氯冉酸钡三水

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

氯冉酸钡三水 基本信息

中文名称:
氯冉酸钡三水 
中文别名:
氯冉酸钡三水;
2,5-Dichloro-3,6-dihydroxy-1,4-benzoquinone barium salt 
英文名称:
2,5-Cyclohexadiene-1,4-dione,2,5-dichloro-3,6-dihydroxy-, barium salt, hydrate (1:1:3)
英文别名:
CHLORANILIC ACID BARIUM SALT TRIHYDRATE;
CHLORANILIC ACID,BARIUM SALT;
Chloranilic acid trihydrate barium salt;
BARIUM CHLORANILATE TRIHYDRATE;
BARIUM CHLOROANILATE TRIHYDRATE;
2,5-DICHLORO-3,6-DIHYDROXY-1,4-BENZOQUINONE BARIUM SALT TRIHYDRATE 
CAS No.:
32458-20-1
分 子 式:
C6H2Cl2O4.Ba.3H2O
分 子 量:
398.34
精确分子量:
397.85400
PSA:
80.29000
MDL:
MFCD00150175
EINECS:
236-567-8
BRN:
6463654
风险术语:
R20/22
安全术语:
S28
分子结构式:
SDS:
查看

氯冉酸钡三水 物化性质

沸点:
300.3ºC at 760mmHg
闪点:
135.4ºC
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

 

遵照规定使用和储存则不会分解。
其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

氯冉酸钡三水 安全信息

危险类别码:
20/22
安全说明:
28
安全标志:
S28:接触皮肤之后,立即使用大量皂液洗涤。
危险标志:
Xn: Harmful;

氯冉酸钡三水 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

氯冉酸钡三水 MSDS


Section 1. Chemical Product and Company Identification
    Barium Chloranilate, Trihydrate
    Common Name/
    Trade Name
    Barium Chloranilate, Trihydrate
    CARCINOGENIC EFFECTS: Not available.
    Potential Chronic Health
    Effects        MUTAGENIC EFFECTS: Not available.    
    TERATOGENIC EFFECTS: Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    The substance may be toxic to kidneys, the nervous system, liver, heart, spleen, gastrointestinal tract, bone
    marrow.
    Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
    Skin Contact        Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.    
    Cold water may be used.
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Not available.
    Products of Combustion
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Special Remarks on        Not available.    
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards
    Barium Chloranilate, Trihydrate

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill        Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water    
    on the contaminated surface and allow to evacuate through the sanitary system.

Section 7. Handling and Storage
    Precautions        Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear    
    suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label.
    Keep away from incompatibles such as oxidizing agents.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area.    

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.    
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Powdered solid.)        Odor        Odorless.    
    Not available.
    Taste
    Molecular Weight        398.35 g/mole    
    Yellow or brown.
    Color
    pH (1% soln/water)        Not available.    
    Boiling Point        Not available.    
    Melting Point        >300°C (572°F)    
    Critical Temperature        Not available.    
    Specific Gravity        Not available.    
    Not applicable.
    Vapor Pressure
    Vapor Density        Not available.    
    Not available.
    Volatility
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        Not available.    
    Ionicity (in Water)        Not available.    
    Dispersion Properties        See solubility in water.    
    Solubility        Soluble in cold water, hot water.    
    Barium Chloranilate, Trihydrate

Section 10. Stability and Reactivity Data
    The product is stable.
    Stability
    Instability Temperature        Not available.    
    Dust generation, incompatible materials
    Conditions of Instability
    Reactive with oxidizing agents.
    Incompatibility with various
    substances
    Corrosivity        Not available.    
    Special Remarks on        Not available.    
    Reactivity
    Special Remarks on        Not available.    
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans May cause damage to the following organs: kidneys, the nervous system, liver, heart, spleen, gastrointestinal
    tract, bone marrow.
    Other Toxic Effects on        Hazardous in case of ingestion, of inhalation.    
    Humans        Slightly hazardous in case of skin contact (irritant).    
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Potential Health Effects:    
    Toxic Effects on Humans        Skin: May cause skin irritation.    
    Eyes: May cause eye irritation.
    Inhalation: May be harmful if inhaled. May cause respiratory tract and mucous membrane irritation.
    Ingestion: May be harmful if swallowed. Ingestion of Barium and soluble Barium compounds can cause
    gastroenteritis, stomach pains, nausea, vomiting, diarrhea, increased salivation muscular paralysis, contractions
    of the smooth, striated and cardiac muscles, slow irregular, pulse, dysrhythmia, hypertension, bradycardia,
    cardiac shock, shallow breathing, tachypnea, respiratory failure, mydriasis, profound hypokalemia, metabolic
    acidosis, dizziness, seizures, temors, liver damage, renal failure.

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    BOD5 and COD        Not available.    
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products may    
    arise.
    Toxicity of the Products        The products of degradation are as toxic as the product itself.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation
    Barium Chloranilate, Trihydrate

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Not applicable.
    Identification
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b)Inventory: Barium Chloranilate (CAS no. 13435-46-6)
    Federal and State
    Barium Chloranilate trihydrate (CAS no. 32458-20-1) is not TSCA listed
    Regulations
    California        California prop. 65: This product contains the following ingredients for which the State of California has found    
    to cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).    
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
    Other Classifications        WHMIS (Canada) Not controlled under WHMIS (Canada).    
    DSCL (EEC)        R20/22- Harmful by inhalation and if        S28- After contact with skin, wash immediately    
    swallowed.        with plenty of water.    
    S36/37/39- Wear suitable protective clothing,
    gloves and eye/face protection.
    S45- In case of accident or if you feel unwell,
    seek medical advice immediately (show the
    label where possible).
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    2 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    Barium Chloranilate, Trihydrate
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

氯冉酸钡三水 分子结构与计算化学数据

分子结构数据

1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据

1、   疏水参数计算参考值(XlogP):无可用

2、   氢键供体数量:0

3、   氢键受体数量:4

4、   可旋转化学键数量:0

5、   拓扑分子极性表面积(TPSA):80.3

6、   重原子数量:13

7、   表面电荷:0

8、   复杂度:275

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:2

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产品介绍:
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