D-蛋氨醇

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学

D-蛋氨醇 基本信息

中文名称:
D-蛋氨醇 
中文别名:
D-蛋氨醇;
(1R)-1,6-dimethyl-1,2-dihydrophenanthro[1,2-b]furan-10,11-dione;
15,16-Dihydrotanshinone I;
Dihydrotanshinone I;
(3-Hydroxymethylphenyl)boronic acid;
(2-Hydroxymethylphenyl)boronic acid, dehydrate;
1-BOC-4-AMINOPIPERIDINE;
1-BUTYLOXYCARBONYL-4-AMINO-PIPERIDINE;
4-AMINO-1-BOC-PIPERIDINE;
4-AMINO-1-TERT-BUTOXYCARBONYL-PIPERIDINE;
4-AMINO-1-N-BOC-PIPERIDINE;
4-AMINO-PIPERIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER;
4-AMINOPIPERIDINE, 1-BOC PROTECTED;
CHEM 
英文名称:
1-Butanol,2-amino-4-(methylthio)-, (2R)-
英文别名:
(2R)-2-amino-4-methylsulfanylbutan-1-ol;
(S)-Methioninol;
H-D-Met-ol;
(R)-2-Amino-4-methylmercapto-butan-1-ol;
(R)-2-amino-4-methylthio-1-butanol;
(R)-2-amino-4-methylsulfanyl-butan-1-ol;
D(+)-Methioninol;
(R)-methioninol;
L-2-amino-4-methylsulfanylbutanol;
AmbotzFAL1006 
CAS No.:
87206-44-8
分 子 式:
C5H13NOS
分 子 量:
135.23
精确分子量:
135.07200
PSA:
71.55000
InChI:
InChI=1/C5H13NOS/c1-8-3-2-5(6)4-7/h5,7H,2-4,6H2,1H3/t5-/m1/s1
风险术语:
R36/37/38
安全术语:
S22;S24/25
分子结构式:
SDS:
查看

D-蛋氨醇 物化性质

外观与性状:
透明晶体
密度:
1.068 g/cm3
熔点:
31 - 33ºC
沸点:
198 - 200ºC
闪点:
113ºC
折射率:
1.5216
存储条件/存储方法:

 

密闭于0-6 ºC阴凉干燥环境中

稳定性相关:

 

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):1.095

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):31-36

5.       沸点(ºC,常压):120-122

6.       沸点(ºC,5.2kPa):无可用

7.       折射率: 1.5216

8.       闪点(ºC):113

9.       比旋光度(º):12.7(C=1.4, 乙醇)

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

D-蛋氨醇 安全信息

海关代码:
2930909090
危险类别码:
R36/37/38
安全说明:
S26-S37/39
安全标志:
S22:不要吸入粉尘。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S24/25:防止皮肤和眼睛接触。
:
危险标志:
Xi: Irritant;

D-蛋氨醇 毒理性

生态数据:

 

 

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

D-蛋氨醇 MSDS

Name: D-(+)-Methioninol Material Safety Data Sheet
Synonym: (R)-2-Amino-4-methylmercapto-1-butano
CAS: 87206-44-8
Section 1 - Chemical Product   MSDS Name:D-(+)-Methioninol Material Safety Data Sheet
Synonym:(R)-2-Amino-4-methylmercapto-1-butano

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
87206-44-8 D-(+)-Methioninol unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 87206-44-8: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: waxy
Odor: sulfurous odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 120-122 deg C @ 1 m
Freezing/Melting Point: 31-36 deg C
Autoignition Temperature: Not available.
Flash Point: > 109 deg C (> 228.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.095
Molecular Formula: C5H13NOS
Molecular Weight: 135.1571

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 87206-44-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
D-(+)-Methioninol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 87206-44-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 87206-44-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 87206-44-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

D-蛋氨醇 海关数据

中国海关编码:2930909090

概述:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

D-蛋氨醇 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:38.23

2、   摩尔体积(m3/mol):126.5

3、   等张比容(90.2K):324.8

4、   表面张力(dyne/cm):43.3

5、   极化率10-24cm3):15.15

计算化学数据

1、   疏水参数计算参考值(XlogP):-0.3

2、   氢键供体数量:2

3、   氢键受体数量:1

4、   可旋转化学键数量:4

5、   拓扑分子极性表面积(TPSA):47.9

6、   重原子数量:8

7、   表面电荷:1

8、   复杂度:51.7

9、   同位素原子数量:0

10、   确定原子立构中心数量:1

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

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