溴化亚铁(II)水合物

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS
  • 结构与计算化学

溴化亚铁(II)水合物 基本信息

中文名称:
溴化亚铁(II)水合物 
中文别名:
溴化亚铁(II)水合物 
英文名称:
Iron bromide (FeBr2),hexahydrate (8CI,9CI)
英文别名:
Iron(II) bromide hydrate;
Ironbromidehydrateorangextl 
CAS No.:
13463-12-2
分 子 式:
Br2Fe.6H2O
分 子 量:
215.67
精确分子量:
231.78200
PSA:
9.23000
风险术语:
R20R36/37/38
安全术语:
S26S36
分子结构式:
SDS:
查看

溴化亚铁(II)水合物 制备方法及用途

制备方法

1.在隔绝空气下将铁粉溶于氢溴酸中,经浓缩、冷却后即析出六水合物的结晶。2.由过量铁与溴水在水中作用而得,或由铁溶于氢溴酸后在低于49℃温度下蒸发而得。

合成制备方法

1.在隔绝空气下将铁粉溶于氢溴酸中,经浓缩、冷却后即析出六水合物的结晶。

2.由过量铁与溴水在水中作用而得,或由铁溶于氢溴酸后在低于49℃温度下蒸发而得。

用途简介

溴化亚铁(II)水合物 物化性质

熔点:
27ºC
稳定性相关:

溶于水、乙醇和乙醚,在潮湿空气中易氧化。

其它信息:

1.       性状:浅绿色至蓝绿色正交棱柱体,对光敏感。

2.       密度(g/mL,25/4℃):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):27

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):不适用的

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

溴化亚铁(II)水合物 安全信息

危险类别码:
20-36/37/38
安全说明:
26-36
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。

溴化亚铁(II)水合物 MSDS


Section 1: Product Identification
   Chemical Name:       Iron (II) bromide hydrate    
   CAS Registry Number:       13463-12-2    
   Formula:       FeBr2.XH2O    
   EINECS Number:       none    
   Chemical Family:       metal halide    
   Synonym:       Ferrous bromide hydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13463-12-2       100%       1mg/m3       no data    

Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. May cause liver damage. Material forms an acidic solution with
   Emergency Overview:
   water.
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust.    
   Eye Contact:       Causes moderate to severe irritation of the eyes.    
   Skin Contact:       Causes irritation, redness, and pain to skin.    
   Inhalation:       Dust causes coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.    
   Ingestion:       Soluble iron salts may cause poisoning.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Prolonged ingestion may lead to damage to the liver and pancreas. Prolonged inhalation of dusts may cause
   Chronic Health Affects:
   pulmonary fibrosis.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       none    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
   Spill and Leak Procedures:
   inert material and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store solid in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       greenish-black xtl.    
   Molecular Weight:       215.67    
   Melting Point:       27°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       very soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       chlorine    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

溴化亚铁(II)水合物 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:231.782167 Da

8、标称质量:232 Da

9、平均质量:233.6683 Da

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