三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 基本信息

中文名称:
三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 
中文别名:
三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷;
5-(三甲基硅基)-1,2,3,4,5-五甲基-1,3-环戊二烯 
英文名称:
1,3-Cyclopentadiene,1,2,3,4,5-pentamethyl-5-(trimethylsilyl)-
英文别名:
(Pentamethylcyclopentadien-1-yl)trimethylsilane;
trimethyl-(1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-yl)silane 
CAS No.:
87778-95-8
分 子 式:
C13H24Si
分 子 量:
208.42
精确分子量:
208.16500
PSA:
0.00000
MDL:
MFCD00151193
InChI:
InChI=1/C13H24Si/c1-9-10(2)12(4)13(5,11(9)3)14(6,7)8/h1-8H3
安全术语:
S24/25
分子结构式:
SDS:
查看

三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 物化性质

外观与性状:
透明黄色液体
密度:
0.864
沸点:
100-101ºC (10 mmHg)
闪点:
76ºC
折射率:
1.488
存储条件/存储方法:

干燥、阴凉、密闭处、惰性气体的环境中

稳定性相关:

按规定使用和贮存的不会分解,避氧化物、热、明火

其它信息:

1.      性状:未确定

2.      密度(g/mL25 ºC):0.864

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):未确定

5.      沸点(ºC,常压):未确定

6.      沸点(ºC10mmHg):100.0-101.0

7.      折射率:n20/D 1.488

8.      闪点(ºC):76

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(正辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 安全信息

海关代码:
2931900090
安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 MSDS


Section 1: Product Identification
   Chemical Name:       Trimethylsilyl pentamethylcyclopentadiene    
   CAS Registry Number:       87778-95-8    
   Formula:       [C5(CH3)5]Si(CH3)3    
   EINECS Number:       none    
   Chemical Family:       organosilicon compounds    
   Synonym:       Cyclopentadienyltrimethylsilane    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       87778-95-8       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       May be irritating to skin, eyes, and respiratory tract.    
   Primary Routes of Exposure:       Inhalation, skin, eyes.    
   Eye Contact:       May cause moderate irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       May cause irritation to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may result in the release of a large amount of acetylene gas.    
   Acute Health Affects:       May be irritating to skin, eyes, and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide or dry powder    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit carbon monoxide, carbon dioxide and t    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Highly flammable. Formation of explosive air/vapor mixtures is possible.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be absorbed into vermiculite or other suitable adsorbent. Sweep up and dispose of properly.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a cool, dry place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       light yellow liq.    
   Molecular Weight:       208.42    
   Melting Point:       no data    
   Boiling Point:       100°C/10 mm    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive, (store cold)    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with heat and ignition sources.    
   Incompatibility:       Strong oxidizing agents and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, silicon dioxide, and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Flammable liquids, N.O.S.    
   Hazard Class (CFR):       3    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1993    
   Shipping Name (IATA):       Flammable liquid, N.O.S.    
   Hazard Class (IATA):       3    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1993    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 海关数据

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:67.85

2、   摩尔体积(m3/mol):246.6

3、   等张比容(90.2K)537.7

4、   表面张力(dyne/cm)22.6

5、   极化率(10-24cm3)26.90

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:14

8.表面电荷:0

9.复杂度:300

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 上游产品

三甲基(1,2,3,4,5-五甲基环戊二烯基)硅烷 下游产品

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