(+)-3-羟基氨基酸异莰醇盐酸

  • 基本信息
  • 物化性质
  • 毒理性
  • MSDS
  • 结构与计算化学

(+)-3-羟基氨基酸异莰醇盐酸 基本信息

中文名称:
(+)-3-羟基氨基酸异莰醇盐酸 
中文别名:
(+)-3-羟基氨基酸异莰醇盐酸 
英文名称:
Bicyclo[2.2.1]heptan-2-ol,3-(hydroxyamino)-1,7,7-trimethyl-, hydrochloride, (1R,2S,3R,4S)- (9CI)
英文别名:
Bicyclo[2.2.1]heptan-2-ol, 3-(hydroxyamino)-1,7,7-trimethyl-, hydrochloride, (1R,2S,3R,4S)- (9CI);
Bicyclo[2.2.1]heptan-2-ol, 3-(hydroxyamino)-1,7,7-trimethyl-, hydrochloride, [1R-(exo,exo)]-;
(1R)-exo-3-(Hydroxylamino)isoborneol hydrochloride 
CAS No.:
162425-96-9
分 子 式:
C10H19NO2.ClH
分 子 量:
221.72
精确分子量:
221.11826
PSA:
52.49000
分子结构式:
SDS:
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(+)-3-羟基氨基酸异莰醇盐酸 物化性质

密度:
1.14g/cm3
熔点:
168-170ºC
沸点:
293.9ºC at 760mmHg
折射率:
1.541
蒸汽压:
0mmHg at 25°C
存储条件/存储方法:

 

 密闭于阴凉干燥环境中
稳定性相关:

 

遵照规定使用和储存则不会分解。
其它信息:

1.      性状:无可用

2.      密度(g/mL,25/4):无可用3.      相对蒸汽密度(g/mL,空气=1):无可用4.      熔点(ºC):168-1705.      沸点(ºC,常压):无可用6.      沸点(ºC,5.2kPa):无可用7.      折射率:无可用8.      闪点(ºC):无可用9.      比旋光度(º):无可用10.   自燃点或引燃温度(ºC):无可用11.   蒸气压(kPa,25ºC):无可用12.   饱和蒸气压(kPa,60ºC):无可用13.   燃烧热(KJ/mol):无可用14.   临界温度(ºC):无可用15.   临界压力(KPa):无可用16.   油水(辛醇/水)分配系数的对数值:无可用17.   爆炸上限(%,V/V):无可用18.   爆炸下限(%,V/V):无可用19.   溶解性:无可用

(+)-3-羟基氨基酸异莰醇盐酸 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

(+)-3-羟基氨基酸异莰醇盐酸 MSDS

Name: (+)-3-Hydroxylamino isoborneol hydrochloride Material Safety Data Sheet
Synonym: None
CAS: 162425-96-9
Section 1 - Chemical Product   MSDS Name:(+)-3-Hydroxylamino isoborneol hydrochloride Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
162425-96-9 (+)-3-Hydroxylamino isoborneol hydroch 97 unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Corrosives area. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 162425-96-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 168 - 170 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 221.73

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 162425-96-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(+)-3-Hydroxylamino isoborneol hydrochloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Pseudomonas putida:

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 162425-96-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 162425-96-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 162425-96-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

(+)-3-羟基氨基酸异莰醇盐酸 分子结构与计算化学数据

分子结构数据

1、  摩尔折射率:50.92

2、  摩尔体积(m3/mol):162.0

3、  等张比容(90.2K):420.2

4、  表面张力(dyne/cm):45.2

5、  极化率10-24cm3):20.18

计算化学数据

1、  疏水参数计算参考值(XlogP):1.7

2、  氢键供体数量:3

3、  氢键受体数量:3

4、  可旋转化学键数量:1

5、  拓扑分子极性表面积(TPSA):52.5

6、  重原子数量:13

7、  表面电荷:0

8、  复杂度:229

9、  同位素原子数量:0

10、  确定原子立构中心数量:4

11、  不确定原子立构中心数量:0

12、  确定化学键立构中心数量:0

13、  不确定化学键立构中心数量:0

14、  共价键单元数量:1

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产品介绍:
产品名称:(+)-3-羟基氨基酸异莰醇盐酸 Cas号:162425-96-9 纯度:99% 包装信息:100kg 价格:洽谈
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