Version 1.6
Regulation (EC) No 1907/2006
1 - Product and Company Information
Product Name LITHIUM CHROMATE HYDRATE, TECHNICAL
GRADE
2 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
May cause cancer. May cause heritable genetic damage. Contact with
combustible material may cause fire. Irritating to eyes,
respiratory system and skin.
3 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
LITHIUM CHROMATE HYDRATE None None None
Formula Li2CrO4 · xH2O
Molecular Weight 129,8800 AMU
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER EYE CONTACT
Assure adequate flushing of the eyes by separating the eyelids
with fingers.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Noncombustible. Use extinguishing media appropriate to
surrounding fire conditions.
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SPECIAL RISKS
Specific Hazard(s): Contact with other material may cause fire.
Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
For fires involving this material, do not enter any enclosed or
confined fire space without proper protective equipment. This
may include self-contained breathing apparatus to protect
against the hazardous effects of the normal products of
combustion or oxygen deficiency
6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Do not use if skin is cut or
scratched. Wash thoroughly after handling.
STORAGE
Conditions of Storage: Keep tightly closed. Keep away from
combustible materials, heat, sparks, and open flame. Store in a
cool dry place.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Discard contaminated
shoes.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
respirator, chemical-resistant gloves, safety goggles, other
protective clothing. Faceshield (8-inch minimum).
9 - Physical and Chemical Properties
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
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Vapor Pressure N/A
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Materials to Avoid: Reducing agents, Organic materials Avoid
contact with acid.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Nature of decomposition products
not known.
11 - Toxicological Information
SENSITIZATION
Sensitization: May cause allergic respiratory and skin reactions
SIGNS AND SYMPTOMS OF EXPOSURE
Large doses of lithium ion have caused dizziness and
prostration, and can cause kidney damage if sodium intake is
limited. Dehydration, weight loss, dermatological effects, and
thyroid disturbances have been reported. Central nervous system
effects that include slurred speech, blurred vision, sensory
loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and
neuromuscular effects such as tremor, clonus, and hyperactive
reflexes may occur as a result of repeated exposure to lithium
ion. Inhalation of dichromate dusts can cause ulceration and
perforation of the nasal septum. Contact with breaks in the skin
can cause ulceration (chrome sores). Other symptoms of exposure
include erosion and discoloration of the teeth, nephritis,
epigastric pain (inflammation and ulceration of the
gastrointestinal tract). Anemia. Stomach pains, vomiting,
diarrhea. Exposure can cause:
ROUTE OF EXPOSURE
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract.
Multiple Routes: Causes eye and skin irritation. May be fatal if
inhaled, swallowed, or absorbed through skin.
TARGET ORGAN INFORMATION
Kidneys. Lungs. Central nervous system. Blood.
CHRONIC EXPOSURE - CARCINOGEN
Result: Carcinogen.
12 - Ecological Information
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No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Cautiously acidify a 3% solution or a suspension of the material
to pH 2 with sulfuric acid. Gradually add a 50% excess of aqueous
sodium bisulfite with stirring at room temperature. An increase in
temperature indicates that a reaction is taking place. If no
reaction is observed on the addition of about 10% of the sodium
bisulfite solution initiate it by cautiously adding more acid. If
manganese, chromium, or molybdenum are present adjust the pH of
the solution to 7 and treat with sulfide to precipitate for burial
as hazardous waste. Destroy excess sulfide, neutralize, and flush
the solution down the drain. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 1479
Class: 5.1
PG: III
Proper Shipping Name: Oxidizing solid, n.o.s.
IMDG
UN#: 1479
Class: 5.1
PG: III
Proper Shipping Name: Oxidizing solid, n.o.s.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 1479
Class: 5.1
PG: III
Proper Shipping Name: Oxidizing solid, n.o.s.
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: O-T+
Oxidizing. Very toxic.
R-PHRASES: 45-46-8-36/37/38
May cause cancer. May cause heritable genetic damage. Contact
with combustible material may cause fire. Irritating to eyes,
respiratory system and skin.
S-PHRASES: 53-17-36/37/39-45
Avoid exposure - obtain special instructions before use. Keep
away from combustible material. Wear suitable protective
clothing, gloves, and eye/face protection. In case of accident
or if you feel unwell, seek medical advice immediately (show
the label where possible).
Caution: Substance not yet fully tested (EU).
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COUNTRY SPECIFIC INFORMATION
Germany
WGK: 3
Self-Classification
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
N/A
