四(乙酰氧基汞)甲烷

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

四(乙酰氧基汞)甲烷 基本信息

中文名称:
四(乙酰氧基汞)甲烷 
中文别名:
四(乙酰氧基汞)甲烷 
英文名称:
Mercury,tetrakis(acetato-kO)-m4-methanetetrayltetra- (9CI)
英文别名:
acetyloxy-[tris(acetyloxymercurio)methyl]mercury;
TAMM 
CAS No.:
25201-30-3
分 子 式:
C9H12Hg4O8
分 子 量:
1050.55
精确分子量:
1055.94000
PSA:
105.20000
InChI:
The Key: FUFKDCOYEVSHMN-UHFFFAOYSA-J
风险术语:
R33R26/27/28
安全术语:
S13S28S45
分子结构式:
SDS:
查看

四(乙酰氧基汞)甲烷 物化性质

熔点:
255-275ºC (dec.)
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):255-275

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

四(乙酰氧基汞)甲烷 安全信息

安全说明:
S13-S28-S45
安全标志:
S13:远离食品、饮料和动物饲料。
S28:接触皮肤之后,立即使用大量皂液洗涤。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。

四(乙酰氧基汞)甲烷 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

四(乙酰氧基汞)甲烷 MSDS


Section 1: Product Identification
   Chemical Name:       Tetrakis(acetoxymercuri)methane, min. 95%    
   CAS Registry Number:       25201-30-3    
   Formula:       C(HgOOCCH3)4    
   EINECS Number:       none    
   Chemical Family:       organomercury compound    
   Synonym:       Carbon tetra(acetoxymercuride)    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       25201-30-3       100%       0.01mg/m3 (Hg)       1mg/10m3 (Hg)    

Section 3: Hazards Identification
   Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Prolonged exposure
   Emergency Overview:
   may permanently degrade the central nervous system.
   Primary Routes of Exposure:       Ingestion, skin, Inhalation of dust.    
   Eye Contact:       May cause mild to severe irritation of the eyes. May deposit mercury in the lens of the eye.    
   Skin Contact:       May cause mild to severe irritation of the skin. May be absorbed through the skin.    
   Dust may cause severe respiratory and gastrointestinal distress, and may damage the central nervous
   Inhalation:
   system.
   Ingestion:       May cause lack of appetite, abdominal cramps, vomiting, kidney failure and paralysis.    
   Poison. Stomach upset and pain, mouth pain, vomiting, excessive salivation, urine production stops, urine
   Acute Health Affects:
   products appear in the blood, ataxia (difficulty in moving).
   The chronic effects of mercury poisoning include stomatitis, tremors, psychic disturbances, excessive
   Chronic Health Affects:       salivation, dermatitis, and pain on chewing. Other effects include loss of memory, insomnia, lack of    
   confidence, irritability and depression, speech and gait impairment.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       dry chemical, carbon dioxide, water, or foam.    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic mercury fumes and carbon monoxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store solid in a tightly sealed container in a cool dry place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Material may form a toxic fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a toxic fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       1050.55    
   Melting Point:       255-275° dec.    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       azides, fulminates and reducing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, and toxic mercury fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no information available    
   Mutagenic Effects:       no information available    
   Tetratogenic Effects:       no information available    

SECTION 12: Ecological Information
   Avoid release to the environment. Very toxic to aquatic organisms. May cause long-term adverse effects in the
   Ecological Information:
   aquatic environment.

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Mercury compounds, solid, N.O.S.    
   Hazard Class (CFR):       6.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 2025    
   Shipping Name (IATA):       Mercury compound, solid, N.O.S.    
   Hazard Class (IATA):       6.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 2025    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See Category Code N458 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

四(乙酰氧基汞)甲烷 分子结构与计算化学数据

分子结构数据

1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:8

4.可旋转化学键数量:12

5.互变异构体数量:无

6.拓扑分子极性表面积105

7.重原子数量:21

8.表面电荷:0

9.复杂度:335

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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