2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 表征图谱

2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物 基本信息

中文名称:
2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物 
中文别名:
2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物;
新亚铜试剂;
2,9-二甲基-1,10-菲啰啉盐酸盐二水;
2,9-二甲基-1,10-菲啉盐酸盐;
2,9-二甲基-1,10-菲啉盐酸盐二水;
2,9-二甲基-1,10-菲咯啉盐酸盐 
英文名称:
1,10-Phenanthroline,2,9-dimethyl-, hydrochloride (1:1)
英文别名:
NEOCUPROINE HYDROCHLORIDE;
2,9-dimethoxyquinacridone;
2,9-dimethylquinacridone;
2,9-Dimethoxy-5,12-dihydroquino[2,3-b]acridine-7,14-dione;
2,9-dimethyl-1,10-phenanthroline hydrochloride 
CAS No.:
7296-20-0
分 子 式:
C14H12N2.ClH
分 子 量:
244.72
精确分子量:
343.25100
PSA:
38.33000
MDL:
MFCD00150062
EINECS:
230-732-8
BRN:
4584190
InChI:
The Key: QUGBNSJLQDNNPK-UHFFFAOYSA-N
危险品标志:
Xi
风险术语:
R36/37/38
安全术语:
S24/25;
分子结构式:
SDS:
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2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物 物化性质

外观与性状:
固体
密度:
1.178g/cm3
熔点:
250ºC
沸点:
367.4ºC at 760 mmHg
闪点:
159.7ºC
存储条件/存储方法:

密封储存于阴凉干燥环境。

 

稳定性相关:

 如果遵照规格使用和储存则不会分解。

 

其它信息:

1.       性状:黄色

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物 安全信息

危险类别码:
36/37/38
安全说明:
S24/25
危险标志:
Xi

2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物 毒理性

生态数据:

该物质对环境可能有危害,对水体应给予特别注意。

2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物 MSDS

Name: Neocuproine hydrochloride monohydrate 99% Material Safety Data Sheet
Synonym: 2,9-Dimethyl-1,10-phenanthroline hydrochloride monohydrat
CAS: 7296-20-0
Section 1 - Chemical Product   MSDS Name:Neocuproine hydrochloride monohydrate 99% Material Safety Data Sheet
Synonym:2,9-Dimethyl-1,10-phenanthroline hydrochloride monohydrat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7296-20-0 Neocuproine hydrochloride monohydrate, 98% 230-732-8
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.Light sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated. Expected to be a low ingestion hazard.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Store protected from light.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 7296-20-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 250 deg C dec
Autoignition Temperature: Not available.
Flash Point: 250 deg C ( 482.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 250 deg C
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H12N2.HCl.H2O
Molecular Weight: 262.75

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 7296-20-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Neocuproine hydrochloride monohydrate, 98% - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7296-20-0: No information available.
Canada
CAS# 7296-20-0 is listed on Canada's DSL List.
CAS# 7296-20-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7296-20-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物 分子结构与计算化学数据

分子结构数据

1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   偶极距(10-24cm3):无此用

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:1

3.氢键受体数量:2

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积25.8

7.重原子数量:17

8.表面电荷:0

9.复杂度:227

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

2,9-二甲基-1,10-邻二氮杂菲盐酸盐一水化物 表征图谱

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