颜料蓝 29; 群青蓝

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 表征图谱

颜料蓝 29; 群青蓝 基本信息

中文名称:
颜料蓝 29; 群青蓝 
中文别名:
颜料蓝 29;
群青蓝 
英文名称:
Pigment Blue 29
英文别名:
Azure blue;
UNII-I39WR998BI;
Ultramarine blue pigment;
Pigment Blue 29;
Ultramarine Blue;
C.I. PIGMENT BLUE 29 
CAS No.:
57455-37-5
分 子 式:
Na6Al4Si6S4O20
分 子 量:
994.50100
精确分子量:
993.46300
PSA:
578.74000
分子结构式:
SDS:
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颜料蓝 29; 群青蓝 制备方法及用途

制备方法

群青蓝是一种无机颜料,其颜料索引体系位列颜料蓝29号。其化学结构为硅铝磷酸盐,是一种人造青金石色颜料。群青具有一种纯净,亮丽且呈红相的蓝色,这使得群青蓝不同于市场上其他的蓝色颜料而具有独特的吸引力。此外,由于群青所具有的非常独特的红光蓝色相,使之具有优异的减弱和矫正黄色色光的功能,并且群青在运用中不会导致同色异谱现象的出现。其增白作用在众多应用领域中效果显著(包括塑料,油漆,洗涤剂等)。

合成制备方法

1.高温煅烧法将陶土、纯碱、硫黄、木炭、硫酸钠、石英等原料混合,经分装坩埚进窑高温煅烧,出料冷却,挑选除未烧成物,经浸渍、研磨、压滤,再经干燥、粉碎,制得群青成品。

2.以埃洛石为原料制备 将埃洛石和石英砂(埃洛石和石英砂的摩尔比控制在2.6~3)用圆盘粉碎机粉碎,然后过200目筛。其他原料(硫黄、纯碱、松香)同样经粉碎后,过200目筛,硫黄和纯碱过量。然后将埃洛石在700℃下煅烧3h,在坩埚中先升温至730℃再煅烧6~8h,再升温至730~800℃加热8h,经水洗、除硫、研磨、干燥即得成品。

3.以陶土为原料制备 将陶土、纯碱、硫黄、木炭、硫酸钠、石英等原料混合,经分装坩埚进窑高温煅烧,出料冷却,挑选除未烧成物,经浸渍、研磨、压滤,再经干燥、粉碎,制得群青成品。其烧成反应式如下:

 

用途简介

用途

1.无机蓝色颜料。涂料工业用于制造色漆,使白度更加鲜明。橡胶工业用于球鞋大底、胶板等橡胶制品的着色、提白或与黄颜料拼配草绿色。造纸工业用于纸浆中以制出鲜明白色或带有蓝色的纸浆。印染纺织工业用于白色棉布、针织品以增加纤维白度及布匹针织物的打印商标。颜料工业用于油画颜料的着色和用作白色颜料的提白剂。塑料工业用于塑料制品和人造革的着色、拼着和提白。建筑工业用于水泥方砖、人造大理石的着色。此外,群青还可用于全氟化碳树脂的防老剂、氢化裂解催化剂,以及从海水中吸附铀等。

颜料蓝 29; 群青蓝 物化性质

外观与性状:
固体
存储条件/存储方法:

贮存于通风、干燥的库房内。应注意防潮。

 

稳定性相关:

具有消除及减低白色涂料或其他白色材料中含有黄色色光的效能。耐碱、耐高温,在大气中对日晒及风雨极其稳定,但不耐酸,遇酸分解变色。

         工作时需佩戴防毒口罩,车间应注意通风和除尘。

耐碱性优良,但不耐酸,遇酸易分解变色。在大气中对日晒稳定,特别具有消除及减低白色涂料或其他白色材料中含有黄色色光的功能。但着色力、遮盖力较低,无毒。

其它信息:

1.       性状:半透明蓝色粉末。色泽鲜艳,带有红光。

2.       密度(g/mL,25ºC):未确定

3.       相对蒸汽密度(g/mL,空气=1): 未确定

4.       熔点(ºC):未确定

5.       沸点(ºC):未确定

6.       沸点(ºC,0.1mmHg):未确定

7.       折射率:未确定

8.       闪点(°C):未确定

9.       比旋光度(ºC):未确定

10.    自燃点或引燃温度(ºC): 未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:不溶于水,不溶于水和有机溶剂。

