硝酸镥六水

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

硝酸镥六水 基本信息

中文名称:
硝酸镥六水 
中文别名:
硝酸镥六水;
无水硝酸镥 
英文名称:
Nitric acid,lutetium(3+) salt (3:1)
英文别名:
LUTETIUM NITRATE HEXAHYDRATE;
lutetium trinitrate;
Trinitric acid lutetium salt;
Lutecium nitrate;
Lutetium nitrate hydrate/;
LUTETIUM NITRATE TETRAHYDRATE;
Nitric acid lutetium 
CAS No.:
10099-67-9
分 子 式:
HNO3.1/3Lu
分 子 量:
469.07
精确分子量:
432.94600
PSA:
243.56000
EINECS:
233-241-7
风险术语:
R8R36/37/38
安全术语:
S17S36/S37/S39
分子结构式:
SDS:
查看

硝酸镥六水 制备方法及用途

制备方法

1.加热下,将过量的硝酸镥与浓硝酸作用,反应结束后,将未反应的氧化物过滤分离。冷却所得到的硝酸盐溶液,即得到五水硝酸镥。 2.将硝酸镥溶于稍过量的8mol/L的硝酸中,蒸发浓缩至呈糊状,用稀硝酸再结晶二次。然后放在50%~60%硫酸干燥器中进行干燥。

合成制备方法

1.加热下,将过量的硝酸镥与浓硝酸作用,反应结束后,将未反应的氧化物过滤分离。冷却所得到的硝酸盐溶液,即得到五水硝酸镥。

2.将硝酸镥溶于稍过量的8mol/L的硝酸中,蒸发浓缩至呈糊状,用稀硝酸再结晶二次。然后放在50%~60%硫酸干燥器中进行干燥。

用途简介

硝酸镥六水 物化性质

沸点:
83ºC at 760 mmHg
蒸汽压:
49.8mmHg at 25°C
存储条件/存储方法:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物分开存放
稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4℃):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

硝酸镥六水 安全信息

包装等级:
II
风险类别:
5.1
危险类别码:
R8
安全说明:
17-36/37/39
安全标志:
S17:远离可燃物质。
:

硝酸镥六水 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OK8925000
CAS REGISTRY NUMBER :
10099-67-9
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
N3-O9.Lu
MOLECULAR WEIGHT :
361.00
WISWESSER LINE NOTATION :
LU N-O3*3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
258 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
223 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975 *** REVIEWS *** TOXICOLOGY REVIEW JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 54,663,1965
毒理学数据:

试验方法:腹腔
摄入剂量: 258毫克/千克
测试对象:啮齿动物-鼠
毒性类型:急性
毒性作用: 1.Details的毒副作用没有报告以外的其他致死剂量值
试验2
试验方法:腹腔
摄入剂量: 223毫克/千克
测试对象:啮齿动物-鼠
毒性类型:急性
毒性作用: 1.Details的毒副作用没有报告以外的其他致死剂量值

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

硝酸镥六水 MSDS


Section 1: Product Identification
   Chemical Name:       Lutetium (III) nitrate hydrate(99.9%-Lu) (REO)    
   CAS Registry Number:       10099-67-9    
   Formula:       Lu(NO3)3.XH2O    
   EINECS Number:       none    
   Chemical Family:       metal nitrate salts    
   Synonym:       Nitric acid, lutetium(3+) salt    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       10099-67-9       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes slight to mild irritation of the eyes    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Metal nitrates can be oxidizers. Contact with strong reducing agents could lead to fires and/or explosions.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Keep away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       360.98    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       very soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high
   Conditions to Avoid:
   temperatures.
   Incompatibility:       reducing agents, organic matter, phosphorus and sulfur    
   Decomposition Products:       nitrogen oxides and lutetium salts    

SECTION 11: Toxicological Information
   RTECS Data:       Intraperitoneal (rat); LD50: 258 mg/kg. Intraperitoneal (mouse); LD50: 223 mg/kg.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Nitrates, Inorganic, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1477    
   Shipping Name (IATA):       Nitrates, Inorganic, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1477    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title Compound: See Category Code N511 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

硝酸镥六水 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据

1、   疏水参数计算参考值(XlogP):无可用

2、   氢键供体数量:0

3、   氢键受体数量:9

4、   可旋转化学键数量:0

5、   拓扑分子极性表面积(TPSA):199

6、   重原子数量:13

7、   表面电荷:0

8、   复杂度:18.8

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:4

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