯;
三异丙醇胺环硼酸盐 
英文名称:
2,8,9-Trioxa-5-aza-1-borabicyclo[3.3.3]undecane,3,7,10-trimethyl-
英文别名:
Triisopropanolamine cyclic borate;
3,7,10-Trimethyl-2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane;
3,7,10-trimethyl-4,6,11-trioxa-1-aza-5-borabicyclo[3.3.3]undecane 
CAS No.:
101-00-8
分 子 式:
C9H18BNO3
分 子 量:
199.06
精确分子量:
199.13800
PSA:
30.93000
MDL:
MFCD03791298
InChI:
InChI=1/C9H18BNO3/c1-7-4-11-5-8(2)13-10(12-7)14-9(3)6-11/h7-9H,4-6H2,1-3H3
安全术语:
S24/25
分子结构式:
SDS:
查看

三异丙醇胺环硼酸盐 制备方法及用途

制备方法

汽油腐蚀抑制剂,金属工作液,汽油脱水剂,聚硅氧烷弹性橡胶稳定剂,粘合剂,聚合物交联剂。

用途简介

用途

汽油腐蚀抑制剂,金属工作液,汽油脱水剂,聚硅氧烷弹性橡胶稳定剂,粘合剂,聚合物交联剂。

三异丙醇胺环硼酸盐 物化性质

外观与性状:
白色至黄褐色的固体
密度:
1.05g/cm3
熔点:
150 °C
沸点:
196.2ºC at 760mmHg
闪点:
72.5°C
折射率:
1.462
蒸汽压:
0.403mmHg at 25°C
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房。

稳定性相关:

与强氧化剂反应。

其它信息:

1.       性状:白色固体

2.       密度(g/mL,25℃):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):150

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,50mmHg):未确定

7.       折射率(n20/D):未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(mmHg,40ºC):未确定

12.    饱和蒸气压(kPa,83ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

三异丙醇胺环硼酸盐 安全信息

海关代码:
2934999090
安全说明:
24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

三异丙醇胺环硼酸盐 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ED5787000
CHEMICAL NAME :
Boric acid, tris(1-amino-2-propyl) ester
CAS REGISTRY NUMBER :
101-00-8
LAST UPDATED :
199709
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C9-H18-B-N-O3
MOLECULAR WEIGHT :
199.09
WISWESSER LINE NOTATION :
Z1Y1&OBOY1Z1&OY1Z1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
7200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
毒理学数据:

1、皮肤/眼睛刺激性

标准的Draize试验:兔子,眼睛接触:10mg;反应的严重程度:轻度。

2、急性毒性:小鼠经口LD50:7200mg/kg;

三异丙醇胺环硼酸盐 MSDS

Name: Triisopropanolamine borate 98+% Material Safety Data Sheet
Synonym:
CAS: 101-00-8
Section 1 - Chemical Product   MSDS Name:Triisopropanolamine borate 98+% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
101-00-8 Triisopropanolamine borate, 98+% 98+% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Can burn in a fire, releasing toxic vapors.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide. Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 101-00-8: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 150 - 152 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H19NO3.H3BO3
Molecular Weight: 251.08

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of boron.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 101-00-8: ED5787000 LD50/LC50:
CAS# 101-00-8: Draize test, rabbit, eye: 10 mg Mild; Oral, mouse: LD50 = 7200 mg/kg.
Carcinogenicity:
Triisopropanolamine borate, 98+% - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 101-00-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 101-00-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 101-00-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

三异丙醇胺环硼酸盐 海关数据

中国海关编码:2934999090

概述:
2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

三异丙醇胺环硼酸盐 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:52.13

2、摩尔体积(cm3/mol):189.3

3、等张比容(90.2K):446.7

4、表面张力(dyne/cm):30.9

5、介电常数:无可用的

6、极化率(10-24cm3):20.66

7、单一同位素质量:199.137974 Da

8、标称质量:199 Da

9、平均质量:199.0551 Da

计算化学数据

1、   疏水参数计算参考值(XlogP):

2、   氢键供体数量:0

3、   氢键受体数量:4

4、   可旋转化学键数量:0

5、   互变异构体数量:

6、   拓扑分子极性表面积(TPSA):30.9

7、   重原子数量:14

8、   表面电荷:0

9、   复杂度:171

10、同位素原子数量:0

11、确定原子立构中心数量:0

12、不确定原子立构中心数量:3

13、确定化学键立构中心数量:0

14、不确定化学键立构中心数量:0

15、共价键单元数量:1

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