Hexa-O-acetyl-cellobial

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

Hexa-O-acetyl-cellobial 基本信息

中文名称:
Hexa-O-acetyl-cellobial 
中文别名:
六乙酰基-D-纤维二糖烯;
Boc-5-Bromo-DL-tryptophan;
5-Bromo-N-{[(2-methyl-2-propanyl)oxy]carbonyl}tryptophan;
Fenpropidin;
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II);
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II);
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE NICKEL DICHLORIDE;
1,1'-Bis(diphenylphosphino)ferrocenedichloronickel;
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]Nickle (II);
(DPPF)NiCl2;
[1,1'-Bis(diphenyphosphino)ferrocene]dichloronickel(II);
N-M 
英文名称:
D-arabino-Hex-1-enitol,1,5-anhydro-2-deoxy-4-O-(2,3,4,6-tetra-O-acetyl-b-D-glucopyranosyl)-, 3,6-diacetate
英文别名:
HEXA-O-ACETYL-CELLOBIAL;
hexa-O-acetyl-D-maltal;
Hexaacetyl-D-maltal;
Maltal peracetate;
2,3,4,6-TETRAFLUOROBENZYLAMINE;
3,6,2',3',4',6'-hexa-O-acetyl-D-maltal;
(2R,3R,4S,5R,6R)-2-((2R,3S,4R)-4-acetoxy-2-(acetoxymethyl)-3,4-dihydro-2H-pyran-3-yloxy)-6-(acetoxymethyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate;
2',3,3',4',6,6'-hexa-O-acetyl-D-maltal;
per-O-acetyl-D-maltal;
Hexa-O-acetylmaltal;
D-arabino-Hex-1-enitol,1,5-anhydro-2-deoxy-4-O-(2,3,4,6-tetra-O-acetyl-a-D-glucopyranosyl)-,diacetate (9CI) 
CAS No.:
67314-36-7
分 子 式:
C24H32O15
分 子 量:
560.5
精确分子量:
560.17400
PSA:
185.49000
InChI:
InChI=1/C24H32O15/c1-11(25)32-9-18-20(17(7-8-31-18)34-13(3)27)39-24-23(37-16(6)30)22(36-15(5)29)21(35-14(4)28)19(38-24)10-33-12(2)26/h7-8,17-24H,9-10H2,1-6H3/t17-,18-,19-,20+,21-,22+,23-,24+/m1/s1
安全术语:
S24/25
分子结构式:
SDS:
查看

Hexa-O-acetyl-cellobial 物化性质

密度:
1.34 g/cm3
沸点:
591.7ºC at 760 mmHg
闪点:
249.2ºC
折射率:
1.51
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

Hexa-O-acetyl-cellobial 安全信息

安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

Hexa-O-acetyl-cellobial 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

Hexa-O-acetyl-cellobial MSDS

Name: Hexa-O-acetyl-cellobial Material Safety Data Sheet
Synonym:
CAS: 67314-36-7
Section 1 - Chemical Product   MSDS Name:Hexa-O-acetyl-cellobial Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
67314-36-7 Hexa-O-acetyl-cellobial unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 67314-36-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid or liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C24H32O15
Molecular Weight: 560.51

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 67314-36-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Hexa-O-acetyl-cellobial - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 67314-36-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 67314-36-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67314-36-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

Hexa-O-acetyl-cellobial 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:125.19

2、   摩尔体积(m3/mol):417.9

3、   等张比容(90.2K):1117.8

4、   表面张力(dyne/cm):51.1

5、   极化率10-24cm3):49.62

计算化学数据

1、   疏水参数计算参考值(XlogP):=0.2

2、   氢键供体数量:0

3、   氢键受体数量:15

4、   可旋转化学键数量:16

5、   拓扑分子极性表面积(TPSA):186

6、   重原子数量:39

7、   表面电荷:0

8、   复杂度;959

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

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产品名称:六乙酰基-D-纤维二糖烯 Cas号:67314-36-7 纯度:≥98% 包装信息:1—25kg 价格:洽谈
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