碘化镍水合物

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 表征图谱

碘化镍水合物 基本信息

中文名称:
碘化镍水合物 
中文别名:
碘化镍水合物 
英文名称:
Nickel iodide n-hydrate
英文别名:
Nickel iodide (NiI2), hexahydrate (8CI,9CI);
Nickel diiodide hexahydrate 
CAS No.:
7790-34-3
分 子 式:
NiI2.XH2O
分 子 量:
312.52
精确分子量:
419.80769
PSA:
55.38000
风险术语:
R45R61R42/43
安全术语:
S22S26S36/S37/S39
分子结构式:
SDS:
查看

碘化镍水合物 制备方法及用途

制备方法

将NiI2水溶液蒸发至成浆状,滤出其中的六水合物晶体,抽干。或先用制备无水NiI2相同的方法制取,但免去在140℃干燥这一步。

合成制备方法

将NiI2水溶液蒸发至成浆状,滤出其中的六水合物晶体,抽干。或先用制备无水NiI2相同的方法制取,但免去在140℃干燥这一步。

用途简介

碘化镍水合物 物化性质

稳定性相关:

在空气中迅速潮解变成褐色并游离出碘。加热至43℃时,尚可存在,但在水浴上加热即变成无水物。

其它信息:

性状:蓝绿色结晶。

密度(g/mL,25/4℃): 不可用

相对蒸汽密度(g/mL,空气=1):不可用

熔点(ºC):不可用

沸点(ºC,常压):不可用

沸点(ºC,5.2kPa): 不可用

折射率: 不可用

闪点(ºC): 不可用

比旋光度(º): 不可用

自燃点或引燃温度(ºC): 不可用

蒸气压(kPa,25ºC): 不可用

饱和蒸气压(kPa,60ºC): 不可用

燃烧热(KJ/mol):不可用

临界温度(ºC): 不可用

临界压力(KPa): 不可用

油水(辛醇/水)分配系数的对数值:不可用 

爆炸上限(%,V/V):不可用

爆炸下限(%,V/V): 不可用

溶解性:不可用

碘化镍水合物 安全信息

危险类别码:
42/43-45-61
安全说明:
22-26-36/37/39
安全标志:
S22:不要吸入粉尘。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

碘化镍水合物 毒理性

毒理学数据:

急性毒性:不可用。

生态数据:

1、其它有害作用:该物质对环境可能有危害,对水体应给予特别注意。

碘化镍水合物 MSDS


Section 1: Product Identification
   Chemical Name:       Nickel (II) iodide hydrate    
   CAS Registry Number:       7790-34-3    
   Formula:       NiI2.XH2O    
   EINECS Number:       none    
   Chemical Family:       metal halide    
   Synonym:       Nickel diiodide hydrate, Nickelous iodide hydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       7790-34-3       100%       0.1mg/m3 (as Ni)       1mg/m3 (as Ni)    

Section 3: Hazards Identification
   Ingestion of nickel salts may cause intestinal disorders, convulsions, and asphyxia. Irritating to skin, eyes and
   Emergency Overview:
   respiratory tract. May cause cancer.
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust.    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Irritating to skin. May cause redness, itching, pimples, boils, hives and blisters. Prolonged contact may lead to
   Skin Contact:
   dermatitis.
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion of nickel salts may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and
   Ingestion:
   convulsions.
   Irritating to skin, eyes and respiratory tract. May cause intestinal disorders, convulsions, asphyxia,
   Acute Health Affects:
   sensitization dermatitis, allergic asthma and pneumonitis.
   May cause cancer. Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running
   Chronic Health Affects:
   nose, headache and irritation of mucous membranes.
   NTP:       Yes    
   IARC:       Yes    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       None. Material is non-flammable.    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       none    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
   Spill and Leak Procedures:
   inert material and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store solid in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       green xtl.    
   Molecular Weight:       312.52    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals, bromine and chlorine    
   Decomposition Products:       water and metal iodide    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       Carcinogen (as Ni)    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See Category Code N495 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

碘化镍水合物 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:1

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积1

7.重原子数量:4

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

碘化镍水合物 表征图谱

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