溴化铑(III)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品

溴化铑(III) 基本信息

中文名称:
溴化铑(III) 
中文别名:
溴化铑(III);
溴化铑(III)水合物;
二水溴化铑;
溴化铑 
英文名称:
Rhodium bromide (RhBr3)
英文别名:
rhodium(3+),tribromide;
Rhodiumtribromid;
EINECS 239-687-9;
Rhodium bromide;
Rhodium tribromide 
CAS No.:
15608-29-4
分 子 式:
Br3Rh
分 子 量:
342.62
精确分子量:
375.68200
PSA:
18.46000
EINECS:
239-687-9
InChI:
The Key: MMRXYMKDBFSWJR-UHFFFAOYSA-K
分子结构式:
SDS:
查看

溴化铑(III) 制备方法及用途

制备方法

将金属铑同45%HBr-Br2的混合物一起加热,所得产物在Br2气流中于400℃下进行处理,即可生成无水溴化铑,将这种物质置于密封的石英管中,在Br2-N2气氛中于850℃加热,可以得到结晶状产品。一种可溶于水的溴化铑可以从RhCl3的水溶液中制得,将Na2CO3加入到RhCl3的水溶液中,沉淀出铑的氢氧化物,将这种氢氧化物分离出并洗净后,用氢溴酸处理,即可得到可溶于水的溴化铑。

合成制备方法

将金属铑同45%HBr-Br2的混合物一起加热,所得产物在Br2气流中于400℃下进行处理,即可生成无水溴化铑,将这种物质置于密封的石英管中,在Br2-N2气氛中于850℃加热,可以得到结晶状产品。一种可溶于水的溴化铑可以从RhCl3的水溶液中制得,将Na2CO3加入到RhCl3的水溶液中,沉淀出铑的氢氧化物,将这种氢氧化物分离出并洗净后,用氢溴酸处理,即可得到可溶于水的溴化铑。

用途简介

原料药。

溴化铑(III) 物化性质

存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 遵照规定使用和储存则不会分解。可溶于水的溴化铑可能在其晶格中含有氢氧根离子。

其它信息:

1.       性状:高温下生成的无水溴化铑为红棕色晶体,单斜系结晶

2.       密度(g/mL,25/4℃):5.59

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

溴化铑(III) 安全信息

包装等级:
III
风险类别:
6.1(b)

溴化铑(III) 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

溴化铑(III) MSDS


Section 1: Product Identification
   Chemical Name:       Rhodium (III) bromide dihydrate    
   CAS Registry Number:       15608-29-4    
   Formula:       RhBr3.2H2O    
   EINECS Number:       none    
   Chemical Family:       metal halide    
   Synonym:       Rhodium tribromide    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       15608-29-4       100%       0.01mg/m3 (as Rh       0.001mg/m3 (as Rh    

Section 3: Hazards Identification
   No notable hazards reported for this material. Unrecognized hazards may be present. Dust may be irritating to
   Emergency Overview:
   the respiratory tract, skin and eyes. May be harmful if swallowed.
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust.    
   Eye Contact:       May be a mild irritant to the eyes.    
   Skin Contact:       May cause slight irritation of the skin.    
   Inhalation:       Inhalation of dust can lead to irritation of the respiratory tract.    
   Ingestion:       Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.    
   Acute Health Affects:       May be irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       none    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
   Spill and Leak Procedures:
   inert material and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store solid in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       brown to black xtl.    
   Molecular Weight:       342.63 (378.66)    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       Pungent odor.    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       chlorine and active metals    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

溴化铑(III) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:4

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

溴化铑(III) 上游产品

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产品介绍:
产品名称:溴化铑(III) Cas号:15608-29-4 纯度: 包装信息:洽谈 价格:洽谈
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产品介绍:
产品名称:溴化铑 Cas号:15608-29-4 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
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