氯化锡(五水)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

氯化锡(五水) 基本信息

中文名称:
氯化锡(五水) 
中文别名:
结晶四氯化锡;
四氯化锡五水合物 
英文名称:
Stannane, tetrachloro-,hydrate (1:5)
英文别名:
Stannic chloride pentahydrate;
Tin(IV) chloride pentahydrate;
tetrachlorostannane,pentahydrate 
CAS No.:
10026-06-9
分 子 式:

Cl4Sn.5H2O

分 子 量:
350.58
精确分子量:
349.83000
PSA:
46.15000
MDL:
MFCD00149864
EINECS:
231-588-9
InChI:
InChI=1/4ClH.5H2O.Sn/h4*1H;5*1H2;/q;;;;;;;;;+4/p-4
危险品标志:

CorrosiveC

风险术语:

R34;R52/53

安全术语:
S26;S45;S61;S36/37/39
分子结构式:
SDS:
查看

氯化锡(五水) 制备方法及用途

制备方法

用作分析试剂和媒染剂

合成制备方法

1.由无水四氯化锡缓慢地加入到水中,得到的热溶液在搅拌下冷却结晶制得。或者将氯气通入二氯化锡溶液中至饱和,加热蒸发,再冷却结晶,分离制得。

2.向33mL水中分次少量地逐渐加入100g无水氯化锡,溶解时剧烈放热,所得透明液体在搅拌和冷却下即可全部结晶。产量100~103g,产率约85%。

3.将干燥的氯气通到装有金属锡粒的带有冷凝器的容器底部,进行反应:

反应比较激烈,放出的热量使四氯化锡发进入冷凝器,待反应结束后,将四氯化锡倒回反应器,密封静置1h,让过量锡与游离氯结合,然后将溶液蒸馏,收集112~114℃馏分,得无水四氯化锡。在搅拌下将所得四氯化锡溶解到适当蒸馏水中 (100g四氯化锡用33ml水) ,溶解时大量放热,待透明热溶液冷却至完全结晶,即为结晶四氯化锡。

用途简介

用途

1.分析试剂、印染的媒染剂。也用于有机合成、电子工业等。

2.用于薄层分析法测定三萜类、类固醇类和酚类等。电子工业中用于镀锡。还用作有机合成脱水剂,织物媒染剂。

氯化锡(五水) 物化性质

外观与性状:
白色至黄色固体
熔点:
56 °C
沸点:
114.1ºC at 760 mmHg
水溶解性:
soluble
蒸汽压:
23.9mmHg at 25°C
存储条件/存储方法:
库房通风低温干燥,与碱分开存放
稳定性相关:

 

其它信息:

1.       性状:白色或微黄色结晶或熔块。微有盐酸气味

2.       密度(g/mL,25℃):2.04

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):56

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,20ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:吸湿性强。易溶于水,溶于乙醇。

氯化锡(五水) 安全信息

包装等级:
III
风险类别:
8
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R34;R52/53
安全说明:
S26-S36/37/39-S45-S7/8-S61
RTECS号:
XP8870000
危险标志:
C: Corrosive;

氯化锡(五水) 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XP8870000
CAS REGISTRY NUMBER :
10026-06-9
LAST UPDATED :
199712
DATA ITEMS CITED :
24
MOLECULAR FORMULA :
Cl4-Sn.5H2-O
MOLECULAR WEIGHT :
350.59
WISWESSER LINE NOTATION :
.SN-G4.QH5

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
120 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
32 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
2 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 282,61,1992 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 2 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,257,1971 OSHA PEL (Gen Indu):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Sn)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Sn)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Sn)/m3 JAN 1993 OEL-FINLAND:TWA 2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 2 mg(Sn)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(Sn)/m3;STEL 2 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Sn)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2 mg(Sn)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Sn)/m3;STEL 4 mg(Sn)/m3 JAN 1993 OEL-THAILAND:TWA 2 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Sn)/m3;STEL 10 mg(Sn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9720 No. of Facilities: 18 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 108 (estimated) No. of Female Employees: 72 (estimated)
毒理学数据:

1、急性毒性:大鼠腹腔LD50:120mg/kg;小鼠注射LC50:32mg/kg;眼睛及皮肤接触后引起灼伤,吸入会刺激咽喉、支气管,引起咳嗽及呼吸困难,重复暴露,X光胸部透视出现异常。

氯化锡(五水) MSDS


Section 1: Product Identification
   Chemical Name:       Tin (IV) chloride pentahydrate, 98%    
   CAS Registry Number:       10026-06-9    
   Formula:       SnCl4.5H2O    
   EINECS Number:       231-588-9    
   Chemical Family:       metal halide    
   Synonym:       Stannic chloride pentahydrate, Tetrachlorostannane pentahydrate, Tin tetrachloride dihydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       10026-06-9       100%       2mg/m3       2mg/m3    

Section 3: Hazards Identification
   Emergency Overview:       May be harmful by inhalation. Corrosive to skin and eyes.    
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust.    
   Eye Contact:       Corrosive to the eyes.    
   Skin Contact:       Causes burns to the skin.    
   May be harmful by inhalation. Forms hydrogen chloride when heated. Inhalation can lead to chemical burns to
   Inhalation:
   the respiratory tract.
   Ingestion:       No information is available on the acute physiological effects of ingestion.    
   Corrosive to skin, eyes and respiratory tract and causes eye, skin burns, dyspnea (breathing difficulty), and
   Acute Health Affects:
   pulmonary edema
   Chronic Health Affects:       Prolonged exposure to dust of tin compounds may result in benign pneumoconiosis.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       None. Material is non-flammable.    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic fumes of hydrogen chloride.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
   Spill and Leak Procedures:
   inert material and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store solid in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Solid may form a fine dust. If possible, handle the solid in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Solid may form a fine dust. If possible, handle the solid in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       off-white lumps    
   Molecular Weight:       260.50 (350.61)    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals    
   Decomposition Products:       water, metal oxychloride, metal oxide, and hydrogen chloride    

SECTION 11: Toxicological Information
   Intraperitoneal (rat); LD50: 120 mg/kg. Intravenous (mouse); LD50: 32 mg/kg. Human Lymphocyte;
   RTECS Data:
   Cytogenetic analysis: 2 mg/L. Human Lymphocyte; Sister chromatid exchange: 2 mg/L.
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       Negative data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Stannic chloride, pentahydrate    
   Hazard Class (CFR):       8    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       III    
   UN ID Number (CFR):       UN# 2440    
   Shipping Name (IATA):       Stannic chloride, pentahydrate    
   Hazard Class (IATA):       8    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       III    
   UN ID Number (IATA):       UN# 2440    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

氯化锡(五水) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:349.830433 Da

8、标称质量:350 Da

9、平均质量:350.5984 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:5

3.氢键受体数量:5

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积5

7.重原子数量:10

8.表面电荷:0

9.复杂度:19.1

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:6

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产品介绍:
产品名称:五水四氯化锡 Cas号:10026-06-9 纯度:0-99% 包装信息:25kg,200kg 价格:洽谈
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