(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷

  • 基本信息
  • 物化性质
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品

(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷 基本信息

中文名称:
(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷 
中文别名:
(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2'-基]二苯基磷;
(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2'-基]二苯基磷;
(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2 
英文名称:
R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN
英文别名:
S-(-)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin, min. 97% (S)-SYNPHOS;
R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN;
(S)-SYNPHOS(R);
(S)-SYNPHOS(TM);
S-(-)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN;
(S)-(-)-[(5,6),(5',6')-BIS(ETHYLENEDIOXY)BIPHENYL-2,2'-DIYL](DIPHENYLPHOSPHINE);
(R)-SYNPHOS(R);
(R)-SYNPHOS(TM);
(R)-(+)-[(5,6),(5',6')-BIS(ETHYLENEDIOXY)BIPHENYL-2,2'-DIYL](DIPHENYLPHOSPHINE) 
CAS No.:
503538-68-9
分 子 式:
C40H32O4P2
分 子 量:
638.63
精确分子量:
638.17800
PSA:
64.10000
MDL:
MFCD05861608
InChI:
The Key: GDMCOFXEPNHXJT-UHFFFAOYSA-N
分子结构式:
SDS:
查看

(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷 物化性质

存储条件/存储方法:

 

 密闭于4ºC阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:白色粉末

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:不溶于水

(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷 MSDS


Section 1: Product Identification
   Chemical Name:       S-(-)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin, min. 97% (S)-SYNPHOS™    
   CAS Registry Number:       503538-68-9    
   Formula:       C40H32O4P2    
   EINECS Number:       none    
   Chemical Family:       organophosphine ligand    
   Synonym:       (S)-SYNPHOS,S-(-)--6,6'-Bis-diphenylphosphanyl-2,3,2',3'- tetrahydro-[5,5']bi[benzo[1,4]dioxinyl]    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       503538-68-9       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes mild irritation of the eyes.    
   Skin Contact:       Causes mild irritation of the skin.    
   Inhalation:       Inhalation of dust will lead to irritation of the respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and phosphorus pentoxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Keep away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white powder    
   Molecular Weight:       638.63    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon monoxide, carbon dioxide, phosphorus oxides and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data available    
   Mutagenic Effects:       no data available    
   Tetratogenic Effects:       no data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷 分子结构与计算化学数据

分子结构数据

1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

推荐供应商更多供应商>>

淄博航宇生物科技发展有限公司

产品介绍:
产品名称:(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷 Cas号:503538-68-9 纯度:99% 包装信息:100kg 价格:洽谈
联系方式:
联系人:张经理 电话:15666366704 手机:15666366704

北京百灵威科技有限公司

产品介绍:
产品名称:(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2'-基]二苯基磷 Cas号:503538-68-9 纯度:min. 97% 包装信息:100mg 价格:洽谈
联系方式:
联系人:翟先生 电话:18210857532 手机:18210857532

苏州市森菲达化工有限公司

产品介绍:
产品名称:503538-68-9 Cas号:503538-68-9 纯度: 包装信息:200kg 价格:洽谈
联系方式:
联系人:吴 电话:15195660023 手机:15195660023

吉林中科研伸科技有限公司

产品介绍:
产品名称:(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2'-基]二苯基磷 Cas号:503538-68-9 纯度:98% 包装信息:1g,5g,25g 价格:洽谈
联系方式:
联系人:李猛 电话:0431-80514536 手机:13596459565

无锡市耀得信化工产品有限公司

产品介绍:
产品名称:(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2'-基]二苯基磷 Cas号:503538-68-9 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:茆 电话:0510-83593312 手机:13665125081

杭州福斯特药业有限公司

产品介绍:
产品名称:(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2'-基]二苯基磷 Cas号:503538-68-9 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:陈福生 电话:86-571-88938669 手机:

郑州杰克斯化工产品有限公司

产品介绍:
产品名称:(S)-(-)-[(5,6),(5'',6'')-双(乙烯二氧)联苯-2,2''-基]二苯基磷 Cas号:503538-68-9 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:许伟伟 电话:0371-86259281 手机:15981966935

上海一基实业有限公司

产品介绍:
产品名称:(S)-(-)-[(5,6),(5,6)-双(乙烯二氧)联苯-2,2-基]二苯基磷 Cas号:503538-68-9 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:张嘉彬 电话:021-60536261 17802116021 手机:17802116021

King Sun Chemical & Pharmaceutical Co., Ltd.

产品介绍:
产品名称:(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2'-基]二苯基磷 Cas号:503538-68-9 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人: 电话:86-021-54776327 手机:
QQ: 2241752642
微信二维码
电话: 19906633110