2-氟-6-(4-氟代苄氧基)苄腈

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

2-氟-6-(4-氟代苄氧基)苄腈 基本信息

中文名称:
2-氟-6-(4-氟代苄氧基)苄腈 
中文别名:
2-氟-6-(4-氯苄氧基)苯甲腈;
2-Fluoro-6-(4-Chlorobenzyloxy)Benzonitrile 2-[(4-Chlorobenzyl)Oxy]-6-Fluorobenzonitrile 2-Fluoro-6-(4-chlorobenzyloxy)benzonitrile 97% 2-Fluoro-6-(4-chlorobenzyloxy)benzonitrile97% 6-(4-Chlorobenzyloxy)-2-Fluorobenzonitrile 
英文名称:
Benzonitrile,2-[(4-chlorophenyl)methoxy]-6-fluoro-
英文别名:
2-[(4-chlorophenyl)methoxy]-6-fluorobenzonitrile;
2-[(4-CHLOROBENZYL)OXY]-6-FLUOROBENZONITRILE;
2-Fluoro-6-(4-chlorobenzyloxy)benzonitrile 97%;
2-Fluoro-6-(4-chlorobenzyloxy)benzonitrile97%;
6-(4-CHLOROBENZYLOXY)-2-FLUOROBENZONITRILE;
2-FLUORO-6-(4-CHLOROBENZYLOXY)BENZONITRILE 
CAS No.:
175204-10-1
分 子 式:
C14H9ClFNO
分 子 量:
261.69
精确分子量:
261.03600
PSA:
33.02000
InChI:
InChI=1/C14H9ClFNO/c15-11-6-4-10(5-7-11)9-18-14-3-1-2-13(16)12(14)8-17/h1-7H,9H2
风险术语:
R20/21/22R36/37/38
安全术语:
S22S36/S37/S39
分子结构式:
SDS:
查看

2-氟-6-(4-氟代苄氧基)苄腈 物化性质

密度:
1.31g/cm3
熔点:
146 °C
沸点:
387.6ºC at 760 mmHg
闪点:
188.2ºC
折射率:
1.593
蒸汽压:
3.25E-06mmHg at 25°C
其它信息:

1.      性状:未确定

2.      密度(g/mL,20):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):146

5.      沸点(ºC,常压):未确定

6.      沸点(ºC 0.5 mmHg):未确定

7.      折射率:未确定

8.      闪点(ºC):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

2-氟-6-(4-氟代苄氧基)苄腈 安全信息

海关代码:
2926909090
危险类别码:
R20/21/22
安全说明:
S22-S36/37/39
安全标志:
S22:不要吸入粉尘。
:
危险标志:
Xi

2-氟-6-(4-氟代苄氧基)苄腈 MSDS

Name: 2-[(4-Chlorobenzyl)oxy]-6-fluorobenzonitrile 97% Material Safety Data Sheet
Synonym: 6-(4-Chlorobenzloxy)-2-fluorobenzonitril
CAS: 175204-10-1
Section 1 - Chemical Product   MSDS Name:2-[(4-Chlorobenzyl)oxy]-6-fluorobenzonitrile 97% Material Safety Data Sheet
Synonym:6-(4-Chlorobenzloxy)-2-fluorobenzonitril

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
175204-10-1 2-[(4-Chlorobenzyl)oxy]-6-fluorobenzon 97% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 175204-10-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 146 - 148 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H9ClFNO
Molecular Weight: 262

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide, fluorine, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 175204-10-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-[(4-Chlorobenzyl)oxy]-6-fluorobenzonitrile - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 175204-10-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 175204-10-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 175204-10-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

2-氟-6-(4-氟代苄氧基)苄腈 海关数据

中国海关编码:2926909090

概述:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

2-氟-6-(4-氟代苄氧基)苄腈 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):3.8

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:3

5.互变异构体数量:无

6.拓扑分子极性表面积33

7.重原子数量:18

8.表面电荷:0

9.复杂度:308

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

2-氟-6-(4-氟代苄氧基)苄腈 上游产品

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