双(四甲基环戊二烯)铁

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS

双(四甲基环戊二烯)铁 基本信息

中文名称:
双(四甲基环戊二烯)铁 
中文别名:
双(四甲基环戊二烯)铁;
Bis(tetramethylcyclopentadienyl)iron 
英文名称:
Ferrocene,1,1',2,2',3,3',4,4'-octamethyl-
英文别名:
Octamethylferrocene;
BIS(TETRAMETHYLCYCLOPENTADIENYL)IRON 
CAS No.:
59568-28-4
分 子 式:
C18H26Fe
分 子 量:
298.24
精确分子量:
298.13800
PSA:
0.00000
MDL:
MFCD01862457
InChI:
The Key: VSUTUDRPAASKEB-UHFFFAOYSA-N
安全术语:
S22S24/25
分子结构式:
SDS:
查看

双(四甲基环戊二烯)铁 物化性质

熔点:
120-160ºC(lit.)
存储条件/存储方法:

在密封的贮藏器内,并放置阴凉,干燥的地方保存

稳定性相关:

避免接触氧化物

其它信息:

1.       性状:未确定

2.       密度(g/cm3 ):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):120-160

5.       沸点(ºC,):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率(°):未确定

8.       闪点ºC,):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值(25℃):未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性(mg/mL):水:未确定

双(四甲基环戊二烯)铁 安全信息

安全说明:
S22-S24/25
安全标志:
S22:不要吸入粉尘。
S24/25:防止皮肤和眼睛接触。

双(四甲基环戊二烯)铁 毒理性

生态数据:

对水是稍微危害的,若无政府许可,勿将材料排入周围环境。

双(四甲基环戊二烯)铁 MSDS


Section 1: Product Identification
   Chemical Name:       Bis(tetramethylcyclopentadienyl)iron, min. 98%    
   CAS Registry Number:       59568-28-4    
   Formula:       [(CH3)4C5H]2Fe    
   EINECS Number:       none    
   Chemical Family:       organometallic complexes    
   Synonym:       None    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       59568-28-4       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, eyes    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may lead to vomiting, and diarrhea.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry area away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow powder    
   Molecular Weight:       298.25    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture-stable material    
   Hazardous Polymerization:       none    
   Conditions to Avoid:       contact with strong oxidizing agents    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, and iron oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in RTECS.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       not listed on the TSCA inventory    
   SARA (Title 313):       Not reportable under SARA Title (313).    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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