颜料蓝 29; 群青蓝 毒理性

毒理学数据:

吸入粉尘,表现为食欲不振,嗝气中含硫化氢,胃液酸性下降。如吞入胃内,会出现硫化氢中毒症状,肺内出现尘肺样变化。

生态数据:

对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境

颜料蓝 29; 群青蓝 MSDS


Section 1. Chemical Product and Company Identification
    Ultramarine blue
    Common Name/
    Trade Name
    Manufacturer
    Commercial Name(s)
    Synonym
    Chemical Name
    Chemical Family
    Ultramarine blue

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for    
    at least 15 minutes. Get medical attention if irritation occurs.
    Skin Contact        Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation    
    develops.
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.    
    Get medical attention.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
    symptoms appear.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not available.    
    Flammable Limits        Not available.    
    Products of Combustion        Not available.    
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Special Remarks on        Not available.    
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill        Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading    
    water on the contaminated surface and allow to evacuate through the sanitary system.

Section 7. Handling and Storage
    Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
    Precautions
    ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the
    label.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area.    
    Ultramarine blue

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
    exposure to airborne contaminants below the exposure limit.
    Personal Protection        Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.    
    Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be
    a Large Spill        used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a    
    specialist BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Powdered solid.)        Odor        Odorless.    
    Taste        Not available.    
    Molecular Weight        Not available.    
    Color        Blue.    
    pH (1% soln/water)        Not applicable.    
    Not available.
    Boiling Point
    Melting Point        Decomposition temperature: >1000°C (1832°F)    
    Critical Temperature        Not available.    
    Specific Gravity        2.3 (Water = 1)    
    Vapor Pressure        Not applicable.    
    Vapor Density        Not available.    
    Volatility        Not available.    
    Not available.
    Odor Threshold
    Water/Oil Dist. Coeff.        Not available.    
    Ionicity (in Water)        Not available.    
    Dispersion Properties        Not available.    
    Solubility        Insoluble in cold water.    

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Instability Temperature        Not available.    
    Conditions of Instability        Excess heat, incompatible materials    
    Reactive with acids.
    Incompatibility with various
    substances
    Non-corrosive in presence of glass.
    Corrosivity
    Special Remarks on        Evolves hydrogen sulfide on contact with acids.    
    Reactivity
    Not available.
    Special Remarks on
    Corrosivity
    Polymerization        Will not occur.    
    Ultramarine blue

Section 11. Toxicological Information
    Routes of Entry        Inhalation. Ingestion.    
    Toxicity to Animals        Acute oral toxicity (LD50): 10000 mg/kg [Mouse].    
    Chronic Effects on Humans Not available.
    Other Toxic Effects on        Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.    
    Humans
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: May cause skin irritation.    
    Eyes: May cause eye irritation.
    Inhalation: May cause respiratory tract irritation.
    Ingestion. Low hazard.
    Chronic Potential Health Effects:
    Prolonged or repeated ingestion of large amounts may affect the gastrointesstional system and urinary
    system. (from RTECS)

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    BOD5 and COD        Not available.    
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products    
    may arise.
    Toxicity of the Products        The product itself and its products of degradation are not toxic.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Not applicable.
    Identification
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)
    Ultramarine blue

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Ultramarine blue
    Federal and State
    Regulations
    California        California prop. 65: This product contains the following ingredients for which the State of California has    
    Proposition 65        found to cause cancer which would require a warning under the statute: No products were found.    
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has
    found to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        EINECS: This product is not on the European Inventory of Existing Commercial Chemical Substances.    
    Canada: Listed on Canadian Domestic Substance List (DSL).
    China: Listed on National Inventory.
    Japan: Listed on National Inventory (ENCS).
    Korea: Listed on National Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    WHMIS (Canada) Not controlled under WHMIS (Canada).
    Other Classifications
    DSCL (EEC)        This product is not classified        Not applicable.    
    according to the EU regulations.
    Health Hazard
    HMIS (U.S.A.)        1 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    1 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent.
    Ultramarine blue


SECTION 16 - ADDITIONAL INFORMATION
N/A

颜料蓝 29; 群青蓝 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:27

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积581

7.重原子数量:47

8.表面电荷:0

9.复杂度:19.1

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:21

颜料蓝 29; 群青蓝 表征图谱

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