活性艳红X-3B

基本信息
制备方法及用途
物化性质
安全信息
毒理性

活性艳红X-3B 基本信息

中文名称：: 活性艳红X-3B

中文别名：: 活性红2;
活性红 2

英文名称：: 2,7-Naphthalenedisulfonicacid,5-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-hydroxy-3-(2-phenyldiazenyl)-,sodium salt (1:2)

英文别名：: 2,7-Naphthalenedisulfonic acid, 5-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-hydroxy-3-(2-phenyldiazenyl)-, sodium salt (1:2);
2,7-Naphthalenedisulfonic acid, 5-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-hydroxy-3-(phenylazo)-, disodium salt (9CI);
2,7-Naphthalenedisulfonic acid, 5-[(4,6-dichloro-s-triazin-2-yl)amino]-4-hydroxy-3-(phenylazo)-, disodium salt (7CI,8CI);
5-(4,6-Dichloro-s-triazinyl-2-amino)-4-hydroxy-3-(phenylazo)-2,7-naphthalenedisulfonic acid disodium salt;
Basilen Red M 5B;
Brilliant Red 5SKh;
Brilliant Red X 3B;
C.I. 18200;
C.I. Reactive Red 2;
Chemictive Brilliant Red 5B;
Helaktyn Red F 5B;
Intracron Red C 5B;
Mikacion Brilliant Red 5BS;
Orbaktiv Brilliant Red M 5B;
Ostazin Brilliant Red S 5B;
Ostazin Red S 5B;
Procion Brilliant Red 5B;
Procion Brilliant Red 5BS;
Procion Brilliant Red M 5B;
Procion Brilliant Red MX 5B;
Procion Red 5CX;
Procion Red 5MX;
Procion Red M 5B;
Procion Red MX 5B;
Reactive Bright Red X 3B;
Reactive Brilliant Red;
Reactive Brilliant Red (Chinese);
Reactive Brilliant Red 5SKh;
Reactive Brilliant Red MX 5B;
Reactive Brilliant Red X 3B;
Reactive Red 2;
Reactive Red 5SKh;
Reactive Red B 5A;
Reactive Red M 5B;
Reactive Red X 3B;
Reactofix Brilliant Red M 5B;
Reactofix Red M 5B;
Red M 5B;
Remazol Red 5BS;
Remazol brilliant red

CAS No.：: 17804-49-8

分子式：: C₁₉H₁₂Cl₂N₆O₇S₂.2Na

分子量：: 615.33

精确分子量：: 615.93814

PSA：: 226.81000

MDL：: MFCD00067094

EINECS：: 241-776-2

危险品标志：

风险术语：

安全术语：

分子结构式：

SDS：: 查看

活性艳红X-3B 制备方法及用途

制备方法

以苯胺、H 酸、三聚氯氰为原料,首先将 H 酸与三聚氯氰缩合,然后将苯胺重氮化,与前述缩合产物偶合,经盐析、过滤、干燥得成品。。在溶解锅中加入水、H 酸及纯碱,搅拌使其溶解。在缩合锅中加水和三聚氯氰,搅拌加冰降温至 5℃,从溶解锅放入已溶解好的 H 酸溶液,同时加入冰和纯碱,维持 0-5℃,弱碱性,搅拌至反应完全。在重氮化锅中加入水和盐酸,搅拌下加入苯胺,加冰降温至 0℃,加入亚硝酸钠溶液,搅拌维持此温度至反应终点。偶合:将缩合锅中物料经布袋过滤器放入偶合锅中,开动搅拌于 0-2℃加入苯胺重氮盐溶液,同时加入纯碱溶液,以加速偶合反应,至反应完全时 pH 值为 6.8-7。盐析:往偶合锅加入食盐、尿素进行盐析,经过滤,滤饼放入捏合机中与无水磷酸氢二钠、无水磷酸氢二钾混合均匀。混合物于 85℃经真空干燥。再经粉碎,在拼混机中与元明粉拼混为成品。

合成制备方法

以苯胺、H 酸、三聚氯氰为原料，首先将 H 酸与三聚氯氰缩合，然后将苯胺重氮化，与前述缩合产物偶合，经盐析、过滤、干燥得成品。。

在溶解锅中加入水、H 酸及纯碱，搅拌使其溶解。在缩合锅中加水和三聚氯氰，搅拌加冰降温至 5℃，从溶解锅放入已溶解好的 H 酸溶液，同时加入冰和纯碱，维持 0-5℃，弱碱性，搅拌至反应完全。

