2,3-二氢咪唑并[2,1-b]并苯并-6-胺

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学

2,3-二氢咪唑并[2,1-b]并苯并-6-胺 基本信息

中文名称:
2,3-二氢咪唑并[2,1-b]并苯并-6-胺 
中文别名:
2,3-二氢咪唑并[2,1-b]并苯并-6-胺;
2,3-二氢咪唑[2,1-B]苯并噻唑-6-胺 
英文名称:
Imidazo[2,1-b]benzothiazol-6-amine,2,3-dihydro-
英文别名:
1,2-dihydroimidazo[2,1-b][1,3]benzothiazol-7-amine;
4-hydro-2-imidazolino[2,1-b]benzothiazole-6-ylamine;
2,3-DICHLORO-4'-THIOMORPHOLINOMETHYL BENZOPHENONE;
2,3-Dihydroimidazo(2,1-b)benzothiazol-6-amine;
2,3-dihydroimidazo[2,1-b][1,3]benzothiazol-6-amine 
CAS No.:
78291-99-3
分 子 式:
C9H9N3S
分 子 量:
191.25
精确分子量:
191.05200
PSA:
71.55000
MDL:
MFCD00044717
EINECS:
278-892-8
InChI:
The Key: HJCGGAYYNMECPO-UHFFFAOYSA-N
安全术语:
S24/25
分子结构式:
SDS:
查看

2,3-二氢咪唑并[2,1-b]并苯并-6-胺 物化性质

密度:
1.61g/cm3
熔点:
200-205ºC
沸点:
430.6ºC at 760 mmHg
闪点:
214.2ºC
折射率:
1.852
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

2,3-二氢咪唑并[2,1-b]并苯并-6-胺 安全信息

海关代码:
2934100090
安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

2,3-二氢咪唑并[2,1-b]并苯并-6-胺 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

2,3-二氢咪唑并[2,1-b]并苯并-6-胺 MSDS

Name: 2 3-Dihydroimidazo(2 1-b)Benzothiazol-6- Amine 90% (Titr.) Material Safety Data Sheet
Synonym:
CAS: 78291-99-3
Section 1 - Chemical Product   MSDS Name:2 3-Dihydroimidazo(2 1-b)Benzothiazol-6- Amine 90% (Titr.) Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
78291-99-3 2,3-Dihydroimidazo[2,1-b]Benzothiazol- 90 278-892-8
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects was found.
Skin:
No information regarding skin irritation and other potential effects was found.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 78291-99-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystalline powder
Color: light beige
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 201.00 - 204.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H9N3S
Molecular Weight: 191.25

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 78291-99-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3-Dihydroimidazo[2,1-b]Benzothiazol-6-Amine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 78291-99-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 78291-99-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 78291-99-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

2,3-二氢咪唑并[2,1-b]并苯并-6-胺 海关数据

中国海关编码:2934100090

概述:
2934100090. 结构上含有一个非稠合噻唑环的化合物(不论是否氢化). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

2,3-二氢咪唑并[2,1-b]并苯并-6-胺 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:53.10

2、   摩尔体积(m3/mol):118.6

3、   等张比容(90.2K):347.9

4、   表面张力(dyne/cm):73.9

5、   极化率10-24cm3):21.05

计算化学数据

1.疏水参数计算参考值(XlogP):0.9

2.氢键供体数量:1

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积66.9

7.重原子数量:13

8.表面电荷:0

9.复杂度:253

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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