(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺 基本信息

中文名称:
(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺 
中文别名:
(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺;
(1S,2S)-N,N'-二甲基-1,2-二苯基-1,2-乙二胺 
英文名称:
1,2-Ethanediamine,N,N'-dimethyl-1,2-diphenyl-, (1S,2S)-
英文别名:
(1S,2S)-(-)-N,N'-DIMETHYL-1,2-DIPHENYL-1,2-ETHANE DIAMINE;
(1S,2S)-N,N'-bis(3',5'-di-tert-butylsalicylidene)-cyclohexane-1,2-diimine;
(1S,2S)-N,N'-bis[(3,5-di-tert-butyl-2-hydroxyphenyl)methylene]-1,2-cyclohexanediamine;
(1S,2S)-N1,N2-dimethyl-1,2-diphenylethane-1,2-diamine;
(1S,2S)-N,N'-dimethyl-1,2-diphenylethane-1,2-diamine;
(S,S)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE;
(1S,2S)-(-)-1,2-Bis(methylamino)-1,2-diphenylethane;
(S,S)-(+)-N,N'-BIS(3,5-DI-T-BU-SALICYL.);
(-)-(1S,2S)-N,N'-dimethyl-1,2-diphenyl-1,2-ethylenediamine;
(S,S)-JACOBSEN'S LIGAND;
(1S,2S)-(-)-N,N'-dimethyl-1,2-diphenyl-1,2-ethanediamine;
(-)-(S,S)-DMPEDA;
(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene);
N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine;
(S,S)-JACOBSEN LIGAND;
(S,S)-N,N'-bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediamine;
(S,S)-2,2'-[(1,2-cyclohexanediyl)bis(nitrilomethylidyne)]bis[4,6-di-tert-butylphenol];
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine(S,S)-Jacobsen Ligand;
(1S,2S)-(+)-1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE) 
CAS No.:
70749-06-3
分 子 式:
C16H20N2
分 子 量:
240.34
精确分子量:
240.16300
PSA:
24.06000
InChI:
The Key: BTHYVQUNQHWNLS-HZPDHXFCSA-N
风险术语:
R34
安全术语:
S26S45S36/S37/S39
分子结构式:
SDS:
查看

(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺 物化性质

外观与性状:
白色至淡黄色晶体或结晶粉末
熔点:
48-51ºC
沸点:
346.4ºC at 760 mmHg
闪点:
193.9ºC
存储条件/存储方法:

 

密闭于0-6 ºC阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):48-51

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺 安全信息

危险类别码:
R34
安全说明:
S26-S45-S36-S37-S39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:

(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺 MSDS

Name: (1S 2S)-(-)-N N -Dimethyl-1 2-Diphenyl-1 2 -Ethane Diamine 99% Material Safety Data Sheet
Synonym: None Known
CAS: 70749-06-3
Section 1 - Chemical Product   MSDS Name:(1S 2S)-(-)-N N -Dimethyl-1 2-Diphenyl-1 2 -Ethane Diamine 99% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
70749-06-3 (1S,2S)-(-)-N,N'-Dimethyl-1,2-Diphenyl 99% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Non-irritating to the eyes.
Skin:
Non-irritating to the skin.
Ingestion:
No hazard expected in normal industrial use. May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
No hazard expected in normal industrial use. May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 70749-06-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 48 - 50 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C16H20N2
Molecular Weight: 240.35

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 70749-06-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(1S,2S)-(-)-N,N'-Dimethyl-1,2-Diphenyl-1,2 -Ethane Diamine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 70749-06-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 70749-06-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 70749-06-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:76.75

2、   摩尔体积(m3/mol):235.0

3、   等张比容(90.2K):588.8

4、   表面张力(dyne/cm):39.3

5、   极化率10-24cm3):30.42

推荐供应商更多供应商>>

北京百灵威科技有限公司

产品介绍:
产品名称:(1S,2S)-N,N'-二甲基-1,2-二苯基-1,2-乙二胺 Cas号:70749-06-3 纯度:97% 包装信息:1g 价格:洽谈
联系方式:
联系人:翟先生 电话:18210857532 手机:18210857532

武汉倍欧药物化学有限公司

产品介绍:
产品名称:(1S,2S)-(-)-N,N-二甲基-1,2-二苯基-1,2-乙烷二胺 Cas号:70749-06-3 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:赵明 电话:027-59847525 手机:18627722880
QQ: 2241752642
微信二维码
电话: 19906633110