(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学

(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a 基本信息

中文名称:
(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a 
中文别名:
(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a;
(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷-环庚[2,1-A:3,4-A']二萘-4-基)二甲胺;
(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷-环庚[2,1-A 
英文名称:
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,N,N,2,6-tetramethyl-, (11bS)-
英文别名:
(S)-4-(dimethylamino)-2,6-dimethyldinaphtho[2,1-di:1',2'-f][1,3,2]-dioxaphosphepine;
(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;
N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 
CAS No.:
185449-86-9
分 子 式:
C24H22NO2P
分 子 量:
387.41
精确分子量:
387.13900
PSA:
29.52000
InChI:
The Key: MXASPZVRFOFONU-UHFFFAOYSA-N
风险术语:
R36/37/38
安全术语:
S26S36/S37/S39
分子结构式:
SDS:
查看

(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a 物化性质

熔点:
228-229ºC
存储条件/存储方法:

 

 密封于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):228-229

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a 安全信息

海关代码:
2921499090
危险类别码:
R36/37/38
安全说明:
S26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a 毒理性

生态数据:

 

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a MSDS


Section 1: Product Identification
   (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
   Chemical Name:
   CAS Registry Number:       185449-86-9    
   Formula:       C24H22NO2P    
   EINECS Number:       none    
   Chemical Family:       Phosphoramidite    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       185449-86-9       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, eyes, inhalation    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       May be harmful if swallowed. No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Keep material in a tightly sealed container. Prolonged exposure to moisture will result in degradation of the
   Handling and Storage:
   product. Handle and store material under a dry atmosphere.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       off-white pwdr.    
   Molecular Weight:       387.41    
   Melting Point:       228-229°    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       reacts slowly with water    

SECTION 10: Stability and Reactivity
   Stability:       air stable, moisture sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       extended exposure to moisture and acids    
   Incompatibility:       oxidizing agents    
   Decomposition Products:       carbon monoxide, phosphorus pentoxide, nitrogen and nitrogen oxides, and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a 海关数据

中国海关编码:2921499090

概述:
2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a 分子结构与计算化学数据

分子结构数据

1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据

1.疏水参数计算参考值(XlogP):6.8

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积29.5

7.重原子数量:28

8.表面电荷:0

9.复杂度:513

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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产品介绍:
产品名称:(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a Cas号:185449-86-9 纯度:99% 包装信息:1kg 价格:洽谈
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产品介绍:
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产品介绍:
产品名称:(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷酸-环庚基[2,1-a Cas号:185449-86-9 纯度: 包装信息:洽谈 价格:洽谈
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