1,3:2,5:4,6-Tri-O-methylene-D-mannitol

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

1,3:2,5:4,6-Tri-O-methylene-D-mannitol 基本信息

中文名称:
1,3:2,5:4,6-Tri-O-methylene-D-mannitol 
中文别名:
1,3:2,5:4,6-三-o-亚甲基-D-甘露糖醇;
1,3:2,5:4,6-三-O-亚甲基-D-甘露糖醇;
1,3:2,5:4,6-三-O-亚甲基-D-甘露醇 
英文名称:
D-Mannitol,1,3:2,5:4,6-tri-O-methylene- (9CI)
英文别名:
1,3:2,5:4,6-TRI-O-METHYLENE-D-MANNITOL;
1-O,3-O:2-O,5-O:4-O,6-O-Trismethylene-D-mannitol;
1,3:2,5:4,6-Tri-O-methylene-D-mannitol,98% 
CAS No.:
5434-31-1
分 子 式:
C9H14O6
分 子 量:
218.2
精确分子量:
218.07900
PSA:
55.38000
MDL:
MFCD00022238
EINECS:
226-600-4
InChI:
The Key: QQQVHHWRMWBKNS-FNCVBFRFSA-N
安全术语:
S24/25
分子结构式:
SDS:
查看

1,3:2,5:4,6-Tri-O-methylene-D-mannitol 物化性质

密度:
1.251g/cm3
熔点:
232-233ºC
沸点:
321.7ºC at 760mmHg
闪点:
135.5ºC
折射率:
1.454
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房。

稳定性相关:

常温常压下稳定,避免与不相容材料接触。

1,3:2,5:4,6-Tri-O-methylene-D-mannitol 安全信息

海关代码:
2932999099
安全说明:
S24/25

1,3:2,5:4,6-Tri-O-methylene-D-mannitol MSDS

Name: 1 3:2 5:4 6-tri-o-methylene-d-mannitol 98% Material Safety Data Sheet
Synonym:
CAS: 5434-31-1
Section 1 - Chemical Product   MSDS Name:1 3:2 5:4 6-tri-o-methylene-d-mannitol 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
5434-31-1 1,3:2,5:4,6-TRI-O-METHYLENE-D-MANNITOL 98% 226-600-4
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5434-31-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 232 - 233 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 218.21

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 5434-31-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,3:2,5:4,6-TRI-O-METHYLENE-D-MANNITOL - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 5434-31-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5434-31-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5434-31-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

1,3:2,5:4,6-Tri-O-methylene-D-mannitol 海关数据

中国海关编码:2932999099

概述:
2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1,3:2,5:4,6-Tri-O-methylene-D-mannitol 分子结构与计算化学数据

计算化学数据

1、   疏水参数计算参考值(XlogP):-0.8

2、   氢键供体数量:0

3、   氢键受体数量:6

4、   可旋转化学键数量:0

5、   互变异构体数量:

6、   拓扑分子极性表面积(TPSA):55.4

7、   重原子数量:15

8、   表面电荷:0

9、   复杂度:201

10、   同位素原子数量:0

11、   确定原子立构中心数量:4

12、   不确定原子立构中心数量:0

13、   确定化学键立构中心数量:0

14、   不确定化学键立构中心数量:0

15、   共价键单元数量:1

1,3:2,5:4,6-Tri-O-methylene-D-mannitol 上游产品

1,3:2,5:4,6-Tri-O-methylene-D-mannitol 下游产品

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