(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁

  • 基本信息
  • MSDS

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁 基本信息

中文名称:
(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁 
中文别名:
(AlphaR,AlphaR)-2,2-双(Alpha-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁;
(S,S)-(-)-2,2'-双[-(N,N-二甲胺基)(苯基)甲基]-1,1'-双(二苯基磷)二茂铁 
英文名称:
Ferrocene,1,1'-bis[(R)-(dimethylamino)phenylmethyl]-2,2'-bis(diphenylphosphino)-,(2S,2'S)-
英文别名:
(1S)-1-(2-diphenylphosphanylcyclopentyl)-N,N-dimethyl-1-phenylmethanamine,iron;
(RP,R inverted exclamation markaP)-1,1 inverted exclamation marka-Bis[(S)-|A-(dimethylamino)benzyl]-2,2 inverted exclamation marka-bis(diphenylphosphino)ferrocene;
(2S,2 inverted exclamation markaS)-1,1 inverted exclamation marka-Bis[(S)-(dimethylamino)phenylmethyl]-2,2 inverted exclamation marka-bis(diphenylphosphino)ferrocene (acc to ) 
CAS No.:
210842-74-3
分 子 式:
C52H50FeN2P2
分 子 量:
820.76
精确分子量:
820.28000
PSA:
33.66000
InChI:
The Key: NOQNSQAYSHWCQC-BRLFTNGRSA-N
分子结构式:
SDS:
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(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁 MSDS


Section 1: Product Identification
   Chemical Name:       (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%    
   CAS Registry Number:       210842-74-3    
   Formula:       C52H50FeN2P2    
   EINECS Number:       None    
   Chemical Family:       organophosphine ligand    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       210842-74-3       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and mucous membranes. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, eyes    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
   Chronic Health Affects:
   may be present.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Keep material in a tightly sealed container. Prolonged exposure to the air may result in degradation of the
   Handling and Storage:
   product. Handle and store material under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       orange-red solid    
   Molecular Weight:       820.76    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       Insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       exposure to oxygen, contact with strong oxidizing agents    
   Incompatibility:       Oxidizing agents and halogens    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, nitrogen oxides and iron oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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上海吉至生化科技有限公司

产品介绍:
产品名称:(S,S)-(-)-2,2'-双[-(N,N-二甲胺基)(苯基)甲基]-1,1'-双(二苯基磷)二茂铁 Cas号:210842-74-3 纯度:98% 包装信息:500mgea 价格:24,372.0元
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上海丹曦化工科技有限公司

产品介绍:
产品名称:(S,S)-(-)-2,2-双[-(N,N-二甲胺基)(苯基)甲基]-1,1-双(二苯基磷)二茂铁 Cas号:210842-74-3 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:董玫娟 电话:021-50107109 手机:13651711708