在重氮化锅中加入水和盐酸，搅拌下加入苯胺，加冰降温至 0℃，加入亚硝酸钠溶液，搅拌维持此温度至反应终点。

偶合：将缩合锅中物料经布袋过滤器放入偶合锅中，开动搅拌于 0-2℃加入苯胺重氮盐溶液，同时加入纯碱溶液，以加速偶合反应，至反应完全时 pH 值为 6.8-7。

盐析：往偶合锅加入食盐、尿素进行盐析，经过滤，滤饼放入捏合机中与无水磷酸氢二钠、无水磷酸氢二钾混合均匀。混合物于 85℃经真空干燥。再经粉碎，在拼混机中与元明粉拼混为成品

用途简介

用于棉、丝、毛和人造丝等织物的染色

用途

活性艳红 X-3B 主要用于棉、黏胶纤维绞纱和织物的染色，亲和力中等，染物为蓝光红色，鲜艳度优良。易于水解，染浴一般用 30-40℃。可染单色，也可拼色，拼色时常用活性黄 X-6G、活性橙 X-GN 或活性艳橙 X-7R 等拼染各种红色，或者与活性金黄 X-G、活性蓝 X-R 组成三原色，拼染各种中、深色泽。一般不用于棉、黏胶纤维织物的印花，可用于丝绸的直接印花，涤/棉混纺布、针织布、棉、丝、毛和人造丝等织物的二浴法染色。

活性艳红X-3B 物化性质

密度：: 1.88g/cm3
熔点：: >300ºC(lit.)
存储条件/存储方法：: 密闭、阴凉、干燥处
稳定性相关：: 按规定使用不会分解，避氧化剂
其它信息：: 1.       性状：枣红色粉末

2.       密度（g/mL,25℃）：未确定

3.       相对蒸汽密度（g/mL,空气=1）：未确定

4.       熔点（ºC）：＞300

5.       沸点（ºC,常压）：未确定

6.       沸点（ºC,1hPa）：未确定

7.       折射率：未确定

8.       闪点（ºF）：未确定

9.       比旋光度（º）：未确定

10.    自燃点或引燃温度（ºC）：未确定

11.    蒸气压（21.1ºC，atm）：未确定

12.    饱和蒸气压（kPa,60ºC）：未确定

13.    燃烧热（KJ/mol）：未确定

14.    临界温度（ºC）：未确定

15.    临界压力（KPa）：未确定

16.    油水（辛醇/水）分配系数的对数值：未确定

17.    爆炸上限（%,V/V）：未确定

18.    爆炸下限（%,V/V）：未确定

19.    溶解性：在水中溶解度 (20℃) 为 80g/L，(50℃) 为 110g/L。水溶液呈蓝光红色，加 1mol/

活性艳红X-3B 安全信息

危险类别码：: 36-42/43
安全标志：: S22:不要吸入粉尘。
S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适，立刻到医生那里寻求帮助（最好带去产品容器标签）。
:
危险标志：: Xn: Harmful;

活性艳红X-3B 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QJ6416000

CHEMICAL NAME :: 2,7-Naphthalenedisulfonic acid, 5-((4,6-dichloro-s-triazin-2-yl)amino)-4-hydroxy-3- (phenylazo)-, disodium salt

CAS REGISTRY NUMBER :: 17804-49-8

LAST UPDATED :: 199710

DATA ITEMS CITED :: 13

MOLECULAR FORMULA :: C19-H10-Cl2-N6-O7-S2.2Na

MOLECULAR WEIGHT :: 615.35

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1300,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7460 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1300,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1300,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1300,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 2100 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - rigidity (including catalepsy) Behavioral - muscle contraction or spasticity

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 10(4),25,1966 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 49980 mg/kg/9W-I

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Liver - changes in liver weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(2),88,1985

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 100 mg/m3/4H/17W-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Related to Chronic Data - death

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 10(4),25,1966

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 2940 mg/kg/14D-I

TOXIC EFFECTS :: Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Blood - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 10(4),25,1966 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - T0834 No. of Facilities: 10 (estimated) No. of Industries: 1 No. of Occupations: 4 No. of Employees: 1214 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T0834 No. of Facilities: 247 (estimated) No. of Industries: 8 No. of Occupations: 8 No. of Employees: 14270 (estimated) No. of Female Employees: 6114 (estimated)