高氯酸铷

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

高氯酸铷 基本信息

中文名称:
高氯酸铷 
中文别名:
高氯酸铷;
过氯酸铷 
英文名称:
Perchloric acid,rubidium salt (1:1)
英文别名:
rubidium(1+),perchlorate;
Rubidium perchlorate;
rubidium(1+) perchlorate ion;
Perchloric acid rubidium salt;
EINECS 236-840-1;
Rubidium chlorate(VII);
rubidium(1+) ion perchlorate 
CAS No.:
13510-42-4
分 子 式:
ClHO4.Rb
分 子 量:
184.92
精确分子量:
183.86000
PSA:
74.27000
MDL:
MFCD00016294
EINECS:
236-840-1
InChI:
The Key: NQYGGOOZLKJKPS-UHFFFAOYSA-M
风险术语:
R8R20/22R36/37/38
安全术语:
S17S26S36
分子结构式:
SDS:
查看

高氯酸铷 制备方法及用途

制备方法

等摩尔的HClO4和碳酸铷溶液混合,蒸发出过量的水,得到晶体。在水中重结晶纯化。加热至150℃以上干燥。

合成制备方法

等摩尔的HClO4和碳酸铷溶液混合,蒸发出过量的水,得到晶体。在水中重结晶纯化。加热至150℃以上干燥。

用途简介

高氯酸铷 物化性质

密度:
2,8 g/cm3
折射率:
1.4701
存储条件/存储方法:

常温密闭,阴凉通风干燥

稳定性相关:

常温常压下稳定

避免的物料 还原剂 易氧化材料 有机材料 金属粉末 硫磺 铝和铝合金 镁。279℃变为立方晶体。吸湿。溶解性(g/100gH2O)1.1(0℃),1.8(25℃),221(100℃),0.06g/100cm3 MeOH(25℃),9×10-3g/100cm3 EtOH(25℃)。ΔfH=-437kJ/mol。ΔfG=-308kJ/mol。S=164J/(K·mol)。熔点281℃。沸点606℃(分解)。密度2.80g/cm3。与有机物或有机金属化合物混合时爆炸。

其它信息:

1.       性状:白色无味晶体

2.       密度(g/mL,25/4℃):2.80

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):281

5.       沸点(ºC,常压):606

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):不适用的

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:易溶解的

高氯酸铷 安全信息

包装等级:
II
风险类别:
5.1
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
8-20/22-36/37/38
安全说明:
S17-S26-S36
安全标志:
S17:远离可燃物质。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
危险标志:
O: Oxidizing agent;Xn: Harmful;

高氯酸铷 毒理性

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;

在眼睛上面:刺激的影响;没有已知的敏化影响。

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

高氯酸铷 MSDS


Section 1: Product Identification
   Chemical Name:       Rubidium perchlorate, anhydrous (99.9%-Rb)    
   CAS Registry Number:       13510-42-4    
   Formula:       RbClO4    
   EINECS Number:       236-840-1    
   Chemical Family:       metal perchlorate salt    
   Synonym:       Perchloric acid, rubidium salt.    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13510-42-4       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract. May affect thyroid and kidney functions    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes moderate irritation of the skin.    
   Inhalation:       May cause difficulty in breathing and irritate mucous membranes and respiratory tract.    
   No specific information is available on the physiological effects of ingestion. May cause gastrointestinal
   Ingestion:
   irritation, nausea, and vomiting.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function may be affected.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       Water spray    
   Spray closed containers with water until fire is out. Avoid contact with combustible material. Fire fighters
   Special Fire Fighting Procedures:
   should be equipped with a NIOSH approved self-contained breathing apparatus.
   Hazardous Combustion and       If involved in a fire this material may emit corrosive hydrogen chloride fumes.    
   Decomposion Products:
   Releases oxygen on heating. May decompose explosively under fire fighting conditions. Do not mix with
   Unusual Fire or Explosion Hazards:
   combustibles.

SECTION 6: Accidental Release Measures
   Do not mix spilled powder with any combustible materials, such as sawdust. Sweep up the solid and dilute
   Spill and Leak Procedures:
   with water.

SECTION 7: Handling and Storage
   Store in a tightly sealed container in a cool dry place away from combustible and flammable materials. If the
   Handling and Storage:
   container is left open, salt may adsorb moisture from the atmosphere

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       184.92    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       2.8    
   Odor:       none    
   Solubility in Water:       Soluble    

SECTION 10: Stability and Reactivity
   Stability:       Hygroscopic    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Any contact with combustible matter.    
   Incompatibility:       Reducing agents, organic matter, active metals, phosphorus, sulfur, hydrazine, hydroxylamine, strong acids    
   Decomposition Products:       Oxygen, Rubidium oxide, hydrogen chloride,    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Perchlorates, Inorganic, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1481    
   Shipping Name (IATA):       Perchlorates, Inorganic, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1481    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

高氯酸铷 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:183.860303 Da

8、标称质量:184 Da

9、平均质量:184.9184 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:4

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积74.3

7.重原子数量:6

8.表面电荷:0

9.复杂度:118

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

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