8-(氯甲基)-6-氟苯并-1,3-二噁烷

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 下游产品

8-(氯甲基)-6-氟苯并-1,3-二噁烷 基本信息

中文名称:
8-(氯甲基)-6-氟苯并-1,3-二噁烷 
中文别名:
8-氯甲基-6-氟-1,3-苯并二氧辛;
8-(氯甲基)-6-氟苯并-1,3-二烷 
英文名称:
4H-1,3-Benzodioxin,8-(chloromethyl)-6-fluoro-
英文别名:
8-(CHLOROMETHYL)-6-FLUORO-4H-1,3-BENZODIOXINE;
4H-1,3-Benzodioxin,8-(chloromethyl)-6-fluoro;
8-(CHLORMETHYL)-6-FLUOR-4H-1,3-BENZODIOXIN;
2-(2,4-DICHLOROPHENOXY)BENZENECARBALDEHYDE;
8-(CHLOROMETHYL)-6-FLUOROBENZO-1,3-DIOXAN;
8-CHLOROMETHYL-6-FLUORO-4H-BENZO[1,3]DIOXINE;
8-(Chloromethyl)-6-fluoro-4H-benzo[d][1,3]dioxine;
8-(chloromethyl)-2-fluorobenzo-1,3-dioxane;
8-chloromethyl-6-fluoro-[1,3]-benzodioxine;
8-(Chloromethyl)-6-fluoro-4H-1,3-benzodioxine;
8-CHLOROMETHYL-6-FLUOROBENZO-1,3-DIOXAN;
8-CHLOROMETHYL-6-FLUOROBENZO-1,3-DIOXENE;
8-(CHLOROMETHYL)-6-FLUOROBENZO-1,3-DIOXANE 
CAS No.:
131728-94-4
分 子 式:
C9H8ClFO2
分 子 量:
202.61
精确分子量:
202.02000
PSA:
18.46000
InChI:
The Key: FMONGDHUPLQOCP-UHFFFAOYSA-N
风险术语:
R36/37/38
安全术语:
S26S36/S37/S39
分子结构式:
SDS:
查看

8-(氯甲基)-6-氟苯并-1,3-二噁烷 物化性质

密度:
1.348g/cm3
熔点:
78ºC
沸点:
310ºC at 760mmHg
闪点:
141.3ºC
折射率:
1.535
蒸汽压:
0.00113mmHg at 25°C
其它信息:

1.        性状:未确定

2.         密度(g/mL,20):未确定

3.         相对蒸汽密度(g/mL,空气=1):未确定

4.         熔点(ºC):78

5.         沸点(ºC,常压):未确定

6.         沸点(ºC,KPa):未确定

7.         折射率:未确定

8.         闪点(ºC):未确定

9.         比旋光度(º):未确定

10.      自燃点或引燃温度(ºC):未确定

11.      蒸气压(Pa,20ºC):未确定

12.      饱和蒸气压(KPa,20ºC):未确定

13.      燃烧热(KJ/mol):未确定

14.      临界温度(ºC):未确定

15.      临界压力(KPa):未确定

16.      油水(辛醇/水)分配系数的对数值:未确定

17.      爆炸上限(%,V/V):未确定

18.      爆炸下限(%,V/V):未确定

19.     溶解性:未确定

8-(氯甲基)-6-氟苯并-1,3-二噁烷 安全信息

海关代码:
2932999099
危险类别码:
R34
安全说明:
S26-S36/37/39-S45
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

8-(氯甲基)-6-氟苯并-1,3-二噁烷 MSDS

Name: 8-(Chloromethyl)-6-fluoro-4h-1 3-benzodioxine 97% Material Safety Data Sheet
Synonym: 8-(Chloromethyl)-6-fluoro-1,3-benzodioxin
CAS: 131728-94-4
Section 1 - Chemical Product   MSDS Name:8-(Chloromethyl)-6-fluoro-4h-1 3-benzodioxine 97% Material Safety Data Sheet
Synonym:8-(Chloromethyl)-6-fluoro-1,3-benzodioxin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
131728-94-4 8-(Chloromethyl)-6-fluoro-4H-1,3-benzo 97% unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 131728-94-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 81 - 84 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H8ClFO2
Molecular Weight: 203

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, fluorine, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 131728-94-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
8-(Chloromethyl)-6-fluoro-4H-1,3-benzodioxine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 131728-94-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 131728-94-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 131728-94-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

8-(氯甲基)-6-氟苯并-1,3-二噁烷 海关数据

中国海关编码:2932999099

概述:
2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

8-(氯甲基)-6-氟苯并-1,3-二噁烷 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:46.78

2、摩尔体积(cm3/mol):150.2

3、等张比容(90.2K):385

4、表面张力(dyne/cm):43.1

5、介电常数:无可用的

6、极化率(10-24cm3):18.54

7、单一同位素质量:202.019685 Da

8、标称质量:202 Da

9、平均质量:202.61 Da

计算化学数据

1.疏水参数计算参考值(XlogP):1.9

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积18.5

7.重原子数量:13

8.表面电荷:0

9.复杂度:179

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

8-(氯甲基)-6-氟苯并-1,3-二噁烷 下游产品

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