4-十二烷基苯酚

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

4-十二烷基苯酚 基本信息

中文名称:
4-十二烷基苯酚 
中文别名:
4-十二烷基苯酚;
对十二烷基苯酚 
英文名称:
Phenol, 4-dodecyl-
英文别名:
4-Dodecylphenol;
4-DODECYLPHENOL 
CAS No.:
104-43-8
分 子 式:
C18H30O
分 子 量:
262.43
精确分子量:
262.23000
PSA:
20.23000
MDL:
MFCD00039521
EINECS:
248-312-8
InChI:
The Key: KJWMCPYEODZESQ-UHFFFAOYSA-N
危险品标志:
CorrosiveC
风险术语:
R34
安全术语:
S26;S36/37/39;S45;
分子结构式:
SDS:
查看

4-十二烷基苯酚 物化性质

外观与性状:
稻黄色的液体
密度:
0.94 g/mL at 25ºC(lit.)
沸点:
310-335ºC(lit.)
闪点:
>230 °F
折射率:
n20/D 1.503(lit.)
蒸汽压:
3.3E-06mmHg at 25°C
其它信息:

1.沸点(ºC):310~335

2.闪点(ºC):>230

4-十二烷基苯酚 安全信息

危险类别码:
R34
安全说明:
26-36/37/39-45
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
C: Corrosive;

4-十二烷基苯酚 MSDS

Name: Dodecylphenol mixture of isomers Material Safety Data Sheet
Synonym: None
CAS: 104-43-8
Section 1 - Chemical Product   MSDS Name:Dodecylphenol mixture of isomers Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
104-43-8 Phenol, 4-dodecyl- >90 203-202-9
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 104-43-8: CAS# 5284-29-7: CAS# 27193-86-8: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Viscous liquid
Color: Clear
Odor: phenolic
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 310-335 deg C @ 760 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 163 deg C ( 325.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: 0.945
Molecular Formula: C18H30O
Molecular Weight: 262.44

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 104-43-8 unlisted.
CAS# 5284-29-7 unlisted.
CAS# 27193-86-8: SL3675000 LD50/LC50:
Not available.
Not available.
CAS# 27193-86-8: Draize test, rabbit, eye: 100 uL Moderate; Draize test, rabbit, skin: 500 uL Severe; Oral, rat: LD50 = 2100 mg/kg; Skin, rabbit: LD50 = 5 mL/kg.
Carcinogenicity:
Phenol, 4-dodecyl- - Not listed by ACGIH, IARC, or NTP.
Phenol, 2-dodecyl- - Not listed by ACGIH, IARC, or NTP.
Dodecylphenol, mixed isomers - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 104-43-8: No information available.
CAS# 5284-29-7: No information available.
CAS# 27193-86-8: 2
Canada
CAS# 104-43-8 is listed on Canada's DSL List.
CAS# 27193-86-8 is listed on Canada's DSL List.
CAS# 104-43-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 5284-29-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 27193-86-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104-43-8 is listed on the TSCA inventory.
CAS# 5284-29-7 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 27193-86-8 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4-十二烷基苯酚 分子结构与计算化学数据

分子结构数据

1、  摩尔折射率:84.01

2、  摩尔体积(cm3/mol):285.7

3、  等张比容(90.2K):696.7

4、  表面张力(dyne/cm):35.3

5、  极化率(10-24cm3):33.30

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