酸性媒介深黄GG

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

酸性媒介深黄GG 基本信息

中文名称:
酸性媒介深黄GG 
中文别名:
酸性媒介黄10;
酸性媒介黄H;
媒染黄1;
酸性媒介深黄 GG;
媒染黄10;
酸性媒介黄;
酸性媒介深黄2G 
英文名称:
Benzoic acid,2-hydroxy-5-[2-(4-sulfophenyl)diazenyl]-, sodium salt (1:2)
英文别名:
Mordant Yellow 10;
chromeyellowk;
Yellow 2GN;
chromeyellow2j;
disodium 5-(p-sulphophenylazo)salicylate;
magracromyellow;
chromeyellowdf;
Solochrom-Gelb ZGS;
MY 10;
cromalyellows;
Ponsol Yel;
ponsolyellowswr;
5-(4-sulfophenylazo)salicylic acid disodium salt 
CAS No.:
6054-99-5
分 子 式:
C13H10N2O6S.2Na
分 子 量:
366.25
精确分子量:
365.99000
PSA:
150.66000
MDL:
MFCD00007504
EINECS:
227-976-2
InChI:
InChI=1/C13H10N2O6S.2Na/c16-12-6-3-9(7-11(12)13(17)18)15-14-8-1-4-10(5-2-8)22(19,20)21;;/h1-7,16H,(H,17,18)(H,19,20,21);;/q;2*+1/p-2/b15-14+;;
危险品标志:
风险术语:
R36/37/38
安全术语:
S24/25;
分子结构式:
SDS:
查看

酸性媒介深黄GG 制备方法及用途

制备方法

由间硝基苯胺重氮化后,与水杨酸偶合,经盐析、过滤及干燥制得本品。该品外观为黄色均匀粉末,色光与标准品近似,强度为标准100±3(分),不溶于水的杂质含量≤1%,水分含量≤5%,细度(通过80目的筛余物含量)≤5%,在羊毛织物上染色的坚牢度合标准品(日晒6-7级,皂洗3-4级,碳化4-5级,汗渍5级,煮呢3-4级,熨烫5级)。原料消耗(kg/t)间硝基苯胺 305水杨酸310

合成制备方法

 由间硝基苯胺重氮化后,与水杨酸偶合,经盐析、过滤及干燥制得本品。该品外观为黄色均匀粉末,色光与标准品近似,强度为标准100±3(分),不溶于水的杂质含量≤1%,水分含量≤5%,细度(通过80目的筛余物含量)≤5%,在羊毛织物上染色的坚牢度合标准品(日晒6-7级,皂洗3-4级,碳化4-5级,汗渍5级,煮呢3-4级,熨烫5级)。原料消耗(kg/t)间硝基苯胺 305水杨酸310

 

用途简介

主要用于羊毛的毛条和散毛染色,可用于蚕丝染色,有时也用于锦纶条的染色(只宜采用后媒法)。羊毛与多种纤维同浴染色时,锦纶得色比羊毛浅,蚕丝更浅,二醋纤、棉、粘胶不沾色。还可在经乙酸铬顶处理的羊毛或蚕丝织物上直接印花,除单独使用外,少量用于拼色和调节色光。

用途

主要用于羊毛的毛条和散毛染色,可用于蚕丝染色,有时也用于锦纶条的染色(只宜采用后媒法)。羊毛与多种纤维同浴染色时,锦纶得色比羊毛浅,蚕丝更浅,二醋纤、棉、粘胶不沾色。还可在经乙酸铬顶处理的羊毛或蚕丝织物上直接印花,除单独使用外,少量用于拼色和调节色光。

酸性媒介深黄GG 物化性质

外观与性状:
黄色至棕色结晶粉末
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房。

稳定性相关:

常温常压下稳定,避免与不相容材料接触。

酸性媒介深黄GG 安全信息

海关代码:
3204120000
危险类别码:
R36/37/38
安全说明:
S37/39-S26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xi:Irritant;

酸性媒介深黄GG 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GB4450000
CHEMICAL NAME :
Benzoic acid, 2-hydroxy-5-((4-sulfophenyl)azo)-, disodium salt
CAS REGISTRY NUMBER :
6054-99-5
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C13-H8-N2-O6-S.2Na

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
14 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(1),14,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
7400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(1),14,1983
毒理学数据:

1、急性毒性:大鼠经口LD5014mg/kg;小鼠经口LD507400mg/kg

生态数据:

对环境有危害,对水体有污染,禁止进入水体。

酸性媒介深黄GG MSDS

Name: Mordant yellow 10 Material Safety Data Sheet
Synonym: Acid Chrome Yellow; Chrome Yellow K; Durochrome Yellow Concentrate
CAS: 6054-99-5
Section 1 - Chemical Product   MSDS Name:Mordant yellow 10 Material Safety Data Sheet
Synonym:Acid Chrome Yellow; Chrome Yellow K; Durochrome Yellow Concentrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6054-99-5 Benzoic acid, 2-hydroxy-5-(4-sulfophen ca. 100 227-976-2
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6054-99-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H8N2O6SNa2
Molecular Weight: 366.26

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 6054-99-5: GB4450000 LD50/LC50:
CAS# 6054-99-5: Oral, mouse: LD50 = 7400 mg/kg; Oral, rat: LD50 = 14 gm/kg.
Carcinogenicity:
Benzoic acid, 2-hydroxy-5-(4-sulfophenyl)azo-,disodium salt - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6054-99-5: No information available.
Canada
CAS# 6054-99-5 is listed on Canada's DSL List.
CAS# 6054-99-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6054-99-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

酸性媒介深黄GG 分子结构与计算化学数据

计算化学数据

1、   疏水参数计算参考值(XlogP):

2、   氢键供体数量:3

3、   氢键受体数量:8

4、   可旋转化学键数量:4

5、   互变异构体数量:4

6、   拓扑分子极性表面积(TPSA):133

7、   重原子数量:23

8、   表面电荷:1

9、   复杂度:663

10、   同位素原子数量:0

11、   确定原子立构中心数量:0

12、   不确定原子立构中心数量:0

13、   确定化学键立构中心数量:0

14、   不确定化学键立构中心数量:1

15、   共价键单元数量:2

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