氯化镱

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS
  • 结构与计算化学

氯化镱 基本信息

中文名称:
氯化镱 
中文别名:
氯化镱(III) 六水合物;
氯化镱 
英文名称:
Ytterbium chloride(YbCl3), hexahydrate (7CI,8CI,9CI)
英文别名:
Ytterbium(III) chloride hexahydrate;
ytterbium(3+),trichloride,hexahydrate 
CAS No.:
10035-01-5
分 子 式:
Cl3Yb.6H2O
分 子 量:
387.49
精确分子量:
386.90900
PSA:
55.38000
MDL:
MFCD00149885
EINECS:
237-632-3
InChI:
InChI=1/3ClH.6H2O.Yb/h3*1H;6*1H2;/q;;;;;;;;;+2/p-3
风险术语:
36/37/38
分子结构式:
SDS:
查看

氯化镱 制备方法及用途

制备方法

将镱的氧化物或氢氧化物溶于盐酸中,将其溶液在水浴上蒸发、浓缩、冷却即析出六水氯化镱(Ⅲ)。

合成制备方法

将镱的氧化物或氢氧化物溶于盐酸中,将其溶液在水浴上蒸发、浓缩、冷却即析出六水氯化镱(Ⅲ)。

用途简介

氯化镱 物化性质

外观与性状:
固体
密度:
2.58 g/mL at 25 °C(lit.)
熔点:
180 °C (dec.)(lit.)
稳定性相关:

易溶于水,溶于无水乙醇。在180℃失去6分子水。

其它信息:

1.       性状:绿色正交系晶体。有吸湿性。

2.       密度(g/mL,25℃):2.575

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):865

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,20ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定。

氯化镱 安全信息

WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R36/37/38
安全说明:
S26-S36
危险标志:
Xi

氯化镱 MSDS

Name: Ytterbium(III) Chloride Hexahydrate 99.999% Material Safety Data Sheet
Synonym: Non
CAS: 10035-01-5
Section 1 - Chemical Product   MSDS Name:Ytterbium(III) Chloride Hexahydrate 99.999% Material Safety Data Sheet
Synonym:Non

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10035-01-5 Ytterbium(III) Chloride Hexahydrate 99.999 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Expected to be a low ingestion hazard.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10035-01-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 865 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: 2.5750g/cm3
Molecular Formula: Cl3Yb.6H2O
Molecular Weight: 387.48

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 10035-01-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ytterbium(III) Chloride Hexahydrate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10035-01-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10035-01-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10035-01-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

氯化镱 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:386.908846 Da

8、标称质量:387 Da

9、平均质量:387.4907 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:6

3.氢键受体数量:9

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积6

7.重原子数量:10

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:10

推荐供应商更多供应商>>

湖北云镁科技有限公司

产品介绍:
产品名称:氯化镱(III) 六水合物 Cas号:10035-01-5 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:方经理 电话:027-59206672 手机:18327059871

山东默派生物科技有限公司

产品介绍:
产品名称:氯化镱(III) 六水合物 Cas号:10035-01-5 纯度:99% 包装信息:1kg 价格:洽谈
联系方式:
联系人:谭经理 电话:13053322091 手机:13053322091

上海吉至生化科技有限公司

产品介绍:
产品名称:氯化镱(III)六水合物 Cas号:10035-01-5 纯度:99.9% 包装信息:100gea,500gea,5gea 价格:29.0元 - 708.0元
联系方式:
联系人:Shirley张 电话:021-57520831 手机:18116052675

南京化学试剂股份有限公司

产品介绍:
产品名称:氯化镱 Cas号:10035-01-5 纯度:99.9% 包装信息:500g 价格:洽谈
联系方式:
联系人:南试 电话:025-58369808 手机:13813995600

北京百灵威科技有限公司

产品介绍:
产品名称:氯化镱(III) 六水合物 602258 Cas号:10035-01-5 纯度:99.9%,金属分析 包装信息:10g,50g,100g,500g 价格:洽谈
联系方式:
联系人:翟先生 电话:18210857532 手机:18210857532

上海瀚思化工有限公司

产品介绍:
产品名称:氯化镱(III),六水合物 Cas号:10035-01-5 纯度:99.9% metals basis 包装信息:50g 价格:494.4元
联系方式:
联系人:张 电话:021-64806089 手机:18049821080

湖北省圣宝莱生物科技有限公司

产品介绍:
产品名称:氯化镱(III) 六水合物 Cas号:10035-01-5 纯度:99% 包装信息:100g 价格:洽谈
联系方式:
联系人:刘 电话:027-59105235 手机:15527244834

山东西亚化学有限公司

产品介绍:
产品名称:氯化镱 Cas号:10035-01-5 纯度:99.99% 包装信息:100g 价格:580.0元
联系方式:
联系人:崔 电话:4009903999 手机:18053972095

湖北恩星生物科技有限公司

产品介绍:
产品名称:氯化镱(III) 六水合物 Cas号:10035-01-5 纯度: 包装信息:100kg,200kg,300kg,400kg,500kg 价格:64.0元 - 100.0元
联系方式:
联系人:邵经理 电话:16621771607 手机:16621771607

江苏从众化工股份有限公司

产品介绍:
产品名称:氯化镱 Cas号:10035-01-5 纯度:99% 包装信息:100kg 价格:100.0元
联系方式:
联系人:王 电话:13862111431 手机:13862111431
QQ: 2241752642
微信二维码
电话: 19906633110