乙酰丙酮镨(III)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS
  • 结构与计算化学

乙酰丙酮镨(III) 基本信息

中文名称:
乙酰丙酮镨(III) 
中文别名:
乙酰丙酮镨(III);
乙酰丙酮镨水合物;
乙酰丙酮化镨N水合物 
英文名称:
Praseodymium,tris(2,4-pentanedionato-kO2,kO4)-, (OC-6-11)-
英文别名:
PRASEODYMIUM(III) ACETYLACETONATE HYDRATE;
Tris-(2,4-pentanedionato)-praseodymium;
PRASEODYMIUM ACETYL ACETONATE;
PRASEODYMIUM ACETYLACETONATE HYDRATE;
PRASEODYMIUM 2,4-PENTANEDIONATE;
PRASEODYMIUM(III) ACETYLACETONATE;
Praseodymium (III) 2,4-pentanedionate 
CAS No.:
14553-09-4
分 子 式:
C15H21O6Pr
分 子 量:
438.23
精确分子量:
310.14200
PSA:
78.90000
EINECS:
238-600-1
风险术语:
20/21/22-36/37/38-63
分子结构式:
SDS:
查看

乙酰丙酮镨(III) 制备方法及用途

制备方法

制法同乙酰丙酮镝。称取5.47g氧化镨溶于尽量少的稀盐酸,加入稀氨水调整溶液pH值为5.0。称取按计算量过量50%的新蒸乙酰丙酮,加入浓氨水和水制成乙酰丙酮氨溶液,搅拌下,将此溶液加入到氯化镨溶液中,保持溶液的pH值为6.5。反应混合液搅拌12h,得到乙酰丙酮镨晶体。过滤、干燥操作同乙酰丙酮镝,收率为90%。

合成制备方法

制法同乙酰丙酮镝。称取5.47g氧化镨溶于尽量少的稀盐酸,加入稀氨水调整溶液pH值为5.0。称取按计算量过量50%的新蒸乙酰丙酮,加入浓氨水和水制成乙酰丙酮氨溶液,搅拌下,将此溶液加入到氯化镨溶液中,保持溶液的pH值为6.5。反应混合液搅拌12h,得到乙酰丙酮镨晶体。过滤、干燥操作同乙酰丙酮镝,收率为90%。

用途简介

乙酰丙酮镨(III) 物化性质

熔点:
130ºC (dec.)(lit.)
沸点:
138.4ºC at 760mmHg
闪点:
43.1ºC
蒸汽压:
0.174mmHg at 25°C
稳定性相关:

溶于二硫化碳、乙酰丙酮。

其它信息:

1.       性状:绿色晶体,对湿汽敏感,易潮解。

2.       密度(g/mL,25/4℃):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):146

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

乙酰丙酮镨(III) 安全信息

危险类别码:
R20/21/22
安全说明:
26-36
危险标志:
Xn: Harmful;

乙酰丙酮镨(III) MSDS


Section 1: Product Identification
   Chemical Name:       Praseodymium (III) acetylacetonate hydrate (99.9%-Pr) (REO)    
   CAS Registry Number:       14553-09-4    
   Formula:       Pr(CH3COCHCOCH3)3.XH2O    
   EINECS Number:       none    
   Chemical Family:       metal beta-diketonate complexes    
   Synonym:       Tris(2,4-pentanedionato)praseodymium (III) hydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       14553-09-4       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, Inhalation of dust.    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the respiratory tract, skin and eyes.    
   Ingestion:       No information on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Ingestion:       Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).    

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a sealed container. Keep away from heat and moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       pale green powder    
   Molecular Weight:       438.23    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       halogens and oxidizing agents    
   Decomposition Products:       Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

乙酰丙酮镨(III) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:438.041413 Da

8、标称质量:438 Da

9、平均质量:438.2313 Da

计算化学数据

1、   氢键供体数量:0

2、   氢键受体数量:6

3、   可旋转化学键数量:3

4、   互变异构体数量:35

5、   拓扑分子极性表面积(TPSA):120

6、   重原子数量:22

7、   表面电荷:0

8、   复杂度:90.4

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:3

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:4

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