番木鳖碱

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 结构与计算化学

番木鳖碱 基本信息

中文名称:
番木鳖碱 
中文别名:
番木鳖碱;
10,11-Dimethoxystrychnine dihydrate 
英文名称:
BRUCINE DIHYDRATE
英文别名:
BRUCINE DIHYDRATE;
2,3-DIMETHOXYSTRYCHNIDIN-10-ONE DIHYDRATE;
10,11-DIMETHOXYSTRYCHNINE DIHYDRATE;
Strychnidin-10-one,2,3-dimethoxy-,dihydrate;
BRUCINE N-HYDRATE 
CAS No.:
145428-94-0
分 子 式:
C23H30N2O6
分 子 量:
430.49
精确分子量:
430.21000
PSA:
69.70000
InChI:
The Key: IEJIBKWJYHZFNW-OPLMDYKZSA-N
风险术语:
R26/28; R52/53
分子结构式:
SDS:
查看

番木鳖碱 物化性质

外观与性状:
白色结晶粉末或晶体
熔点:
174 °C
沸点:
633.7ºC at 760mmHg
闪点:
337.1ºC
蒸汽压:
0mmHg at 25°C
其它信息:

1.       性状:无色光亮针状结晶,味极苦

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):284286

番木鳖碱 安全信息

WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R26/28;R52/53
安全说明:
S24/25
危险标志:
T+

番木鳖碱 MSDS

Name: Brucine dihydrate 99% Material Safety Data Sheet
Synonym: Non
CAS: 145428-94-0
Section 1 - Chemical Product   MSDS Name:Brucine dihydrate 99% Material Safety Data Sheet
Synonym:Non

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
145428-94-0 Brucine dihydrate 99.0 unlisted
Hazard Symbols: T+
Risk Phrases: 26/28

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Very toxic by inhalation and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Poison by ingestion.
May cause tremors and convulsions.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Poison room locked.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 145428-94-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: @ 760.00mm Hg
Freezing/Melting Point: 176.00 - 178.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density:
Molecular Formula: C23H26N2O4.2H2O
Molecular Weight: 430.50

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of nitrogen, oxides of carbon, nitrogen.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 145428-94-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Brucine dihydrate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: BRUCINE
Hazard Class: 6.1
UN Number: 1570
Packing Group: I
IMO
Shipping Name: BRUCINE
Hazard Class: 6.1
UN Number: 1570
Packing Group: I
RID/ADR
Shipping Name: BRUCINE
Hazard Class: 6.1
UN Number: 1570
Packing group: I

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/28 Very toxic by inhalation and if swallowed.
Safety Phrases:
S 1 Keep locked up.
S 13 Keep away from food, drink and animal feeding
stuffs.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 145428-94-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 145428-94-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 145428-94-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

番木鳖碱 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:430.210387 Da

8、标称质量:430 Da

9、平均质量:430.4941 Da

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