三叔丁基硼酸

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

三叔丁基硼酸 基本信息

中文名称:
三叔丁基硼酸 
中文别名:
三叔丁基硼酸酯;
三叔丁基硼酸 
英文名称:
Boric acid,tris(1,1-dimethylethyl) ester
英文别名:
tritert-butyl borate;
Tris(tert-butyl) borate;
Borsaeure-tri-tert-butylester;
Tris(tert-butyloxy)borane;
Tri-tert-butoxyborane;
Boric acid (H3BO3),tri-tert-butyl ester;
tri-t-butyl borate;
B(tert.-OC4H9)3;
boric acid tri-tert-butyl ester;
Boron tert-butoxide;
Tri-tert-butyl borate 
CAS No.:
7397-43-5
分 子 式:
C12H27BO3
分 子 量:
230.15
精确分子量:
230.20500
PSA:
27.69000
MDL:
MFCD00009652
InChI:
The Key: ZMCWFMOZBTXGKI-UHFFFAOYSA-N
风险术语:
10
安全术语:
S16S33
分子结构式:
SDS:
查看

三叔丁基硼酸 物化性质

外观与性状:
透明无色液体
密度:
0.811 g/mL at 25ºC(lit.)
熔点:
18-19ºC(lit.)
沸点:
175.3ºC at 760 mmHg
闪点:
29.4ºC
折射率:
n20/D 1.389(lit.)
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房。远离火源,易燃易爆区。常用氮气保护。

稳定性相关:

常温常压下稳定,避免与强氧化剂接触。

三叔丁基硼酸 安全信息

包装等级:
III
风险类别:
3.2
海关代码:
2920909090
危险类别码:
R10
安全说明:
16-33
安全标志:
S16:远离火源。
S33:采取防护措施防止静电发生。

三叔丁基硼酸 MSDS

Name: Tri-tert-butyl borate 98% Material Safety Data Sheet
Synonym: Tri-tert-butoxyboran
CAS: 7397-43-5
Section 1 - Chemical Product   MSDS Name:Tri-tert-butyl borate 98% Material Safety Data Sheet
Synonym:Tri-tert-butoxyboran

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7397-43-5 Tri-tert-butyl borate 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: 10

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable.The toxicological properties of this material have not been fully investigated.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Can burn in a fire, releasing toxic vapors. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Flammable liquid and vapor.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Container should be opened by a technically qualified person. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep away from heat, sparks and flame.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 7397-43-5: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 101 deg C @ 74.00mm Hg
Freezing/Melting Point: 18 - 19 deg C
Autoignition Temperature: Not available.
Flash Point: 29 deg C ( 84.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .8110g/cm3
Molecular Formula: C12H27BO3
Molecular Weight: 230.15

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
May decompose on exposure to moist air or water. Moisture sensitive.
Conditions to Avoid:
Ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of boron.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 7397-43-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tri-tert-butyl borate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 7397-43-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7397-43-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7397-43-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

三叔丁基硼酸 海关数据

中国海关编码:2920909090

概述:
2920909090 其他无机酸酯(不包括卤化氢的酯)(包括其盐及它们的卤化,磺化,硝化和亚硝化衍生物)。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

三叔丁基硼酸 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:6

5.互变异构体数量:无

6.拓扑分子极性表面积27.7

7.重原子数量:16

8.表面电荷:0

9.复杂度:170

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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产品介绍:
产品名称:三叔丁基硼酸酯 Cas号:7397-43-5 纯度:98% 包装信息:50gea 价格:1,688.0元
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南京肽业生物科技有限公司

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产品名称:7397-43-5 Cas号:7397-43-5 纯度:98% 包装信息:管g 价格:洽谈
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郑州杰克斯化工有限公司

产品介绍:
产品名称:三叔丁基硼酸 Cas号:7397-43-5 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:许伟伟 电话:0371-86259281 15981966935 手机:15981966935