4,4-甲烯双-(2,6-二异丙基苯胺)

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

4,4-甲烯双-(2,6-二异丙基苯胺) 基本信息

中文名称:
4,4-甲烯双-(2,6-二异丙基苯胺) 
中文别名:
4,4’-亚甲双(2,6-二异丙基苯胺);
4,4'-亚甲基双(2,6-二异丙基苯胺) 
英文名称:
4,4-Methylenebis-(2,6-diisopropylaniline)
英文别名:
4-[[4-amino-3,5-di(propan-2-yl)phenyl]methyl]-2,6-di(propan-2-yl)aniline;
4,4'-methylenebis(N-salicylidene-2,6-diisopropylaniline);
4,4'-methylene-bis(2,6-diisopropylaniline);
methylene-1,1-bis(2,6-diisopropylaniline);
4-{[4-amino-3,5-bis(methylethyl)phenyl]methyl}-2,6-bis(methylethyl)phenylamine;
di(2,6-diisopropyl-4-aminophenyl)methane 
CAS No.:
19900-69-7
分 子 式:
C25H38N2
分 子 量:
366.58
精确分子量:
366.30300
PSA:
52.04000
MDL:
MFCD00071554
EINECS:
243-421-7
风险术语:
R20/21/22R36/37/38R36/38
安全术语:
S26S36S36/S37/S39
分子结构式:
SDS:
查看

4,4-甲烯双-(2,6-二异丙基苯胺) 物化性质

外观与性状:
褐色熔融
密度:
0.98 g/cm3
熔点:
10-30ºC
沸点:
215-218ºC (0.5 mmHg) ,481ºC at 760 mmHg
闪点:
294ºC
折射率:
1.559
蒸汽压:
2.07E-09mmHg at 25°C
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):0.99

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):10-30

5.       沸点(ºC,常压):215-218 /0.5 mmHg

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):113

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

4,4-甲烯双-(2,6-二异丙基苯胺) 安全信息

海关代码:
2921590090
危险类别码:
R36/38
安全说明:
36/37/39-26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
:

4,4-甲烯双-(2,6-二异丙基苯胺) 毒理性

生态数据:

 

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

4,4-甲烯双-(2,6-二异丙基苯胺) MSDS

Name: 4 4 -Methylenebis-(2 6-diisopropylaniline) 90-95% Material Safety Data Sheet
Synonym: None
CAS: 19900-69-7
Section 1 - Chemical Product   MSDS Name:4 4 -Methylenebis-(2 6-diisopropylaniline) 90-95% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
19900-69-7 Benzenamine,4,4'-methylenebis2,6-bis(1 100 243-421-7
Hazard Symbols: XN
Risk Phrases: 22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 19900-69-7: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: beige
Odor: Not
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 215.0 - 218.0 deg C @ .50mmHg
Freezing/Melting Point: 52.00 - 59.00 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.0150g/cm3
Molecular Formula: C25H38N2
Molecular Weight: 366.58

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 19900-69-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzenamine,4,4'-methylenebis2,6-bis(1-methylethyl)- - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 19900-69-7: No information available.
Canada
CAS# 19900-69-7 is listed on Canada's NDSL List.
CAS# 19900-69-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 19900-69-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4,4-甲烯双-(2,6-二异丙基苯胺) 海关数据

中国海关编码:2921590090

概述:
2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

4,4-甲烯双-(2,6-二异丙基苯胺) 分子结构与计算化学数据

分子结构数据

1   摩尔折射率:120.77

2   摩尔体积m3/mol373.6

3   等张比容(90.2K):930.1

4   表面张力dyne/cm38.3

5   极化率10-24cm347.88

计算化学数据

1.疏水参数计算参考值(XlogP):7

2.氢键供体数量:2

3.氢键受体数量:2

4.可旋转化学键数量:6

5.互变异构体数量:无

6.拓扑分子极性表面积52

7.重原子数量:27

8.表面电荷:0

9.复杂度:366

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

4,4-甲烯双-(2,6-二异丙基苯胺) 上游产品

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