1,1-双(三甲基硅氯)乙烯

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品

1,1-双(三甲基硅氯)乙烯 基本信息

中文名称:
1,1-双(三甲基硅氯)乙烯 
中文别名:
1,1-双(三甲基硅氯)乙烯;
1,1-双(三氯甲硅烷基甲基)乙烯 
英文名称:
Silane,(2-methylene-1,3-propanediyl)bis[trichloro- (9CI)
英文别名:
trichloro-[2-(trichlorosilylmethyl)prop-2-enyl]silane;
3-(Trichlorosilyl)-2-<(trichlorosilyl)methyl>-1-propene;
3-Trichlorsilyl-2-(trichlorsilyl-methyl)-propen;
1,5-Disilapentane,1,1,1,5,5,5-hexachloro-3-methylene-(6CI);
1,1-BIS(TRICHLOROSILYLMETHYL)ETHYLENE;
3-trichlorosilanyl-2-(trichlorosilanyl-methyl)-propene 
CAS No.:
78948-04-6
分 子 式:
C4H6Cl6Si2
分 子 量:
322.98
精确分子量:
319.81400
PSA:
0.00000
MDL:
MFCD00239510
InChI:
InChI=1/C4H6Cl6Si2/c1-4(2-11(5,6)7)3-12(8,9)10/h1-3H2
风险术语:
R14R34
安全术语:
S26S27S45S36/S37/S39
分子结构式:
SDS:
查看

1,1-双(三甲基硅氯)乙烯 物化性质

外观与性状:
透明无色液体
密度:
1.4 g/mL at 25ºC(lit.)
沸点:
128-131ºC16 mm Hg(lit.)
闪点:
178 °F
折射率:
n20/D 1.488(lit.)
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):1.4

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):128-131

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:1.488

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

1,1-双(三甲基硅氯)乙烯 安全信息

危险类别码:
14-34
安全说明:
26-27-36/37/39-45
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S27:立刻除去所有污染衣物。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
C: Corrosive;

1,1-双(三甲基硅氯)乙烯 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

1,1-双(三甲基硅氯)乙烯 MSDS

Name: 1 1-Bis(trichlorosilylmethyl)ethylene Material Safety Data Sheet
Synonym: (2-Methylene-1,3-propanediyl)bis(trichlorosilan
CAS: 78948-04-6
Section 1 - Chemical Product   MSDS Name:1 1-Bis(trichlorosilylmethyl)ethylene Material Safety Data Sheet
Synonym:(2-Methylene-1,3-propanediyl)bis(trichlorosilan

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
78948-04-6 1,1-Bis(trichlorosilylmethyl)ethylene unlisted
Hazard Symbols: C
Risk Phrases: 14 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Combustible liquid.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area. Store under an inert atmosphere.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 78948-04-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: light yellow
Odor: acrid odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 240 - 242 deg C @ 7
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts with water
Specific Gravity/Density: 1.4100g/cm3
Molecular Formula: Cl3SiCH2C(CH2)CH2SiCl3
Molecular Weight: 322.98

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases, alcohols, amines.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 78948-04-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,1-Bis(trichlorosilylmethyl)ethylene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 78948-04-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 78948-04-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 78948-04-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

1,1-双(三甲基硅氯)乙烯 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:66.67

2、   摩尔体积(m3/mol):229.2

3、   等张比容(90.2K):525.4

4、   表面张力(dyne/cm):27.6

5、   极化率10-24cm3):26.43

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:12

8.表面电荷:0

9.复杂度:149

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

1,1-双(三甲基硅氯)乙烯 上游产品

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产品名称:1,1-双(三甲基硅氯)乙烯 Cas号:78948-04-6 纯度: 包装信息:洽谈 价格:洽谈
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