(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 基本信息

中文名称:
(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 
中文别名:
(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮;
(4R,5s)-(+)-4-甲基-5-苯基-2-噁唑烷酮;
(4R,5S)-4-甲基-5-苯基-2-噁唑啉酮;
(4R,5S)-(+)-4-甲基-5-苯基-2-噁唑啉酮 
英文名称:
2-Oxazolidinone,4-methyl-5-phenyl-, (4R,5S)-
英文别名:
(4R,5S)-(+)-4-Methyl-5-phenyl-2-oxazolidinone;
(4R,5S)-4-methyl-5-phenyl-1,3-oxazolidin-2-one 
CAS No.:
77943-39-6
分 子 式:
C10H11NO2
分 子 量:
177.20
精确分子量:
177.07900
PSA:
38.33000
MDL:
MFCD00010845
BRN:
1211705
InChI:
The Key: PPIBJOQGAJBQDF-CBAPKCEASA-N
风险术语:
 N:;
安全术语:
S22S24/25
分子结构式:
SDS:
查看

(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 物化性质

外观与性状:
白色至淡黄色晶体粉末
密度:
1.132 g/cm3
熔点:
121-123 °C(lit.)
沸点:
395.8ºC
闪点:
193.2ºC
折射率:
1.526
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):121-123

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 安全信息

海关代码:
2934999090
WGK_Germany:
3
德国有关水污染物质的分类清单
安全说明:
S22-S24/25
安全标志:
S22:不要吸入粉尘。
S24/25:防止皮肤和眼睛接触。
危险标志:
N: Dangerous for the environment;

(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 MSDS

Name: (4R 5S)-(+)-4-Methyl-5-phenyl-2-oxazolidinone 99% Material Safety Data Sheet
Synonym: None Known
CAS: 77943-39-6
Section 1 - Chemical Product   MSDS Name:(4R 5S)-(+)-4-Methyl-5-phenyl-2-oxazolidinone 99% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
77943-39-6 (4R,5S)-(+)-4-Methyl-5-phenyl-2-oxazol 99% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 77943-39-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 106 - 109 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H11NO2
Molecular Weight: 177.20

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 77943-39-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(4R,5S)-(+)-4-Methyl-5-phenyl-2-oxazolidinone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 77943-39-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 77943-39-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 77943-39-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 海关数据

中国海关编码:2934999090

概述:
2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:48.07

2、   摩尔体积(m3/mol):156.4

3、   等张比容(90.2K):384.0

4、   表面张力(dyne/cm):36.3

5、   极化率10-24cm3):19.05

计算化学数据

1.疏水参数计算参考值(XlogP):1.7

2.氢键供体数量:1

3.氢键受体数量:2

4.可旋转化学键数量:1

5.互变异构体数量:2

6.拓扑分子极性表面积38.3

7.重原子数量:13

8.表面电荷:0

9.复杂度:199

10.同位素原子数量:0

11.确定原子立构中心数量:2

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

推荐供应商更多供应商>>

湖北诺纳科技有限公司

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 Cas号:77943-39-6 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:张经理 电话:027-59209883 手机:17386169806

上海吉至生化科技有限公司

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基-5-苯基-2-噁唑烷酮 Cas号:77943-39-6 纯度:98% 包装信息:10gea,1gea,25gea,5gea 价格:108.0元 - 1,805.0元
联系方式:
联系人:江珊 电话:021-57520831 手机:15316869680

北京百灵威科技有限公司

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 271158 Cas号:77943-39-6 纯度:99% 包装信息:1g,5g 价格:洽谈
联系方式:
联系人:翟先生 电话:18210857532 手机:18210857532

湖北鑫鸣泰化学有限公司

产品介绍:
产品名称:4R,5S)-4-甲基-5-苯基恶唑烷酮 Cas号:77943-39-6 纯度:98% 包装信息:200/桶kg,200/桶kg 价格:1.0元 - 1.0元
联系方式:
联系人:黄经理 电话:027-51833411 手机:13237166274

湖北臻博化工有限公司

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 Cas号:77943-39-6 纯度:98% 包装信息:200kg,25kg,1kg 价格:洽谈
联系方式:
联系人:张经理 电话:18071535998 手机:18071535998

湖北鑫鸣泰化学有限公司

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基 Cas号:77943-39-6 纯度:99% 包装信息:100kg,200kg 价格:1.0元 - 1.0元
联系方式:
联系人:黄 电话:027-50662354 手机:13264726139

天津卡普希科技有限公司

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 海兔毒素中间体4 Cas号:77943-39-6 纯度:98 包装信息:1g 价格:洽谈
联系方式:
联系人:刘琼 电话:022-66211079 手机:15270500295

武汉福德化工有限公司

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 Cas号:77943-39-6 纯度: 包装信息:25kg 价格:洽谈
联系方式:
联系人:刘雅倩 电话:027-83855392 手机:15827396479

西格玛奥德里奇

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基-5-苯基-2-噁唑啉酮 Cas号:77943-39-6 纯度:99% 包装信息:g-kg 价格:洽谈
联系方式:
联系人:默克 电话:021-61514946 手机:

武汉伯业科技发展有限公司

产品介绍:
产品名称:(4R,5S)-(+)-4-甲基-5-苯基-2-恶唑啉酮 Cas号:77943-39-6 纯度:98% 包装信息:25kg 价格:1.0元
联系方式:
联系人:刘婧 电话:027-81625225 手机:15387090420