2,2-双(二环己膦基)-1,1-联苯

  • 基本信息
  • 物化性质
  • 毒理性
  • MSDS
  • 结构与计算化学

2,2-双(二环己膦基)-1,1-联苯 基本信息

中文名称:
2,2-双(二环己膦基)-1,1-联苯 
中文别名:
2,2-双(二环己膦基)-1,1-联苯;
2,2' - 双(二环己基)-1,1' - 联苯;
1,1'-联苯-2,2'-二基双(二环己基膦) 
英文名称:
Phosphine,1,1'-[1,1'-biphenyl]-2,2'-diylbis[1,1-dicyclohexyl-
英文别名:
dicyclohexyl-[2-(2-dicyclohexylphosphanylphenyl)phenyl]phosphane;
2,2'-BIS(DICYCLOHEXYLPHOSPHINO)-1,1'-BIPHENYL;
2,2'-BIS(DICYCLOHEXYLPHOSPHINO)BIPHENYL;
2,2'-Bis(dicyclohexylphosphino)-1,1'-biphenyl,min.97%;
2,2''-BIS(DICYCLOHEXYLPHOSPHINO)-1,1''-BIPHENYL, MIN. 97%;
1,1'-Biphenyl-2,2'-diylbis(dicyclohexylphosphine) 
CAS No.:
255897-36-0
分 子 式:
C36H52P2
分 子 量:
546.75
精确分子量:
546.35400
PSA:
27.18000
InChI:
The Key: BSSFMHHLTVJPGW-UHFFFAOYSA-N
分子结构式:
SDS:
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2,2-双(二环己膦基)-1,1-联苯 物化性质

存储条件/存储方法:

 

 密封于阴凉干燥环境中
稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.      性状:无可用

2.      密度(g/mL,25/4):无可用3.      相对蒸汽密度(g/mL,空气=1):无可用4.      熔点(ºC):无可用5.      沸点(ºC,常压):无可用6.      沸点(ºC,5.2kPa):无可用7.      折射率:无可用8.      闪点(ºC):无可用9.      比旋光度(º):无可用10.   自燃点或引燃温度(ºC):无可用11.   蒸气压(kPa,25ºC):无可用12.   饱和蒸气压(kPa,60ºC):无可用13.   燃烧热(KJ/mol):无可用14.   临界温度(ºC):无可用15.   临界压力(KPa):无可用16.   油水(辛醇/水)分配系数的对数值:无可用17.   爆炸上限(%,V/V):无可用18.   爆炸下限(%,V/V):无可用19.   溶解性:无可用

2,2-双(二环己膦基)-1,1-联苯 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

2,2-双(二环己膦基)-1,1-联苯 MSDS


Section 1: Product Identification
   Chemical Name:       2,2'-Bis(dicyclohexylphosphino)-1,1'-biphenyl, min. 97%    
   CAS Registry Number:       255897-36-0    
   Formula:       C36H52P2    
   EINECS Number:       none    
   Chemical Family:       organophosphine ligand    
   Synonym:       2,2'-Bis-dicyclohexylphosphanyl-biphenyl    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       255897-36-0       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes irritation to eyes    
   Skin Contact:       Causes irritation to skin    
   Inhalation:       Inhalation of dust is irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unususal fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Keep in a cool, dry, well ventilated place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white to pale yellow powder    
   Molecular Weight:       546.75    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents, halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, phosphorus pentoxide, organic fumes    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

2,2-双(二环己膦基)-1,1-联苯 分子结构与计算化学数据

分子结构数据

1摩尔折射率:无可用

2、  摩尔体积(cm3/mol):无可用       

3、  等张比容(90.2K):无可用

4、  表面张力(dyne/cm):无可用

5、  极化率:无可用

计算化学数据

1.疏水参数计算参考值(XlogP):9.9

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:7

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:38

8.表面电荷:0

9.复杂度:573

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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产品介绍:
产品名称:2,2-双(二环己膦基)-1,1-联苯 Cas号:255897-36-0 纯度: 包装信息:洽谈 价格:洽谈
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