(3,3-二甲基-1-丁炔)六羰基二钴

  • 基本信息
  • 物化性质
  • 毒理性
  • MSDS
  • 结构与计算化学

(3,3-二甲基-1-丁炔)六羰基二钴 基本信息

中文名称:
(3,3-二甲基-1-丁炔)六羰基二钴 
中文别名:
(3,3-二甲基-1-丁炔)六羰基二钴 
英文名称:
Cobalt, hexacarbonyl[m-[(1,2-h:1,2-h)-3,3-dimethyl-1-butyne]]di-, (Co-Co) (9CI)
英文别名:
(3,3-DIMETHYL-1-BUTYNE)DICOBALT HEXACARBONYL;
Dicobalt hexacarbonyl t-butylacetylene 
CAS No.:
56792-69-9
分 子 式:
C12H10Co2O6
分 子 量:
368.07
精确分子量:
367.91400
PSA:
0.00000
InChI:
The Key: ZJCVAZZKJPVOPY-UHFFFAOYSA-N
分子结构式:
SDS:
查看

(3,3-二甲基-1-丁炔)六羰基二钴 物化性质

存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

(3,3-二甲基-1-丁炔)六羰基二钴 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

(3,3-二甲基-1-丁炔)六羰基二钴 MSDS


Section 1: Product Identification
   Chemical Name:       (3,3-Dimethyl-1-butyne)dicobalt hexacarbonyl, 98%    
   CAS Registry Number:       56792-69-9    
   Formula:       Co2O6C13H10    
   EINECS Number:       none    
   Chemical Family:       metalocene    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       56792-69-9       100%       0.02mg/m3 (as Co)       no data    

Section 3: Hazards Identification
   Harmful by inhalation and if swallowed. Inhalation can lead to headaches and dizziness. May cause
   Emergency Overview:
   sensitization by skin contact. Limited evidence of a carcinogenic effect.
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       May cause mild irritation to the eyes.    
   Skin Contact:       May cause mild irritation to the skin. May cause sensitization by skin contact.    
   Inhalation:       Harmful by inhalation. Inhalation could lead to dizziness and headache.    
   Ingestion:       Harmful if swallowed.    
   Harmful by inhalation and if swallowed. Inhalation can lead to headaches and dizziness. May cause
   Acute Health Affects:
   sensitization by skin contact.
   Chronic Health Affects:       Limited evidence of a carcinogenic effect.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire, this material may emit toxic carbon monoxide, carbon dioxide and cobalt oxide dust.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable liquid. No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Prolonged exposure to air may
   Handling and Storage:
   result in degradation of the product. Keep containers tightly sealed.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       dark red liquid    
   Molecular Weight:       368.07    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       prolonged contact with air    
   Incompatibility:       oxidizing agents and halogens    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, cobalt oxides    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Flammable liquids, N.O.S.    
   Hazard Class (CFR):       3    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       III    
   UN ID Number (CFR):       UN# 1993    
   Shipping Name (IATA):       Flammable liquid, N.O.S    
   Hazard Class (IATA):       3    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       III    
   UN ID Number (IATA):       UN# 1993    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

(3,3-二甲基-1-丁炔)六羰基二钴 分子结构与计算化学数据

分子结构数据

1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

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