R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学

R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 基本信息

中文名称:
R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 
中文别名:
(+)-对溴四咪唑草酸盐;
R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 
英文名称:
R(+)-6-(4-Bromophenyl)-2,3,5,6-tetrahydroimidazo[2,1,b]thiazole oxalate
英文别名:
(+)-P-BROMOTETRAMISOLE OXALATE;
(+)-6(4-BROMOPHENYL)-2,3,5,6-TETRAHYDROIMIDAZO[2,1-B]THIAZOLE ETHANEDIOATE OXALATE SALT;
D-(+)-P-BROMOTETRAMISOLE OXALATE;
D-P-BROMOTETRAMISOLE OXALATE;
(+)-P-BROMOTETRAMISOLE OXALATE SALT;
(R)-(+) 4-BROMOTETRAMISOLE OXALATE;
(R)-6-(p-bromophenyl)-2,3,5,6-tetrahydroimidazo[2,1-b]thiazole oxalate;
PLUS-P-BROMOTETRAMISOLE OXALATE 
CAS No.:
71461-24-0
分 子 式:
C11H11BrN2S?C2H2O4
分 子 量:
373.22
精确分子量:
371.97800
PSA:
115.50000
EINECS:
275-471-0
分子结构式:
SDS:
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R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 制备方法及用途

制备方法

用于生化研究。

用途简介

用途

用于生化研究。    

R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 物化性质

外观与性状:
白色固体
密度:
1.69g/cm3
熔点:
192ºC (dec.)(lit.)
沸点:
388.6ºC at 760 mmHg
闪点:
188.8ºC
折射率:
1.75
存储条件/存储方法:

 本品应密封于4℃干燥避光保存。

稳定性相关:

常温常压下稳定

避光强氧化剂
其它信息:

1.      性状:结晶。

2.      密度(g/mL,25/4℃):未确定3.      相对蒸汽密度(g/mL,空气=1):未确定4.      熔点(ºC):192℃(分解)。5.      沸点(ºC,常压):未确定6.      沸点(ºC,5.2kPa):未确定7.      折射率:未确定8.      闪点(ºC):未确定9.      比旋光度(º):[α]D25+105°(C=0.5,水中)。10.   自燃点或引燃温度(ºC):未确定11.   蒸气压(kPa,25ºC):未确定12.   饱和蒸气压(kPa,60ºC):未确定13.   燃烧热(KJ/mol):未确定14.   临界温度(ºC):未确定15.   临界压力(KPa):未确定16.   油水(辛醇/水)分配系数的对数值:未确定17.   爆炸上限(%,V/V):未确定18.   爆炸下限(%,V/V):未确定19.   溶解性:未确定。

R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 安全信息

海关代码:
2934100090
安全说明:
S24/25

R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 MSDS

Name: d-(+)-p-Bromotetramisole oxalate 99% Material Safety Data Sheet
Synonym: None
CAS: 71461-24-0
Section 1 - Chemical Product   MSDS Name:d-(+)-p-Bromotetramisole oxalate 99% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
71461-24-0 D-(+)-p-bromotetramisole oxalate 99 275-471-0
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 71461-24-0: Personal Protective Equipment Eyes: Wear chemical splash goggles. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin. Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 192 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C11H11BrN2S.C2H2O4
Molecular Weight: 373.22

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 71461-24-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
D-(+)-p-bromotetramisole oxalate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 71461-24-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 71461-24-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 71461-24-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 海关数据

中国海关编码:2934100090

概述:
2934100090. 结构上含有一个非稠合噻唑环的化合物(不论是否氢化). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

R(+)-6-(4-溴苯基)-2,3,5,6-四氢咪唑并[2,1,b]噻唑草酸盐 分子结构与计算化学数据

计算化学数据

1、  疏水参数计算参考值(XlogP):2.5

2、  氢键供体数量:0

3、  氢键受体数量:2

4、  可旋转化学键数量:1

5、  互变异构体数量:

6、  拓扑分子极性表面积(TPSA):15.6

7、  重原子数量:15

8、  表面电荷:0

9、  复杂度:274

10、同位素原子数量:0

11、确定原子立构中心数量:1

12、不确定原子立构中心数量:0

13、确定化学键立构中心数量:0

14、不确定化学键立构中心数量:0

15、共价键单元数量:1

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产品介绍:
产品名称:(+)-对溴四咪唑草酸盐 Cas号:71461-24-0 纯度: 包装信息:洽谈 价格:洽谈
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