Section 1: Product Identification
Acetonitrilebis[2-diphenylphosphino-6-t-butylpyridine]cyclopentadienylruthenium (II) hexafluorophosphate, min.
Chemical Name:
98%
CAS Registry Number: 776230-17-2
Formula: Ru(C5H5)(CH3CN)[C21H22NP]2+PF6-
EINECS Number: none
Chemical Family: metal phosphine complex
Synonym: Acetonitrile-cyclopentadienyl-bis[2-diphenylphosphino-6-t-butyl pyridine]ruthenium (II) hexafluorophosphate
Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 776230-17-2 100% 2.5mg/m3 (as F) 2.5mg/m3 (as F)
Section 3: Hazards Identification
Emergency Overview: Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure: Inhalation, skin, eyes
Eye Contact: Causes irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Dust is irritating to the nose, mucous membranes and respiratory tract.
Ingestion: No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects: Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Chronic Health Affects: Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic organic fumes, carbon monoxide and carbon dioxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.
SECTION 7: Handling and Storage
The material will degrade on prolonged exposure to air. Store and handle under an inert atmosphere of
Handling and Storage:
nitrogen or argon. Keep bottle tightly sealed and away from heat and direct sunlight.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: If possible, handle the material in an efficient fume hood.
If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: yellow microxtl.
Molecular Weight: 990.94
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air sensitive
Hazardous Polymerization: No hazardous polymerization
Conditions to Avoid: contact with air. This material may degrade on prolonged exposure to air.
Incompatibility: strong oxidizing agents, air and halogens
carbon monoxide, carbon dioxide, phosphorous pentoxide, ruthenium salts, organofluorides and organic
Decomposition Products:
fumes
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory
SARA (Title 313): Title compound not listed
Second Ingredient: none
SECTION 16 - ADDITIONAL INFORMATION
N/A
