碳酸氢三钠

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • MSDS
  • 结构与计算化学

碳酸氢三钠 基本信息

中文名称:
碳酸氢三钠 
中文别名:
碳酸氢三钠;
碳酸钠盐(2:3);
倍半碳酸钠 
英文名称:
Carbonic acid, sodiumsalt (2:3)
英文别名:
SODIUM SESQUICARBONATE DIHYDRATE;
urao;
snowflakecrystals;
trisodiumhydrogendicarbonate;
KANWA;
magadisoda;
Carbonicacid,sodiumsalt(2:3);
SODIUM SESQUICARBONATE 2H2O;
sq810;
SODIUM CARBONATE,SESQUIOXIDE;
TRONADUST 
CAS No.:
533-96-0
分 子 式:

CH2O3.3/2Na

分 子 量:
226.03
精确分子量:
189.94700
PSA:
123.55000
EINECS:
208-580-9
InChI:
InChI=1/2CH2O3.3Na.3H/c2*2-1(3)4;;;;;;/h2*(H2,2,3,4);;;;;;/p-4/r2CH2O3.3HNa/c2*2-1(3)4;;;/h2*(H2,2,3,4);3*1H/p-4
危险品标志:

 

风险术语:

 

安全术语:

 

分子结构式:
SDS:
查看

碳酸氢三钠 制备方法及用途

制备方法

由等摩尔的碳酸钠和碳酸氢钠溶于水后再结晶而得。

合成制备方法

1.由等摩尔的碳酸钠和碳酸氢钠溶于水后再结晶而得。

用途简介

用于水处理及生产洗涤剂、去污剂等

用途

1.作缓冲剂和中和剂,可用于羊奶、乳制品、饼干和糕点,按生产需要适量使用。

2.用作碱性剂、缓冲剂及乳制品中和剂。主要用于稀释奶油和禽类(烫毛)。 

碳酸氢三钠 物化性质

密度:
2.112
稳定性相关:

白色针状晶体、片状或结晶性粉末。相对密度2.112。易溶于水及酸,水溶液呈碱性,较碳酸钠弱。

其它信息:

1.性状: 白色针状或片状结晶或结晶性粉末

2.相对密度(20℃/4℃):2.112

3.溶解性:易溶于水及酸,水溶液呈强碱性,但较碳酸钠弱。

碳酸氢三钠 MSDS


Section 1. Chemical Product and Company Identification
    Sodium sesquicarbonate        Catalog    
    Common Name/
    Number(s).
    Trade Name
    CAS#        533-96-0    
    Manufacturer
    RTECS        FG2092000    
    SPECTRUM CHEMICAL MFG. CORP.
    TSCA        TSCA 8(b) inventory: Sodium    
    sesquicarbonate
    Commercial Name(s)        Not available.    
    CI# Not available.
    Synonym        Not available.    
    IN CASE OF EMERGENCY
    Chemical Name
    Chemical Family        Not available.        CALL (310) 516-8000    
    C2HNa3O6.2H2O
    Chemical Formula
    SPECTRUM CHEMICAL MFG. CORP.

Section 2.Composition and Information on Ingredients
    Exposure Limits
    TWA (mg/m3)        STEL (mg/m3) CEIL (mg/m3)    
    Name        CAS #        % by Weight    
    1) Sodium sesquicarbonate        533-96-0        100    
    Toxicological Data        Sodium sesquicarbonate    
    on Ingredients        LD50: Not available.    
    LC50: Not available.

Section 3. Hazards Identification
    Potential Acute Health Effects Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of eye contact
    (irritant). Slightly hazardous in case of skin contact (corrosive).
    Potential Chronic Health        CARCINOGENIC EFFECTS: Not available.    
    Effects        MUTAGENIC EFFECTS: Not available.    
    TERATOGENIC EFFECTS: Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged exposure is not known to aggravate medical condition.
    Sodium sesquicarbonate

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.    
    Skin Contact        After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin    
    with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.
    Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical    
    attention.
    Inhalation        Allow the victim to rest in a well ventilated area. Seek immediate medical attention.    
    Serious Inhalation        Not available.    
    Ingestion        Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not    
    breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
    Serious Ingestion
    Not available.

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Not applicable.
    Flash Points
    Not applicable.
    Flammable Limits
    Products of Combustion        Not available.    
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Not available.
    Special Remarks on
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill        Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water    
    on the contaminated surface and allow to evacuate through the sanitary system.
    Sodium sesquicarbonate

Section 7. Handling and Storage
    Precautions        Keep container dry. Do not breathe dust. Never add water to this product In case of insufficient ventilation, wear    
    suitable respiratory equipment If you feel unwell, seek medical attention and show the label when possible. Avoid
    contact with skin and eyes
    Storage        No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be    
    sure that it is not necessary to strain to reach materials, and that shelves are not overloaded.

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.    
    Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid.        Odor        Not available.    
    Taste        Not available.    
    Molecular Weight        226.03 g/mole    
    Color        Not available.    
    pH (1% soln/water)        Not available.    
    Not available.
    Boiling Point
    Melting Point        Decomposes.    
    Not available.
    Critical Temperature
    Specific Gravity        2.112 (Water = 1)    
    Vapor Pressure        Not applicable.    
    Vapor Density        Not available.    
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        Not available.    
    Ionicity (in Water)        Not available.    
    Dispersion Properties        Not available.    
    Solubility        Not available.    

Section 10. Stability and Reactivity Data
    The product is stable.
    Stability
    Instability Temperature        Not available.    
    Conditions of Instability        Not available.    
    Not available.
    Incompatibility with various
    substances
    Non-corrosive in presence of glass.
    Corrosivity
    Sodium sesquicarbonate
    Not available.
    Special Remarks on
    Reactivity
    Not available.
    Special Remarks on
    Corrosivity
    Polymerization        No.    

Section 11. Toxicological Information
    Routes of Entry        Eye contact. Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans Not available.
    Other Toxic Effects on
    Very hazardous in case of skin contact (irritant), of ingestion, of inhalation.
    Humans        Slightly hazardous in case of skin contact (corrosive).    
    Special Remarks on
    Not available.
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Not available.    
    Toxic Effects on Humans

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    Not available.
    BOD5 and COD
    Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    Products of Biodegradation
    arise.
    Toxicity of the Products        The products of degradation are more toxic.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Identification        Not applicable.    
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)
    Sodium sesquicarbonate

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Sodium sesquicarbonate
    Federal and State
    Regulations
    California
    Proposition 65
    Warnings
    Other Regulations        OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).    
    WHMIS (Canada) CLASS D-2B: Material causing other toxic effects (TOXIC).
    Other Classifications
    DSCL (EEC)        R36/38- Irritating to eyes and skin.    
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    2 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent. Wear appropriate respirator
    when ventilation is inadequate.
    Splash goggles.


SECTION 16 - ADDITIONAL INFORMATION
N/A

碳酸氢三钠 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:1

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积124

7.重原子数量:11

8.表面电荷:0

9.复杂度:43.5

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:5

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