亚麻酰基氯

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品
  • 下游产品

亚麻酰基氯 基本信息

中文名称:
亚麻酰基氯 
中文别名:
亚麻酰基氯;
cis-Linolenoyl chloride 
英文名称:
9,12,15-Octadecatrienoylchloride, (9Z,12Z,15Z)-
英文别名:
LINOLENOYL CHLORIDE;
Linolenoyl chloride,tech.;
cis,cis,cis-9,12,15-octadecatrienoyl chloride;
Linolensaeurechlorid;
linolenic acid chloride 
CAS No.:
59044-29-0
分 子 式:
C18H29ClO
分 子 量:
296.88
精确分子量:
296.19100
PSA:
17.07000
MDL:
MFCD00041727
EINECS:
261-572-7
InChI:
The Key: MRKXCQPDRPTZCG-PDBXOOCHSA-N
风险术语:
R34
安全术语:
S26S45S36/S37/S39
分子结构式:
SDS:
查看

亚麻酰基氯 物化性质

密度:
0.942g/cm3
沸点:
382.9ºC at 760 mmHg
闪点:
184.8ºC
折射率:
1.478-1.48
存储条件/存储方法:

 

 密闭于阴凉干燥环境中
稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.      性状:无可用

2.      密度(g/mL,25/4):无可用3.      相对蒸汽密度(g/mL,空气=1):无可用4.      熔点(ºC):无可用5.      沸点(ºC,常压):无可用6.      沸点(ºC,5.2kPa):无可用7.      折射率:1.478-1.488.      闪点(ºC):无可用9.      比旋光度(º):无可用10.   自燃点或引燃温度(ºC):无可用11.   蒸气压(kPa,25ºC):无可用12.   饱和蒸气压(kPa,60ºC):无可用13.   燃烧热(KJ/mol):无可用14.   临界温度(ºC):无可用15.   临界压力(KPa):无可用16.   油水(辛醇/水)分配系数的对数值:无可用17.   爆炸上限(%,V/V):无可用18.   爆炸下限(%,V/V):无可用19.   溶解性:无可用

亚麻酰基氯 安全信息

危险类别码:
34
安全说明:
45-36/37/39-26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:

亚麻酰基氯 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

亚麻酰基氯 MSDS

Name: Linolenoyl Chloride (Pract) Material Safety Data Sheet
Synonym: None known
CAS: 59044-29-0
Section 1 - Chemical Product   MSDS Name:Linolenoyl Chloride (Pract) Material Safety Data Sheet
Synonym:None known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
59044-29-0 9,12,15-Octadecatrienoyl Chloride, (Z, ca 100 261-572-7
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 59044-29-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: chlorine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C18H29ClO
Molecular Weight: 296.88

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, chlorine, oxides of chlorine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 59044-29-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
9,12,15-Octadecatrienoyl Chloride, (Z,Z,Z)- - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 59044-29-0: No information available.
Canada
CAS# 59044-29-0 is listed on Canada's DSL List.
CAS# 59044-29-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 59044-29-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

亚麻酰基氯 分子结构与计算化学数据

分子结构数据

1、  摩尔折射率:90.49

2、  摩尔体积(m3/mol):315.0

3、  等张比容(90.2K):753.4

4、  表面张力(dyne/cm):32.7

5、  极化率10-24cm3):35.87

计算化学数据

1、  疏水参数计算参考值(XlogP):6.9

2、  氢键供体数量:0

3、  氢键受体数量:1

4、  可旋转化学键数量:13

5、  拓扑分子极性表面积(TPSA):17.1

6、  重原子数量:20

7、  表面电荷:0

8、  复杂度:303

9、  同位素原子数量:0

10、  确定原子立构中心数量:0

11、  不确定原子立构中心数量:0

12、  确定化学键立构中心数量:3

13、  不确定化学键立构中心数量:0

14、  共价键单元数量:1

亚麻酰基氯 上游产品

亚麻酰基氯 下游产品

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