乙酸钪

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS

乙酸钪 基本信息

中文名称:
乙酸钪 
中文别名:
乙酸钪;
水合乙酸钪(III);
水合乙酸钪(Ⅲ);
乙酸钪水合物;
乙酸钪(III);
乙酸钪(III)六水合物 
英文名称:
Acetic acid,scandium(3+) salt (3:1)
英文别名:
Scandium (III) acetate hydrate (99.9%-Sc) (REO);
acetic acid,scandium acetate;
Scandium triacetate;
Scandiumoxalat-Hexahydrat;
SCANDIUM OXALATE HYDRATE;
Scandium Oxalate Pentahydrate 99.;
Essigsaeure,Scandiumacetat;
Scandium Carbonate Hydrate;
scandium oxalate hexahydrate;
Scandiumacetat;
SCANDIUM OXALATE HYDRATE,99. 
CAS No.:
3804-23-7
分 子 式:
C2H4O2.1/3Sc
分 子 量:
222.09
精确分子量:
221.99600
PSA:
120.39000
EINECS:
223-274-5
InChI:
The Key: ORQKSRXFNGXMKE-UHFFFAOYSA-M
分子结构式:
SDS:
查看

乙酸钪 制备方法及用途

合成制备方法

取氧化钪10g,加至盛有500mL的50%醋酸水溶液的1L圆底烧瓶中,用蒸气浴加热片刻,氧化钪溶于醋酸溶液中。若仍有少量未反应氧化物残留于瓶底,则需过滤。将滤液置于75℃水浴上加热,以除去大部分溶剂。冷却,滤集晶体,得到一水醋酸钪,可用醋酸重结晶。在150℃加热至恒重,得到无水物。

乙酸钪 物化性质

外观与性状:
白色结晶固体
沸点:
117.1ºC at 760mmHg
闪点:
40ºC
存储条件/存储方法:

避光,通风干燥处,密封保存

稳定性相关:

常温常压下稳定。加热至285~305℃,发生分解,分出醋酸酐,用水吸收得到醋酸。加热至372℃,重新得到氧化钪。

其它信息:

一、物性数据

1.       性状:无色或白色晶体,具吸湿性。

2.       密度(g/mL,25/4℃):不确定

3.       相对蒸汽密度(g/mL,空气=1):不确定

4.       熔点(ºC):不确定

5.       沸点(ºC,常压):不确定

6.       沸点(ºC,5.2kPa):不确定

7.       折射率:不确定

8.       闪点(ºC):不确定

9.       比旋光度(ºC):不确定

10.    自燃点或引燃温度(ºC)不确定

11.    蒸气压(kPa,25ºC):不确定

12.    饱和蒸气压(kPa,60ºC):不确定

13.    燃烧热(KJ/mol):不确定

14.    临界温度(ºC):不确定

15.    临界压力(KPa):不确定

16.    油水(辛醇/水)分配系数的对数值:不确定

17.    爆炸上限(%,V/V):不确定

18.    爆炸下限(%,V/V):不确定

19.    溶解性:与水反应。

乙酸钪 安全信息

危险标志:
Xi: Irritant;

乙酸钪 毒理性

生态数据:

该物质对环境可能有危害,对水体应给予特别注意

乙酸钪 MSDS

Name: Scandium(III)Acetate Hydrate 99.9% Material Safety Data Sheet
Synonym: None
CAS: 3804-23-7
Section 1 - Chemical Product   MSDS Name:Scandium(III)Acetate Hydrate 99.9% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
3804-23-7 Scandium(III)Acetate Hydrate 99.9% 223-274-5
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 3804-23-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white crystalline
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C6H9O6Sc.XH2O
Molecular Weight: 222.09

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 3804-23-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Scandium(III)Acetate Hydrate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3804-23-7: No information available.
Canada
CAS# 3804-23-7 is listed on Canada's NDSL List.
CAS# 3804-23-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3804-23-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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