3-氯-2,6-二氟苯酚

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

3-氯-2,6-二氟苯酚 基本信息

中文名称:
3-氯-2,6-二氟苯酚 
中文别名:
3-氯-2,6-二氟苯酚;
3-氯-2,6-二氟苯酚, 97+% 
英文名称:
Phenol,3-chloro-2,6-difluoro-
英文别名:
3-Chloro-2,6-difluorophenol;
3-chloro-2,6-difluoro-phenol 
CAS No.:
261762-51-0
分 子 式:
C6H3ClF2O
分 子 量:
164.5377
精确分子量:
163.98400
PSA:
20.23000
MDL:
MFCD01631330
InChI:
The Key: CCLYWHXHYLQWQK-UHFFFAOYSA-N
风险术语:
R20/21/22R36/37/38
安全术语:
S26S36/S37/S39
分子结构式:
SDS:
查看

3-氯-2,6-二氟苯酚 物化性质

密度:
1.52g/cm3
沸点:
168.3ºC at 760mmHg
闪点:
55.6ºC
折射率:
1.522
蒸汽压:
1.23mmHg at 25°C
存储条件/存储方法:

保存方法:密闭,阴凉,通风干燥处

稳定性相关:

避氧化物

其它信息:

1.      性状:气味类似酚的无色液体

2.      密度(g/mL):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):未确定

5.      沸点(ºC,常压):未确定

6.      沸点(ºC60mmHg):未确定

7.      折射率:未确定

8.      闪点(ºF):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:不能拌和或难以拌和

3-氯-2,6-二氟苯酚 安全信息

包装等级:
III
海关代码:
2908199090
危险类别码:
R20/21/22
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
T: Toxic;

3-氯-2,6-二氟苯酚 毒理性

生态数据:

1、其它有害作用:通常对水是稍微危害的,若无政府许可,勿将材料排入周围环境。

3-氯-2,6-二氟苯酚 MSDS

  Material Safety Data Sheet

Section 1. Identification of the substance
    Product Name:      3-Chloro-2,6-difluorophenol    
    Synonyms:

Section 2. Hazards identification
    Harmful by inhalation, in contact with skin, and if swallowed.
    H301:        Toxic if swallowed    
    H311:        Toxic in contact with skin    
    H314:        Causes severe skin burns and eye damage    
    H318:        Causes serious eye damage    
    H411:        Toxic to aquatic life with long lasting effects    
    H401:        Toxic to aquatic life    
    P260:        Do not breathe dust/fume/gas/mist/vapours/spray    
    P301+P310:        IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician    
    P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
    water/shower
    P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
    and easy to do – continue rinsing
    P361:        Remove/Take off immediately all contaminated clothing    
    P405:        Store locked up    

Section 3. Composition/information on ingredients.
    Ingredient name:        3-Chloro-2,6-difluorophenol    
    CAS number:        261762-51-0    

Section 4. First aid measures
    Skin contact:        Immediately wash skin with copious amounts of water for at least 15 minutes while removing    
    contaminated clothing and shoes. If irritation persists, seek medical attention.
    Eye contact:        Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate    
    flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
    attention.
    Inhalation:        Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.    
    Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.
    Ingestion:

Section 5. Fire fighting measures
    In the event of a fire involving this material, alone or in combination with other materials, use dry
    powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
    should be worn.

Section 6. Accidental release measures
    Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
    standards.
    Respiratory precaution:        Wear approved mask/respirator    
    Hand precaution:        Wear suitable gloves/gauntlets    
    Skin protection:        Wear suitable protective clothing    
    Eye protection:        Wear suitable eye protection    
    Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
    for disposal. See section 12.
    Environmental precautions: Do not allow material to enter drains or water courses.

Section 7. Handling and storage
    This product should be handled only by, or under the close supervision of, those properly qualified
    Handling:
    in the handling and use of potentially hazardous chemicals, who should take into account the fire,
    health and chemical hazard data given on this sheet.
    Storage:        Store in closed vessels.    

Section 8. Exposure Controls / Personal protection
    Engineering Controls: Use only in a chemical fume hood.
    Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
    General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section 9. Physical and chemical properties
    Appearance:        Not specified    
    Boiling point:        No data    
    Melting point:        No data    
    Flash point:        No data    
    Density:        No data    
    Molecular formula:        C6H3ClF2O    
    164.5
    Molecular weight:

Section 10. Stability and reactivity
    Conditions to avoid: Heat, flames and sparks.
    Materials to avoid: Oxidizing agents.
    Possible hazardous combustion products: Carbon monoxide, hydrogen chloride, hydrogen fluoride.

Section 11. Toxicological information
    No data.

Section 12. Ecological information
    No data.

Section 13. Disposal consideration
    Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
    disposal authority, in accordance with national and regional regulations.

Section 14. Transportation information
    UN Number:        UN3265 Class: 8 Packing group: III    
    Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (3-Chloro-2,6-difluorophenol)

Section 15. Regulatory information
    No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
    302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
    Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

3-氯-2,6-二氟苯酚 海关数据

中国海关编码:2908199090

概述:
HS:2908199090 其他酚及酚醇的仅含卤素取代基的衍生物及其盐 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

3-氯-2,6-二氟苯酚 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):2.4

2.氢键供体数量:1

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:3

6.拓扑分子极性表面积20.2

7.重原子数量:10

8.表面电荷:0

9.复杂度:122

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

3-氯-2,6-二氟苯酚 上游产品

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