铊氢三[3-(2-吡啶基)吡唑-1-基]硼酸

  • 基本信息
  • 物化性质
  • MSDS

铊氢三[3-(2-吡啶基)吡唑-1-基]硼酸 基本信息

中文名称:
铊氢三[3-(2-吡啶基)吡唑-1-基]硼酸 
中文别名:
铊氢三[3-(2-吡啶基)吡唑-1-基]硼酸 
英文名称:
THALLIUM HYDROTRIS[3-(2-PYRIDYL)PYRAZOL-1-YL]BORATE
英文别名:
Thallium, [hydrotris[2-(1H-pyrazol-3-yl)pyridinato]borato(1-)]- (9CI) 
CAS No.:
165257-90-9
分 子 式:
C24H21BN9O3Tl
分 子 量:
698.68
精确分子量:
649.16006
PSA:
152.82000
分子结构式:
SDS:
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铊氢三[3-(2-吡啶基)吡唑-1-基]硼酸 物化性质

熔点:
283-285ºC
其它信息:

1.      性状:未确定

2.      密度(g/mL,20):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):283-285

5.      沸点(ºC,常压):未确定

6.      沸点(ºC  28mmHg):未确定

7.      折射率:未确定

8.      闪点(ºF):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

铊氢三[3-(2-吡啶基)吡唑-1-基]硼酸 MSDS


Section 1: Product Identification
   Chemical Name:       Thallium hydrotris[3-(2-pyridyl)pyrazol-1-yl]borate, min. 98%    
   CAS Registry Number:       165257-90-9    
   Formula:       [C24H19BN9]Tl    
   EINECS Number:       none    
   Chemical Family:       metal borate    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       165257-90-9       100%       0.1 mg/m3 (sol Tl)       0.1 mg/m3 (sol Tl)    

Section 3: Hazards Identification
   Thallium compounds are very toxic by inhalation and if swallowed. May be irritating to skin, eyes and
   Emergency Overview:
   respiratory tract. danger of cumulative effects.
   Primary Routes of Exposure:       Ingestion, skin, inhalation of dust.    
   Eye Contact:       May cause slight to mild irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       Very toxic by inhalation. May be irritating to the nose, mucous membranes respiratory tract.    
   Very toxic if swallowed. Ingestion may result in swelling of the feet and legs, mental confusion, paralysis,
   Ingestion:
   angina-like pains.
   Very toxic by inhalation and if swallowed. Acute poisoning results in pain of the extremities, fever, nausea and
   Acute Health Affects:
   vomiting, jumbled speech, tremors, convulsions, kidney failure, and pulmonary edema.
   Danger of cumulative effects. Prolonged exposure to thallium compounds has been reported to lead to
   Chronic Health Affects:       discoloration of the hair, which later falls out, joint pain, loss of appetite, fatigue, severe pain in the legs,    
   albuminuria, and optic neuritis. Possible mutagen.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide or dry powder    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire toxic oxidation or decomposition products may form.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store material in a cool, dry place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white pwdr.    
   Molecular Weight:       648.66    
   Melting Point:       283-285°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       slightly soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       thallium oxide, carbon monoxide, carbon dioxide, boron oxide, and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Avoid release to the environment. Toxic to aquatic organisms . May cause long-term adverse effects to the
   Ecological Information:
   aquatic environment.

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Thallium Compound, N.O.S.    
   Hazard Class (CFR):       6.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1707    
   Shipping Name (IATA):       Thallium Compound, N.O.S.    
   Hazard Class (IATA):       6.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1707    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See category N760 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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