硝酸汞(2+)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

硝酸汞(2+) 基本信息

中文名称:
硝酸汞(2+) 
中文别名:
硝酸汞;
硝酸汞(剧毒) 
英文名称:
mercury(2+),dinitrate
英文别名:
Nitric acid, mercury(2+) salt (2:1);
Mercury(II) nitrate (Hg(NO3)2) (6CI);
Nitric acid, mercury(2+) salt (8CI,9CI);
Citrine ointment;
Mercuric nitrate;
Mercury dinitrate;
Mercury nitrate;
Mercury nitrate (Hg(NO3)2);
Mercury(2+) nitrate;
Mercury(II) nitrate;
Millon's reagent;
Named reagents and solutions, Millon's 
CAS No.:
10045-94-0
分 子 式:
HgN2O6
分 子 量:
324.60000
精确分子量:
327.96192
PSA:
137.76000
EINECS:
233-152-3
InChI:
InChI=1/Hg.NO3/c;2-1(3)4/q+2;-1
风险术语:
8-23/24/25-33-34
分子结构式:
SDS:
查看

硝酸汞(2+) 制备方法及用途

制备方法

制法 将100mL 8mol/L硝酸热至50~60℃。分次加入50g汞(或计算量的氧化汞),加热搅拌,直到Hg完全氧化溶解为止,(取反应溶液少许加入盐酸不呈混浊)。在水浴上于70~80℃蒸发浓缩,待形成薄膜后,加入2~3mL 8mol/L硝酸,此时结晶溶解(否则再加热搅拌)。然后在-5~-10℃下放置过夜使其结晶,吸滤,用10mL 8mol/L硝酸洗涤结晶。得产品50~60g。

合成制备方法

制法 将100mL 8mol/L硝酸热至50~60℃。分次加入50g汞(或计算量的氧化汞),加热搅拌,直到Hg完全氧化溶解为止,(取反应溶液少许加入盐酸不呈混浊)。在水浴上于70~80℃蒸发浓缩,待形成薄膜后,加入2~3mL 8mol/L硝酸,此时结晶溶解(否则再加热搅拌)。然后在-5~-10℃下放置过夜使其结晶,吸滤,用10mL 8mol/L硝酸洗涤结晶。得产品50~60g。

用途简介

主要用作分析试剂,用于有机合成及药品和雷汞的制造。

用途

用作分析试剂,及用于有机合成,药品和雷汞的制造。[15]

硝酸汞(2+) 物化性质

密度:
1.025 g/mL at 25 °C
熔点:
79ºC
沸点:
83ºC
蒸汽压:
49.8mmHg at 25°C
存储条件/存储方法:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物,食品原料分开存放
稳定性相关:

1.稳定性[9]  稳定

2.禁配物[10]  易燃或可燃物、强还原剂、无机物、磷、活性金属粉末等

3.避免接触的条[11]  受热

4.聚合危害[12]  不聚合

5.分解产物[13]  氮氧化物、氧化汞

其它信息:

1.性状:无色或白色透明结晶,有潮解性。[1]

2.熔点(℃):79[2]

3.沸点(℃):180(分解)[3]

4.相对密度(水=1):4.39[4]

5.溶解性:易溶于水,不溶于乙醇,溶于硝酸。[5]

硝酸汞(2+) 安全信息

包装等级:
II
风险类别:
6.1(a)
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R8-23/24/25-33-34
安全说明:
S36/37
危险标志:
Xn

硝酸汞(2+) 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OW8225000
CAS REGISTRY NUMBER :
10045-94-0
LAST UPDATED :
199712
DATA ITEMS CITED :
29
MOLECULAR FORMULA :
N2-O6.Hg
MOLECULAR WEIGHT :
324.61
WISWESSER LINE NOTATION :
HG N-O3*2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
26 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
75 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
25 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
7200 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
20 mg/kg
REFERENCE :
MOLAAF Monatsschrift fuer Ohrenheilkunde und Laryngo-Rhinologie. (Vienna, Austria) V.1-108, 1867-1974. For publisher information, see LROTDW. Volume(issue)/page/year: 73,751,1939 *** REVIEWS *** ACGIH TLV-TWA 0.025 mg(Hg)/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.05 mg(Hg)/m3 DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,22,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.05 mg(Hg)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.05 mg(Hg)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-FINLAND:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-FRANCE:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-GERMANY:TWA 0.01 ppm (0.1 mg(Hg)/m3) JAN 1993 OEL-HUNGARY:TWA 0.02 mg(Hg)/m3;STEL 0.04 mg(Hg)/m3 JAN 1993 OEL-JAPAN:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.05 mg(Hg)/m3;STEL 0.15 mg(Hg)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-POLAND:TWA 0.01 mg(Hg)/m3 JAN 1993 OEL-RUSSIA:TWA 0.05 mg(Hg)/m3;STEL 0.01 mg(Hg)/m3 JAN 1993 OEL-SWEDEN:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-THAILAND:STEL 0.05 mg(Hg)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.05 mg(Hg)/m3;STEL 0.15 mg(Hg)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO MERCURY, ARYL AND INORGANIC-air:CL 0.1 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81005 No. of Facilities: 925 (estimated) No. of Industries: 9 No. of Occupations: 13 No. of Employees: 7651 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81005 No. of Facilities: 1345 (estimated) No. of Industries: 14 No. of Occupations: 17 No. of Employees: 13589 (estimated) No. of Female Employees: 6114 (estimated)
毒理学数据:

1.急性毒性[6]

LD50:26mg/kg(大鼠经口);75mg/kg(大鼠经皮)

2.刺激性  暂无资料

3.亚急性与慢性毒性[7]  动物的慢性中毒表现最早是行为改变,继而出现神经系统功能障碍,血液变化主要有白细胞增多、血沉加快,然后出现肝、肾功能受损。动物尸检见直肠下段溃疡,肝肾脂肪变性,肝有灶性坏死。

生态数据:

1.生态毒性  暂无资料

2.生物降解性  暂无资料

3.非生物降解性  暂无资料

4.其他有害作用[8]  该物质对环境有危害,应特别注意对水体的污染;汞元素在生物体内有很强的蓄积作用。

硝酸汞(2+) MSDS

第一部分:化学品名称

硝酸汞(2+) 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积126

7.重原子数量:9

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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