四羟基苯醌; 四羟基-1,4-苯二酮

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

四羟基苯醌; 四羟基-1,4-苯二酮 基本信息

中文名称:
四羟基苯醌; 四羟基-1,4-苯二酮 
中文别名:
四羟基苯醌;
2,3,5,6-四羟基-2,5-环已二烯-1,4-二酮;
四羟基-1,4-苯二酮;
四氧醌;
四氢-P-苯醌 
英文名称:
2,5-Cyclohexadiene-1,4-dione,2,3,5,6-tetrahydroxy-
英文别名:
Tetrahydroxyquinone;
2,3,5,6-tetrahydroxybenzoquinone;
Tetroquinone monohydrate;
tetrahydroxy-p-benzoquinone;
2,3,5,6-TETRAHYDROXY-1,4-BENZOQUINONE;
Tetrahydroxy-p-quinone;
Kelox;
HPEK-1;
tetrahydroxy-1,4-benzoquinone;
Terasin;
TETRAHYDROXY-1,4-QUINONE;
TETRAHYDROXY BENZOQUINONE;
2,3,5,6-tetrahydroxo-1,4-benzoquinone;
2,3,5,6-tetrahydroxy-1,4-benzoquinone;
TETROQUINONE 
CAS No.:
319-89-1
分 子 式:
C6H4O6
分 子 量:
172.09
精确分子量:
172.00100
PSA:
115.06000
EINECS:
206-275-5
InChI:
The Key: DGQOCLATAPFASR-UHFFFAOYSA-N
危险品标志:
风险术语:
R36/37/38   
安全术语:
S26;S36
分子结构式:
SDS:
查看

四羟基苯醌; 四羟基-1,4-苯二酮 物化性质

外观与性状:
固体。
密度:
0.79
熔点:
300ºC
沸点:
148 °C / 15mmHg
折射率:
2.023
其它信息:

一、物性数据

性状:不可用

密度(g/mL,25/4): 不可用

相对蒸汽密度(g/mL,空气=1)不可用

熔点(ºC):不可用

沸点(ºC,常压):不可用

沸点(ºC,5.2kPa): 不可用

折射率: 不可用

闪点(ºC): 不可用

比旋光度(º): 不可用

自燃点或引燃温度(ºC): 不可用

蒸气压(kPa,25ºC): 不可用

饱和蒸气压(kPa,60ºC): 不可用

燃烧热(KJ/mol):不可用

临界温度(ºC): 不可用

临界压力(KPa): 不可用

油水(辛醇/水)分配系数的对数值:不可用 

爆炸上限(%,V/V):不可用

爆炸下限(%,V/V): 不可用

溶解性:不可用

四羟基苯醌; 四羟基-1,4-苯二酮 安全信息

海关代码:
2914690090
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R36/37/38
安全说明:
S26-S36
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
危险标志:
Xi: Irritant;

四羟基苯醌; 四羟基-1,4-苯二酮 毒理性

毒理学数据:

二、毒理学数据:

急性毒性:不可用 。

生态数据:

三、生态学数据:

1、其它有害作用:该物质对环境可能有危害,对水体应给予特别注意。

四羟基苯醌; 四羟基-1,4-苯二酮 MSDS

Name: Tetrahydroxy-P-Quinone Monohydrate 99% (Titr.) Material Safety Data Sheet
Synonym: Tetrahydroxy-P-Benzoquinone; Tetroquinon
CAS: 319-89-1
Section 1 - Chemical Product   MSDS Name:Tetrahydroxy-P-Quinone Monohydrate 99% (Titr.) Material Safety Data Sheet
Synonym:Tetrahydroxy-P-Benzoquinone; Tetroquinon

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
319-89-1 Tetrahydroxyquinone 99 206-275-5
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Dust is irritating to the respiratory tract. May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Wash clothing before reuse. Flush skin with plenty of soap and water.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 319-89-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: black
Odor: penetrating odor
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not applicable.
Boiling Point: Not available.
Freezing/Melting Point: 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in cold water
Specific Gravity/Density: Not available.
Molecular Formula: C6H4O6.H2O
Molecular Weight: 172.0244

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 319-89-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetrahydroxyquinone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 319-89-1: No information available.
Canada
CAS# 319-89-1 is listed on Canada's DSL List.
CAS# 319-89-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 319-89-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

四羟基苯醌; 四羟基-1,4-苯二酮 海关数据

中国海关编码:2914690090

概述:
2914690090 其他醌. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
摘要/Summary:
2914690090 other quinones。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

四羟基苯醌; 四羟基-1,4-苯二酮 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:33.48

2、   摩尔体积(m3/mol):65.9

3、   等张比容(90.2K):279.3

4、   表面张力(dyne/cm):321.9

5、   极化率10-24cm3):13.27

计算化学数据

1.疏水参数计算参考值(XlogP):-0.6

2.氢键供体数量:4

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:7

6.拓扑分子极性表面积115

7.重原子数量:12

8.表面电荷:0

9.复杂度:272

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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