甲基苯基二硫醚

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

甲基苯基二硫醚 基本信息

中文名称:
甲基苯基二硫醚 
中文别名:
甲基苯基二硫醚;
5,10,15,20-tetraphenyl-21H,23H-porphine copper(ii);
magnesium sulfate monohydrate;
Salen-CoSALCOMINE;
N,N-BIS(SALICYLIDENE)ETHYLENE-DIIMINOCOBALT (II);
N,N'-Bis(salicylidene)ethylenediamine cobalt salt;
Phenyl-2-pyridylcarbinol;
a-Phenyl-2-pyridinemethanol;
2-Pyridinemethanol, a-phenyl-;
AlPCCl;
Aluminum phthalocyanine chloride;
29H,31H-phthalocyanine, nickel(2+) salt (1:1);
[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]nickel;
EDTA-CuNa2;
dis 
英文名称:
Disulfide, methylphenyl
英文别名:
(methyldisulfanyl)benzene;
Methyl phenyl disulfide;
Phenyl-methyldisulfid;
Methyl-phenyl-disulfid;
methyl phenyl disulfide;
Methyl phenyl disulphide;
phenylmethyl disulfide;
Disulfide,methyl phenyl 
CAS No.:
14173-25-2
分 子 式:
C7H8S2
分 子 量:
156.26
精确分子量:
156.00700
PSA:
50.60000
MDL:
MFCD00026035
EINECS:
238-020-9
InChI:
InChI=1/C7H8S2/c1-8-9-7-5-3-2-4-6-7/h2-6H,1H3
风险术语:
36/37/38-10
分子结构式:
SDS:
查看

甲基苯基二硫醚 物化性质

密度:
1.16g/cm3
沸点:
215ºC at 760mmHg
闪点:
112.4ºC
折射率:
1.617-1.619
蒸汽压:
0.222mmHg at 25°C
存储条件/存储方法:

 密闭于阴凉干燥环境中

稳定性相关:

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):1.15

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):65

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:1.617-1.619 

8.       闪点(ºC):22

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

甲基苯基二硫醚 安全信息

海关代码:
2930909090
危险类别码:
R36/37/38
安全说明:
37/39-26-16
危险标志:
Xi: Irritant;

甲基苯基二硫醚 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

甲基苯基二硫醚 MSDS

Name: Methyl phenyl disulfide 97+% Material Safety Data Sheet
Synonym: Non
CAS: 14173-25-2
Section 1 - Chemical Product   MSDS Name:Methyl phenyl disulfide 97+% Material Safety Data Sheet
Synonym:Non

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
14173-25-2 Methyl phenyl disulfide, 97+% 97+% 238-020-9
Hazard Symbols: None Listed.
Risk Phrases: 10

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable.The toxicological properties of this material have not been fully investigated.Stench.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
No information found.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Use spark-proof tools and explosion proof equipment. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 14173-25-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear slightly yellow
Odor: Rather pungent odor, reminiscent
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 65 deg C @ 2.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 22 deg C ( 71.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.1500g/cm3
Molecular Formula: C7H8S2
Molecular Weight: 156.26

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 14173-25-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl phenyl disulfide, 97+% - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 14173-25-2: No information available.
Canada
CAS# 14173-25-2 is listed on Canada's NDSL List.
CAS# 14173-25-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14173-25-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

甲基苯基二硫醚 海关数据

中国海关编码:2930909090

概述:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

甲基苯基二硫醚 分子结构与计算化学数据

分子结构数据

1   摩尔折射率:47.40

2   摩尔体积m3/mol):134.4

3   等张比容90.2K):348.4

4   表面张力3.0 dyne/cm):45.1

5   极化率0.5 10-24cm3):18.79

计算化学数据

1.疏水参数计算参考值(XlogP):2.5

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积50.6

7.重原子数量:9

8.表面电荷:0

9.复杂度:67.3

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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